Mechanically and Thermally Stable Cathode Electrolyte Interphase Enables High-temperature, High-voltage Li||LiCoO2 Batteries.

The development of high-energy-density Li||LiCoO2 batteries is severely limited by the instability of cathode electrolyte interphase (CEI) at high voltage and high temperature. Here we propose a mechanically and thermally stable CEI by electrolyte designing for achieving the exceptional performance of Li||LiCoO2 batteries at 4.6 V and 70 °C. 2,4,6-tris(3,4,5-trifluorophenyl)boroxin (TTFPB) as the additive could preferentially enter into the first shell structure of PF6 - solvation and be decomposed on LiCoO2 surface at low oxidation potential to generate a LiBx Oy -rich/LiF-rich CEI. The LiBx Oy surface layer effectively maintained the integrity of CEI and provided excellent mechanical and thermal stability while abundant LiF in CEI further improved the thermal stability and homogeneity of CEI. Such CEI drastically alleviated the crack and regeneration of CEI and irreversible phase transformation of the cathode. As expected, the Li||LiCoO2 batteries with the tailored CEI achieved 91.9 % and 74.0 % capacity retention after 200 and 150 cycles at 4.6 and 4.7 V, respectively. Moreover, such batteries also delivered an unprecedented high-temperature performance with 73.6 % capacity retention after 100 cycles at 70 °C and 4.6 V.

Simultaneous chiral polarization and edge enhancement imaging enabled by a single geometric-phase-based element.

In this Letter, we propose a multifunctional imaging system enabled by a single geometric-phase-based liquid crystal (LC) element, which integrates chiral polarization and edge enhancement imaging. The element is located at the frequency domain plane in a 4F imaging system, and the phase profile of the element consists of a fork grating in the x direction and a grating in the y direction, which provide edge enhancement and chiral polarization imaging capabilities. Benefiting from the tunable property of the LC, the system can be switched from a polarization and edge imaging mode to the normal conventional imaging mode which is capable of conveniently acquiring the needed image information. Experiments demonstrate that the system can easily achieve multifunctional and switchable imaging, which agrees well with our design, and our LC element can work in the broadband spectrum because of the geometric phase modulation. The multifunctional strategy used here can effectively avoid the need to increase the size of the original microscopic system and the need for additional mechanical rotation of components. We believe that the proposed system with the additional advantages of electric control and tunability can find applications in biological imaging, medical detection, and optical computing.

Geometric-phase-based axicon lens for computational achromatic imaging.

Conventional optical imaging systems usually utilize several lenses within a precise assembly to eliminate chromatic aberration, which increases the difficulty of system integration. In recent years, with the rapid development of metasurfaces and liquid crystals (LCs), planar optical elements provide feasible solutions to realize flexible light manipulation and lightweight systems. However, there also exists chromatic aberration, which can be corrected but at the cost of a complex device design. Here, a geometric-phase-based axicon lens is utilized to correct chromatic aberration across a broadband wavelength with the assistance of a post-process algorithm. The axicon lens is fabricated through arranging orientations of liquid-crystal molecules with a standard photoalignment technique, and it produces an approximately invariant point spread function (PSF) at several discrete wavelengths, which is used as the prior information to extract the object in the blurred image. In the experiment, the reconstruction quality is significantly improved after the post-process algorithm. We expect our work to provide further development to reduce the dispersion with both the device design and the computational image technique.

Reversal of hyperactive subthalamic circuits differentially mitigates pain hypersensitivity phenotypes in parkinsonian mice.

Although pain is a prevalent nonmotor symptom in Parkinson's disease (PD), it is undertreated, in part because of our limited understanding of the underlying mechanisms. Considering that the basal ganglia are implicated in pain sensation, and that their synaptic outputs are controlled by the subthalamic nucleus (STN), we hypothesized that the STN might play a critical role in parkinsonian pain hypersensitivity. To test this hypothesis, we established a unilateral parkinsonian mouse model with moderate lesions of dopaminergic neurons in the substantia nigra. The mice displayed pain hypersensitivity and neuronal hyperactivity in the ipsilesional STN and in central pain-processing nuclei. Optogenetic inhibition of STN neurons reversed pain hypersensitivity phenotypes in parkinsonian mice, while hyperactivity in the STN was sufficient to induce pain hypersensitivity in control mice. We further demonstrated that the STN differentially regulates thermal and mechanical pain thresholds through its projections to the substantia nigra pars reticulata (SNr) and the internal segment of the globus pallidus (GPi)/ventral pallidum (VP), respectively. Interestingly, optogenetic inhibition of STN-GPi/STN-VP and STN-SNr projections differentially elevated mechanical and thermal pain thresholds in parkinsonian mice. In summary, our results support the hypothesis that the STN and its divergent projections play critical roles in modulating pain processing under both physiological and parkinsonian conditions, and suggest that inhibition of individual STN projections may be a therapeutic strategy to relieve distinct pain phenotypes in PD.

Highly Oxidation-Resistant Electrolyte for 4.7†V Sodium Metal Batteries Enabled by Anion/Cation Solvation Engineering.

Sodium metal batteries (SMBs) are considered as promising battery system due to abundant Na sources. However, poor compatibility between electrolyte and cathode severely impedes its development. Herein, we proposed an anion/cation solvation strategy for realizing 4.7 V resistant SMBs electrolyte with NaClO4 and trimethoxy(pentafluorophenyl)silane (TPFS) as dual additives (DA). The ClO4 - can rapidly transfer to the cathode surface and strongly coordinate with Na+ to form stable polymer-like chains with solvents. Meanwhile, TPFS can preferentially enter into the PF6 - anion solvation sheath for reducing PF6 -solvent interaction and effectively scavenge adverse electrolyte species for protecting electrode electrolyte interphases. Thus, such electrolyte elevates the oxidative stability of carbonate electrolytes from 3.77 to 4.75 V, and enables Na||Na3 V2 (PO4 )2 O2 F (NVPF) battery with a capacity retention of 93 % and an average Coulombic efficiency (CE) of 99.6 % after 500 cycles at 4.7 V.

D2 receptor activation relieves pain hypersensitivity by inhibiting superficial dorsal horn neurons in parkinsonian mice.

Chronic pain is a common and undertreated nonmotor symptom in Parkinson's disease (PD). Although chronic pain is improved by L-dopa in some PD patients, the underlying mechanisms remain unclear. In this study, we established PD mice by unilateral microinjection of 6-OHDA in the medial forebrain bundle to investigate the contribution of spinal cord dopamine receptors to parkinsonian pain hypersensitivity. The von Frey filament tests and thermal pain tests revealed that these PD mice displayed decreased nociceptive thresholds in both hindpaws; intrathecal injection of L-dopa or apomorphine significantly increased the mechanical and thermal nociceptive thresholds, and the analgesic effect was mimicked by ropinirole (a D2 receptor agonist), but not SKF38393 (a D1/D5 receptor agonist), and blocked by sulpiride (a D2 receptor antagonist), but not SKF83566 (a D1/D5 receptor antagonist). Whole-cell recordings in lumber spinal cord slices showed that superficial dorsal horn (SDH) neurons in PD mice exhibited hyperexcitability, including more depolarized resting membrane potentials and more action potentials evoked by depolarizing current steps, which were mitigated by ropinirole. Furthermore, ropinirole inhibited the frequency of spontaneous excitatory postsynaptic currents (sEPSCs) in SDH neurons more strongly in PD mice than in control mice. However, sulpiride caused less disinhibition of sEPSCs in PD mice than in control mice. Taken together, our data reveal that pain hypersensitivity in PD mice is associated with hyperexcitability of SDH neurons, and both events are reversed by activation of spinal D2 receptors. Therefore, spinal D2 receptors can be promising therapeutic targets for the treatment of PD pain.

Achromatic metasurface doublet with a wide incident angle for light focusing.

Benefiting from the excellent capabilities of arbitrarily controlling the phase, amplitude and polarization of the electromagnetic wave, metasurfaces have attracted much attention and brought forward the revolution of fields ranging from device fabrications to optical applications. Cascaded metasurfaces have been demonstrated to correct the monochromatic aberration and enable a near-diffraction-limited focusing spot over a wide incident angle. However, they can only work under the design wavelength and suffer from the axial chromatic aberration at another wavelength. Here, an achromatic metasurface doublet is proposed to eliminate the axial achromatic aberration and enable high-quality focusing with a wide incident angle at distinct wavelengths. It consists of square nanopillar arrays with spatially varying width to simultaneously realize wavelength-dependent phase controls. The constructed metasurface doublet is further verified numerically and near-diffraction-limited foci are exactly formed at the same plane with an incident angle up to 20° for design wavelengths. We expect that our proposed approach can find optical applications in the fields of holograms, photograms, microscopy and machine vision.

Achromatic super-oscillatory metasurface through optimized multiwavelength functions for sub-diffraction focusing.

Optical super-oscillatory lenses based on planar micro/nano structures have been demonstrated as promising alternatives for shaping wavefronts of light and realizing super-resolution images in a NA-limited optical system. However, as the super-oscillatory foci originated from the delicate interference of the light, the change of the parameters might destroy the hotspots, such as the incident wavelength. Here, a multiwavelength achromatic super-oscillatory metasurface (ASOM) is proposed through simultaneously controlling distinct wavelength-dependent wavefronts. The constructed multiwavelength ASOM is then verified numerically, and the foci are precisely formed at the same axial plane for the design wavelengths with resolution beyond the diffraction limit. We expect that our proposed multiwavelength controllable method will give more freedom for the designs of planar and lightweight components, which would be useful in optical applications, such as data storage, super-resolution imaging, holography, etc.

Liquid crystal bifocal lens with adjustable intensities through polarization controls.

In this Letter, transverse and longitudinal liquid crystal bifocal lenses (LCBLs) are proposed to continuously control the relative intensity of two foci through a simple polarization control. The modulation of a LCBL comes from the geometric phase control and is designed through the principle of holography, where the object wave is a light field from two foci respectively formed by the left-circular polarized (LCP) and right-circular polarized (RCP) light, and the reference wave is the incident plane wave. Constructed millimeter-scale LCBLs are verified experimentally, and the foci are precisely formed at the preset plane. Besides, the relative intensity can be easily controlled with different weights of LCP and RCP light. The proposed strategy overcomes the shortcomings of previous bifocal lenses, such as a complex design method, a long optimization time, and an unchangeable relative intensity, and it is expected to find potential applications in parallel optical processing and optical interconnections.

Visible achromatic super-oscillatory metasurfaces for sub-diffraction focusing.

Conventional optical lenses enable precise foci but suffer from the diffraction limit due to the cutoff of spatial frequencies. Development of a super-oscillatory phenomenon offers an alternative approach to realize far-field sub-diffraction focusing. However, most super-oscillatory lenses exhibit a strong dependence on incident wavelengths, resulting in a narrow-band working frequency due to a fragile super-oscillatory field. Here, for the first time, achromatic super-oscillatory metasurfaces (ASOMs) are proposed to simultaneously steer optical fields at visible wavelengths of 473 nm, 532 nm and 632.8 nm and to achieve focusing at the same axial position with a resolution beyond the diffraction limit. These metasurface-based devices provide dispersionless phase profiles so that the material dispersion can be neglected in the optimization process. In addition, the design strategy can effectively circumvent the axial chromatic aberration observed in previously demonstrated metasurfaces. Constructed ASOMs are further verified numerically and simulated results for one ASOM with spot sizes of 0.706, 0.722 and 0.750 times the diffraction limit at the preset plane are consistent with the designs. Furthermore, benefiting from flexible and arbitrary phase modulations of the metasurface, the proposed method gives more freedom for a design of a super-oscillatory field and enables a lightweight, low-cost and compact optical element to replace the bulky doublet/triplet lens in a conventional optical system.

Single-shot large field of view imaging with scattering media by spatial demultiplexing.

Benefiting from the memory effect (ME) for speckle intensity correlations, only one single-shot speckle pattern can be used for the high-quality recovery of objects. However, ME gives a restriction to the field of view (FOV) for imaging with scattering media. Objects beyond the ME region cannot be recovered and produce unwanted speckle patterns, which cause reduction in the speckle contrast and recovery quality. Nevertheless, all the spatial information from a large object is embedded in a single speckle image. Here, we extract the spatial information from these unavoidable speckle patterns and enlarge the FOV of the imaging system with scattering media. Regional point spreading functions, which are fixed and only need to be recorded once for all-time use, are employed to recover corresponding spatial regions of an object by deconvolution. Then, an automatic weighted averaging in an iterative process is performed to obtain the object with significantly enlarged FOV. Our results present an important advancement of imaging techniques with strongly scattering media.

A super-oscillatory step-zoom metalens for visible light.

In recent years, the super-oscillation method based on the fine interference of optical fields has been successfully applied to sub-diffraction focusing and super-resolution imaging. However, most previously reported works only describe static super-oscillatory lenses. Super-oscillatory lenses using phase-change materials still have issues regarding dynamic tunability and inflexibility. Therefore, it is vital to develop a flexible and tunable modulation approach for super-oscillatory lenses. In this paper, we propose a super-oscillatory step-zoom lens based on the geometric phase principle, which can switch between two focal lengths within a certain field of view. The designed device consists of nanopillars with high efficiency of up to 80%, and the super-resolution focusing with 0.84 times of diffraction limit is verified by the full-wave simulation. The proposed method bears the potential to become a useful tool for label-free super-resolution microscopic imaging and optical precision machining.

Reflective Quasi-Continuous Metasurface with Continuous Phase Control for Light Focusing.

Benefitting from the arbitrary and flexible light modulation, metasurface has attracted extensive attention and been demonstrated in different applications. However, most reported metasurface-based devices were normally composed of discrete micro or nano structures, therefore the discretization precision limited the performance of the device, including the focusing efficiency, stray light suppression, and broadband performance. In this work, an all-metallic reflective metasurface consisting of numerous quasi-continuous nanostructures is proposed to realize high-efficiency and broadband focusing. The constructed quasi-continuous metasurface (QCMS) is then verified numerically through electromagnetic simulation, and the numerical results show a higher focusing efficiency and a better stray light suppression effect, compared to a binary-phase-based metalens. Through the same design strategy, a QCMS with the ability to overcome the diffraction limit can also be constructed, and a focal spot with the size of 0.8 times the diffraction limit can be achieved. We expect that this quasi-continuous structure could be utilized to construct other high-performance devices that require continuous phase controls, such as the beam deflector, orbital angle momentum generator, and self-accelerating beam generator.

Internal States Influence the Representation and Modulation of Food Intake by Subthalamic Neurons.

Deep brain stimulation of the subthalamic nucleus (STN) is an effective therapy for motor deficits in Parkinson's disease (PD), but commonly causes weight gain in late-phase PD patients probably by increasing feeding motivation. It is unclear how STN neurons represent and modulate feeding behavior in different internal states. In the present study, we found that feeding caused a robust activation of STN neurons in mice (GCaMP6 signal increased by 48.4% ± 7.2%, n = 9, P = 0.0003), and the extent varied with the size, valence, and palatability of food, but not with the repetition of feeding. Interestingly, energy deprivation increased the spontaneous firing rate (8.5 ± 1.5 Hz, n = 17, versus 4.7 ± 0.7 Hz, n = 18, P = 0.03) and the depolarization-induced spikes in STN neurons, as well as enhanced the STN responses to feeding. Optogenetic experiments revealed that stimulation and inhibition of STN neurons respectively reduced (by 11% ± 6%, n = 6, P = 0.02) and enhanced (by 36% ± 15%, n = 7, P = 0.03) food intake only in the dark phase. In conclusion, our results support the hypothesis that STN neurons are activated by feeding behavior, depending on energy homeostatic status and the palatability of food, and modulation of these neurons is sufficient to regulate food intake.

Polarization-insensitive colorful meta-holography employing anisotropic nanostructures.

Benefiting from advances in nanofabrication technology, emerging metasurfaces are promising for compact and wearable multicolor meta-holograms with large fields of view. However, due to the inherent electromagnetic properties of the structures that are used, current multicolor meta-holograms are often sensitive to the incident light polarization, which greatly restricts the application of meta-holography. Here, we took advantage of the amplitude properties of metasurfaces and the off-axis illumination method to carry out experiments involving polarization-insensitive colorful meta-holography with anisotropic nanostructures. With red, green and blue lasers illuminating the meta-hologram along different angles, a polarization-insensitive colorful holographic image was achieved and the disturbance from zero-order diffraction light was essentially eliminated. To the best of our knowledge, the current work was the first time that a polarization-insensitive colorful meta-hologram with anisotropic nanostructures was experimentally demonstrated. We expect our approach to provide promising prospects for the use of metasurfaces in applications such as flat meta-lenses, data storage and virtual/augmented reality.

Enhancing security of incoherent optical cryptosystem by a simple position-multiplexing technique and ultra-broadband illumination.

A position-multiplexing technique with ultra-broadband illumination is proposed to enhance the information security of an incoherent optical cryptosystem. This simplified optical encryption system only contains one diffuser acting as the random phase mask (RPM). Incoherent light coming from a plaintext passes through this nature RPM and generates the corresponding ciphertext on a camera. The proposed system effectively reduces problems of critical alignment sensitivity and coherent noise that are found in the coherent illumination. Here, the use of ultra-broadband illumination has the advantage of reducing the speckle contrast that makes the ciphertext more complex. Reduction of the ciphertext size further increases the strength of the ciphering. Using the spatial decorrelation of the speckle pattern we have demonstrated a position multiplexed based cryptosystem, where the ciphertext is the superposition of uniquely encrypted texts from various spatial positions. These unique spatial keys are utilized to decrypt the plaintext located at different spatial positions, and a complete decrypted text can be concatenated with high fidelity. Benefiting from position-multiplexing, the information of interest is scrambled together by a truly random method in a smaller ciphertext. A high performance security for an optical cryptosystem has been achieved in a simple setup with a ground glass diffuser as a nature RPM, the broadband incoherent illumination and small position-multiplexed ciphertext.

Super-resolution optical telescopes with local light diffraction shrinkage.

Suffering from giant size of objective lenses and infeasible manipulations of distant targets, telescopes could not seek helps from present super-resolution imaging, such as scanning near-field optical microscopy, perfect lens and stimulated emission depletion microscopy. In this paper, local light diffraction shrinkage associated with optical super-oscillatory phenomenon is proposed for real-time and optically restoring super-resolution imaging information in a telescope system. It is found that fine target features concealed in diffraction-limited optical images of a telescope could be observed in a small local field of view, benefiting from a relayed metasurface-based super-oscillatory imaging optics in which some local Fourier components beyond the cut-off frequency of telescope could be restored. As experimental examples, a minimal resolution to 0.55 of Rayleigh criterion is obtained, and imaging complex targets and large targets by superimposing multiple local fields of views are demonstrated as well. This investigation provides an access for real-time, incoherent and super-resolution telescopes without the manipulation of distant targets. More importantly, it gives counterintuitive evidence to the common knowledge that relayed optics could not deliver more imaging details than objective systems.