Heterogeneous Fe-Doped NiCoP-MoO3 Efficient Electrocatalysts for Overall Water Splitting.

Transition metal phosphides with excellent performance are one of the effective alternatives to noble metal catalysts in overall water splitting. In this paper, the Fe-NiCoP-MoO3 composite was prepared by a facile synthesis as the bifunctional electrocatalyst. Fe-NiCoP-MoO3 achieves an operating current density of 10 mA/cm2 at a low overpotential of 65 mV for hydrogen evolution reaction and drives an operating current density of 50 mA/cm2 at only 293 mV for oxygen evolution reaction. Significantly, Fe-NiCoP-MoO3 was employed as the anode and cathode for overall water splitting, which only requires a cell voltage of 1.586 V to reach 10 mA/cm2 as well as shows excellent stability. The electrocatalytic activity of Fe-NiCoP-MoO3 exceeds most of the recently reported typical bifunctional electrocatalysts. This may be due to the coupling effect between the polymetallic phosphides. In addition, heterogeneous catalysts generally expose more active sites than homogeneous catalysts. In addition, replacing MoO3 with WO3 and VO3 can also improve the performance of Fe-NiCoP. This work provides an idea for the modification of phosphides.

An adaptive pulmonary nodule detection algorithm.

Recently, lung cancer has been paid more and more attention. People have reached a consensus that early detection and early treatment can improve the survival rate of patients. Among them, pulmonary nodules are the important reference for doctors to determine the lung health. With the continuous improvement of CT image resolution, more suspected pulmonary nodule information appears from the impact of chest CT. How to relatively and accurately locate the suspected nodule location from a large number of CT images has brought challenges to the doctor's daily diagnosis. To solve the problem that the original DBSCAN clustering algorithm needs manual setting of the threshold, this paper proposes a region growing algorithm and an adaptive DBSCAN clustering algorithm to improve the accuracy of pulmonary nodule detection. The image is roughly processed and ROI (Regions of Interest) region is roughly extracted by CLAHE transform. The region growing algorithm is used to roughly process the adjacent region's expansibility and the suspected region in ROI, and mark the center point in the region and the boundary point of its point set. The mean value of region range is taken as the threshold value of DBSCAN clustering algorithm. The center of the point domain is used as the starting point of clustering, and the rough set of points is used as the MinPts threshold. Finally, the clustering results are labeled in the initial CT image. Experiments show that the pulmonary nodule detection method proposed in this paper effectively improves the accuracy of the detection results.

In-situ construction defect-rich CuNiCoS4 /1T-MoS2 heterostructures as superior electrocatalysts for water splitting.

Rational design and construction of bifunctional heterostructure electrocatalysts with high-conductivity and more active sites is imperative for water splitting. Herein, based on the tunable property of layered double hydroxide laminates cations, topological transformation technology and template confine method, a series of high-performance bifunctional catalysts composed of transition metal doping NiCo2S4 (MNiCoS4, M = Cu, Fe, Zn, Mn) and 1T-MoS2 were in-situ fabricated on nickel foam. In particular, CuNiCoS4/1T-MoS2 exhibits an ultralow overpotential of 163 mV at 50 mA cm-2 for oxygen evolution reaction (OER) and favorable hydrogen evolution reaction activity. The two-electrode system requires only 1.52 V to attain a current density of 10 mA cm-2. To the best of our knowledge, its OER electrocatalytic activity far exceed state-of-art catalysts reported. The outstanding performance of this series of catalysts can be attributed to two aspects. First, the highly conductive 1T-MoS2 can facilitate electron transfer, and second, the defect-rich heterostructure can effectively regulate the electronic structure of the active metal and expose abundant active sites. This work provides a valuable strategy for developing high activity electrocatalysts for efficient water splitting.

Novel Vertical 3D Structure of TaOx-based RRAM with Self-localized Switching Region by Sidewall Electrode Oxidation.

A novel vertical 3D RRAM structure with greatly improved reliability behavior is proposed and experimentally demonstrated through basically compatible process featuring self-localized switching region by sidewall electrode oxidation. Compared with the conventional structure, due to the effective confinement of the switching region, the newly-proposed structure shows about two orders higher endurance (>10(8) without verification operation) and better retention (>180h@150 °C), as well as high uniformity. Corresponding model is put forward, on the base of which thorough theoretical analysis and calculations are conducted as well, demonstrating that, resulting from the physically-isolated switching from neighboring cells, the proposed structure exhibits dramatically improved reliability due to effective suppression of thermal effects and oxygen vacancies diffusion interference, indicating that this novel structure is very promising for future high density 3D RRAM application.