Silk Biomaterials for Bone Tissue Engineering.

Silk is a natural fibrous polymer with application potential in regenerative medicine. Increasing interest remains for silk materials in bone tissue engineering due to their characteristics in biocompatibility, biodegradability and mechanical properties. Plenty of the in vitro and in vivo studies confirmed the advantages of silk in accelerating bone regeneration. Silk is processed into scaffolds, hydrogels, and films to facilitate different bone regenerative applications. Bioactive factors such as growth factors and drugs, and stem cells are introduced to silk-based matrices to create friendly and osteogenic microenvironments, directing cell behaviors and bone regeneration. The recent progress in silk-based bone biomaterials is discussed and focused on different fabrication and functionalization methods related to osteogenesis. The challenges and potential targets of silk bone materials are highlighted to evaluate the future development of silk-based bone materials.

Degradation of textile dyes from aqueous solution using tea-polyphenol/Fe loaded waste silk fabrics as Fenton-like catalysts.

In this study, waste silk fabrics (SF) were modified with tea-polyphenols (TPs) and then iron (Fe2+). The modified silk fabrics (TP-SF/Fe) were characterized via Fourier-transform infrared (FTIR), energy dispersive spectroscopy (EDS), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS) analysis. TP-SF/Fe was used in the Fenton-like removal of dyes (methylene blue, reactive orange GRN, and cationic violet X-5BLN) from aqueous solutions with catalyst-like activity. The effects of different catalyst samples, contact time, H2O2 concentration, initial dye concentration, and pH values on dye removal were investigated. The results showed that the dye removal percentages with the TP-SF/Fe-H2O2 sample reached 98%, 97%, and 95% in 5-40 min for methylene blue, reactive orange GRN, and cationic violet X-5BLN, respectively. Different thermodynamic and kinetic models were used to check the best fit of the adsorption data. The results indicated that the Freundlich isotherm and pseudo first-order kinetics models were the best fits. Moreover, it was also proved that TP-SF/Fe would be quite an effective and economical adsorbent for the treatment of textile dye wastewater. This work provides the basis for waste silk application in the removal of dyes from wastewater.

Dopamine Grafted Iron-Loaded Waste Silk for Fenton-Like Removal of Toxic Water Pollutants.

Dispersion of iron was achieved on waste silk fibers (wSF) after grafting of polydopamine (PDA). The catalytic activity of the resulting material (wSF-DA/Fe) was investigated in Fenton-like removal of toxic aromatic dyes (Methylene Blue, Cationic Violet X-5BLN, and Reactive Orange GRN) water. The dye removal yield reached 98%, 99%, and 98% in 10-40 min for Methylene Blue, Cationic Violet X-5BLN, and Reactive Orange GRN, respectively. The catalytic activity was explained in terms of the effects of temperature, dyes, and electrolytes. In addition, the kinetic study showed that the removal of dyes followed pseudo-1st order adsorption kinetics. These findings allow envisaging the preparation of fiber-based catalysts for potential uses in environmental and green chemistry.