RESUMEN
The properties of periodic cellular structures strongly depend on the regular spatial arrangement of their constituent base materials and can be controlled by changing the topology and geometry of the repeating unit cell. Recent advances in three-dimensional (3D) fabrication technologies more and more expand the limits of fabricable real-world architected materials and strengthen the need of novel microstructural topologies for applications across all length scales and fields in both fundamental science and engineering practice. Here, we systematically explore, interpret, and analyze publicly available crystallographic network topologies from a structural point of view and provide a ready-to-use unit cell catalog with more than 17,000 unique entries in total. We show that molecular crystal networks with atoms connected by chemical bonds can be interpreted as cellular structures with nodes connected by mechanical bars. By this, we identify new structures with extremal properties as well as known structures such as the octet-truss or the Kelvin cell and show how crystallographic symmetries are related to the mechanical properties of the structures. Our work provides inspiration for the discovery of novel cellular structures and paves the way for computational methods to explore and design microstructures with unprecedented properties, bridging the gap between microscopic crystal chemistry and macroscopic structural engineering.