Superionic Conduction in K3SbS4 Enabled by Cl-Modified Anion Lattice.

All-solid-state potassium batteries emerge as promising alternatives to lithium batteries, leveraging their high natural abundance and cost-effectiveness. Developing potassium solid electrolytes (SEs) with high room-temperature ionic conductivity is critical for realizing efficient potassium batteries. In this study, we present the synthesis of K2.98Sb0.91S3.53Cl0.47, showcasing a room-temperature ionic conductivity of 0.32 mS/cm and a low activation energy of 0.26 eV. This represents an increase of over two orders of magnitude compared to the parent compound K3SbS4, marking the highest reported ionic conductivity for non-oxide potassium SEs. Solid-state 39K magic-angle-spinning nuclear magnetic resonance on K2.98Sb0.91S3.53Cl0.47 reveals an increased population of mobile K+ ions with fast dynamics. Ab initio molecular dynamics (AIMD) simulations further confirm a delocalized K+ density and significantly enhanced K+ diffusion. This work demonstrates diversification of the anion sublattice as an effective approach to enhance ion transport and highlights K2.98Sb0.91S3.53Cl0.47 as a promising SE for all-solid-state potassium batteries.

Frontier performance of in situ formed α-MnO2 dispersed over functionalized multi-walled carbon nanotubes covalently anchored to a graphene oxide nanosheet framework as supercapacitor materials.

α-MnO2 has been recognized as a potential material for supercapacitor applications because of its abundance, cost-effectiveness, environmental-benign nature and high theoretical specific capacitance (C sp) of 1370 F g-1. In this study, we succeeded for the first time to achieve the theoretical C sp with 3D multi-walled carbon nanotubes (MWCNTs) horizontally dispersed on 2D graphene oxide (GO) nanosheet framework-supported MnO2 ternary nanocomposites synthesized by a simple precipitation method. The in situ formation of α-MnO2 and GO, and the growth of 3D MWCNT/GO framework took place simultaneously in a strong acidic suspension containing functionalized-MWCNTs, graphite, NaNO3 and KMnO4. Characterizations of the composites synthesized by varying % wt MWCNTs were performed with state-of-the-art techniques. These composites were characterized to be semi-crystalline and mesoporous in nature, and the scrupulous analyses of field emission scanning electron microscopic images showed MnO2 nano-flower distributed over 3D MWCNTs dispersed-on-GO-nanosheet frameworks. These composites deposited on a graphite electrode exhibited an ideal supercapacitive behavior in an Na2SO4 solution measured via cyclic voltammetry and chronopotentiometry. Optimum contents of MnO2 and MWCNTs in the composites showed a maximum C sp of 1380 F g-1 with satisfactory energy and power densities compared in the Ragone plot. An ascending trend of C sp against the charge-discharge cycle number studied for 700 cycles was noticed. Well-dispersion of α-MnO2 nanoparticles throughout 3D MWCNTs covalently-anchored to the GO nanosheet framework is discussed to aid in achieving the frontier C sp of MnO2.