Speed Measurement of the Moving Targets Using the Stepping Equivalent Range-Gate Method.

In this paper, we proposed a stepping equivalent range-gate method (S-ERG method) to measure the speed and the distance of the moving target for range-gated imaging lidar. In this method, the speed is obtained by recording the time at which the moving target passes the front and back edges of the range gate, the distance information can also be obtained by the front and back edges of the range gate at the same time. To verify the feasibility of this method, a stationary target and a moving target with different speeds were measured by the S-ERG method. By using the S-ERG method, we not only obtained the distance information of the stationary target and the moving target at the front and back edges of the range gate, respectively, but also obtained the speed of the moving target. Compared to speeds measured by rotational displacement sensors, the speed measurement error of the S-ERG method is less than 5%, whether the target is far away or close to the range-gated lidar system, and this method is almost independent of the delay step time. The theoretical analysis and experimental results indicate range-gated imaging lidar using the S-ERG method has high practicality and wide applications.

Research on Small-Scale Detection Instrument for Drinking Water Combined Laser Spectroscopy and Conductivity Technology.

In order to realize rapid and accurate evaluation of drinking water quality, a small-scale water quality detection instrument is designed in this paper that can detect two representative water quality parameters: the permanganate index and total dissolved solids (TDS). The permanganate index measured by the laser spectroscopy method can achieve the approximate value of the organic matter in water, and the TDS measured by the conductivity method can obtain the approximate value of the inorganic matter in water. In addition, to facilitate the popularization of civilian applications, the evaluation method of water quality based on the percent-scores proposed by us is presented in this paper. The water quality results can be displayed on the instrument screen. In the experiment, we measured the water quality parameters of the tap water as well as those after the primary and secondary filtration in Weihai City, Shandong Province, China. The testing results show that the instrument can quickly detect dissolved inorganic and organic matter, and intuitively display the water quality evaluation score on the screen. The instrument designed in this paper has the advantages of high sensitivity, high integration, and small volume, which lays the foundation for the popularity of the detection instrument.

Optically pumped gas terahertz fiber laser based on gold-coated quartz hollow-core fiber.

An optically pumped gas terahertz fiber laser based on gold-coated quartz hollow-core fiber is demonstrated. When the terahertz fiber laser is filled with methanol gas and pumped by a piezoelectric-ceramic-transducer-adjusted transversely excited atmospheric pressure carbon dioxide laser, a continuous 2.52 THz laser with the output power of 110 mW is obtained. Attributed to the adjustment of the piezoelectric ceramic transducer in the carbon dioxide laser, the fluctuation of the terahertz fiber laser output power is controlled within ±5%. The result confirms the possibility of a compact flexible optically pumped gas terahertz fiber laser.

[Nonlinear Regression Methods of Ethanol Raman Spectra Quantitative Analysis].

Ethanol concentration quantitative analysis of ethanol-water solution can be realized by measuring the ratio of Raman characteristic peak heights. The content of ethanol can be determined by linear relation between relative intensity ratio and ethanol concentration. However, this analytical method only applies to the ethanol solution at low concentration. Concerning this issue, relative intensity of characteristic peak of ethanol (asymmetric stretching vibration of CH2 2 924.0 cm-1) and peak background of water (3 350 cm-1) at different ethanol concentration is experimentally measured by using a self-developed laser Raman ethanol content detection system. According to the relationship between relative ratio of characteristic peak heights and ethanol concentration, the nonlinear regression analysis methods are proposed to apply in the measurement of ethanol concentration in a wide range. Adjacent region average method is utilized to remove mutational random noise in Raman spectra of ethanol solution. Combined with multi-point interpolation processing, the baseline of Raman spectra can be calibrated. The influences of mutational random noise and the strong fluorescence background can be effectively eliminated with baseline correction and normalization methods. Polynomial and exponential mathematical models are adopted for nonlinear regression analyses by the relation between ratio of characteristic peak heights and concentration of ethanol solution. The analysis results show that the correlation coefficient of linear fitting and nonlinear fitting is about 0.991 and higher than 0.997 respectively. The linear analytical method can be effectively applied when ethanol concentration range is 15%～60%. The nonlinear analytical method has higher measurement accuracy in a wider ethanol concentration range of 3%～97%. Nonlinear mathematical model will provide theoretical basis for analysis of ethanol concentration, which can be applied in laser Raman ethanol content detection system to calculate the relatively accurate ethanol concentration of ethanol-water solution. Rapid, real-time and accurate quantitative analysis of wide concentration range ethanol solution, which has mutational random noise and strong fluorescence background interference, can be achieved by these analytical methods.

Theoretical and experimental investigations on measuring underwater temperature by the coherent Brillouin scattering method.

In this paper, a new method of measuring a water-stimulated Brillouin scattering (SBS) frequency shift by optical coherent detection is presented, in order to remote-sense the underwater temperature of the ocean. A single longitudinal mode, passively Q-switched pulsed Nd:YAG laser is used as the light source, the water SBS beam is used as the signal beam, and a portion of the incident laser beam is used as the local oscillator. The heterodyne is detected by a high-speed photodetector, and the heterodyne frequency is the Brillouin frequency shift. Therefore, the underwater temperature can be determined according to the relationship between the Brillouin frequency shift and the water temperature. To test and verify its practicability, the heterodyne waveforms at different water temperatures are recorded in the laboratory with a wide-band oscilloscope, and the Brillouin frequency shifts are deduced by a Fourier transform. The experimental results are consistent with the theoretical analysis. This work provides the foundation for the development of a water temperature measurement system based on coherent Brillouin scattering.

General fabrication of ordered nanocone arrays by one-step selective plasma etching.

One-step selective direct current (DC) plasma etching technology is employed to fabricate large-area well-aligned nanocone arrays on various functional materials including semiconductor, insulator and metal. The cones have nanoscale apexes (∼2 nm) with high aspect ratios, which were achieved by a selective plasma etching process using only CH4 and H2 in a bias-assisted hot filament chemical vapor deposition (HFCVD) system without any masked process. The CH(3)(+) ions play a major role to etch the roughened surface into a conical structure under the auxiliary of H(+) ions. Randomly formed nano-carbon may act as an original mask on the smooth surface to initiate the following selective ions sputtering. Physical impinging of energetic ions onto the concave regions is predominant in comparison with the etching of convex parts on the surface, which is identified as the key mechanism for the formation of conical nanostructures. This one-step maskless plasma etching technology enables the universal formation of uniform nanocone structures on versatile substrates for many promising applications.

Study of frequency stabilization for electro-optical Q-switched radio-frequency-excited waveguide CO2 laser using build-up time method.

An electro-optical Q-switched RF-excited Z-fold CO(2) waveguide laser was designed, which can output a Q-switched laser and a cavity-dumped laser synchronously. The build-up time method is presented to stabilize the laser frequency. A closed-loop control system was designed to keep the laser oscillating at the peak of the gain curve by measuring the pulse build-up time continuously and controlling the cavity length. In the experiment, the variations for the pulse build-up time and cavity-dumped laser output power with time were recorded in a period of time. The frequency fluctuation is less than ±16 MHz.

Theoretical investigation on the photophysical properties of N-heterocyclic carbene iridium (III) complexes (fpmb)(x)Ir(bptz)(3-x) (x = 1-2).

In the search for efficiently phosphorescent materials, this article presents a rational design and theoretical comparative study of some photophysical properties in the (fpmb)(x)Ir(bptz)(3-x) (x = 1-2), which involve the usage of two 2-pyridyl triazolate (bptz) chromophores and a strong-field ligand fpmb (fpmb = 1-(4-difluorobenzyl)-3-methylbenzimidazolium). The first principle theoretical analysis under the framework of the time-dependent density functional theory approach is implemented in this article to investigate the electronic structures, absorption and phosphorescence spectra. It is intriguing to note that 1 and 2 exhibit theirs blue phosphorescent emissions with maxima at 504 and 516 nm, respectively. Furthermore, to obtain the mechanism of low phosphorescence yield in 1 and estimate the radiative rate constant k(r) for 2, we approximately measure the radiative rate constant k(r), the spin-orbital coupling (SOC) value, ΔE (S - T), and the square of the SOC matrix element (<Ψ(S1·)H(SO·)Ψ(T1)>(2)) for 1 and 2. Finally, we tentatively come to conclusion that the switch of the cyclometalated ligand from the main to ancillary chelate seems to lower the splitting ΔE (S - T) in the current system.

Active and passive frequency stabilization for a Q-switched Z-fold radio-frequency-excited waveguide CO2 laser with two channels.

We report on passive offset frequency stability in free-running applications and active offset frequency stability achieved by use of a frequency-locking technique for a Q-switched Z-fold rf-excited waveguide CO2 laser with two channels. The laser structure of common electrodes and two channels has the advantage of compensating for the frequency variation caused by variations in temperature, cavity length, gas refractive index, and mechanical vibrations, so its offset frequency stability is higher than that of two separate lasers. In the experiments, the offset frequency shift was less than 6 MHz for 3 min in free-running mode. The technique of active offset frequency locking by counting was also introduced. The beat frequency shifting value was smaller than +/- 0.5 MHz in the long-term.