RESUMEN
Using nanoparticle surfactants to stabilize the liquid-liquid interface has attracted significant attention for developing all-liquid constructs including emulsions and liquid devices. Here, an efficient strategy is demonstrated to stabilize complex emulsions that consist of multiphase droplets by using the co-assembly between the cellulose nanocrystal and amine-functionalized polystyrene. Cellulose nanocrystal surfactants (CNCSs) form and assembly in situ at the specified area of emulsion interface, showing a unique pH responsiveness due to their dynamic nature and allowing the reconfiguration of complex emulsion from encapsulated to Janus structures. Such complex emulsions can be further used as the templates to fabricate polymeric particles with hollow, semi-spherical, and spherical shapes on large scale. These findings establish a promising platform for designing intelligent soft matter that can be used in microreactors, sensors, and anisotropic materials.
RESUMEN
Nanoparticle surfactants have been widely used to construct structured liquids in oil-water systems. Less attention, though, has been given in non-aqueous systems, for example, oil-oil systems, mainly due to the lack of suitable surfactants. Here, by using newly developed molecular brush surfactants (MBSs) that form at the DMSO-silicone oil interface, the construction of all-oil microfluidic devices is reported with advanced functions. Due to the high interfacial activity of MBSs, Plateau-Rayleigh instabilities of liquid jets can be completely suppressed, leading to the production of liquid threads with jammed MBSs at the interface. Taking advantage of the 3D printing technique, all-oil microfluidic devices with complex structures can be constructed, showing promising applications in mass transmission, chemical separation, and material synthesis.
RESUMEN
Cation-π and charge-transfer (CT) interactions are pervasive with significant implications in the fields of chemistry, materials science, and biology. However, much less is known about the construction of interfacial assemblies based on the two interactions. Here, by combining cation-π and CT interactions between an acceptor molecule, dicationic naphthalenediimide, and an aromatic donor, pyrene-terminated poly-l-lactic acid, we report the generation of supramolecular complex surfactants (SCSs) in situ at the toluene-water interface. The utilization of SCSs as building blocks enables the fabrication of interfacial assemblies including 2D films, emulsions, and structured liquids. By modification of the redox state of the acceptor molecules under chemical stimulus, the association/assembly and dissociation/disassembly of SCSs can be precisely regulated, imparting intriguing redox-responsive properties to the resulting assemblies.
RESUMEN
Welding of thermoplastics is a common practice in many industrial sectors, but it has yet to be realized with fluids. Here, the thermal welding of liquids by using the assembly and jamming of nanoparticle surfactants (NPSs) at liquid-liquid interfaces is reported. By fine-tuning the dynamic interaction strength within NPSs, the interfacial activity of NPSs, as well as the binding energy of NPSs to the interface can be precisely controlled, leading to a dynamic exchange of NPSs, maximizing the reduction in the interfacial energy. With NPSs jammed at the interface, the structures of liquids can be manipulated to complex geometries by applying an external force and, due to the temperature responsiveness of NPSs, when bringing liquids into contact and heating the system, welding of liquids can be achieved. This work provides a straightforward strategy for the construction of modular all-liquid fluidics, opening up numerous opportunities in fields like biotechnology, healthcare, and materials science.