1.
J Org Chem
; 88(15): 11278-11283, 2023 Aug 04.
Artículo
en Inglés
| MEDLINE
| ID: mdl-37486801
RESUMEN
The partial oxidation of methane with O2 is significant due to its potential of providing abundant chemical feedstock. Only a few examples realized this type of reaction in homogeneous solvent systems, most of which are in low efficiency. Herein, we present a pyridine N-oxide-promoted cobalt-catalyzed O2-mediated methane oxidation to produce methylene bis(trifluoroacetate) with productivity over 500 molester molmetal-1 h-1.