Application of waste tyre-based powdered activated carbon for the adsorptive removal of cylindrospermopsin toxins from environmental matrices: Optimization using response surface methodology and desirability function.

Activated carbon (AC) derived from waste tyre was investigated for the removal of cylindrospermopsin (CYN) from aqueous solutions and spiked real water samples. Response surface methodology based on Box-Behnken design was used for the optimization of experimental conditions. Based on the desirability score of 1.0, the percentage recovery of CYN was optimized at 104% and the optimum conditions were found to be 50.0 mg for the mass of adsorbent, 60 min for contact time and sample pH value of 3. The experimental equilibrium data best fitted Langmuir isotherm model and the maximum monolayer adsorption uptake of the waste tyre-based AC (WTAC) was 107 µg g-1. Kinetic studies demonstrated that the adsorption data were best described by pseudo-second-order. Finally, the optimized adsorption process was applied for the removal of CYN from real samples.

Adsorptive removal of microcystin-LR from surface and wastewater using tyre-based powdered activated carbon: Kinetics and isotherms.

Microcystin LR (MC-LR) is a highly toxic compound and it is known for its adverse health effect on both humans and animals. Due to the ineffectiveness of conventional water treatments methods, for the past decades, researchers have been developing cost-effective ways of removing MC-LR from water bodies. This study reports the application of powdered activated carbon (PAC) obtained from the waste tyre for the removal of MC-LR. The choice of the adsorbent was chosen due to its attractive properties. The prepared tyre-based PAC was found to have the large surface area (1111 m2 g-1). The detection of MC-LR was achieved using high performance liquid chromatography (HPLC) coupled with a PDA detector. The experimental parameters (such as optimum pH, dosage and contact time) affecting the removal of MC-LR using tyre based-powdered activated carbon were optimized using response surface methodology (RSM). Maximum removal of MC-LR was achieved under the following optimum conditions; sample pH 4, carbon dosage concentration 10,000 mg L-1 and contact time of 34 min. Under optimum conditions, kinetic studies and adsorption isotherms reflected better fit for pseudo-second-order rate and Langmuir isotherm model, respectively. The optimized method was applied for the removal of MC-LR in wastewater sample. The effluent and influent sample contained initial concentrations ranging from 0.52 to 8.54 µg L-1 and the removal efficiency was 100%.