RESUMEN
The power conversion efficiency (PCE) of polymer solar cells (PSCs) has recently reached >19% through the development of photoactive materials, particularly non-fullerene acceptors. Interfacial layers (ILs) have been another essential factor in optimizing device charge extraction. In this study, we propose a series of ILs, in which ionic iridium(III) (Ir(III)) complexes of different alkali metal cations (Li+, Na+, and K+) enhance the charge collection efficiency between zinc oxide and active layers through an induced internal electric field. The anionic coordinate sphere and counter-cations of the Ir(III) complexes are distributed according to the operating voltage of the PSCs, causing electric dipoles that enhance the internal electric field and charge collection efficiency. Ion species migration in the ILs is confirmed using electrochemical impedance spectroscopy. The PCE of the PM6:Y6-based PSCs was improved from 14.0% to 15.6% by introducing an IL (Ir-K+). Furthermore, the stability of PSCs containing ionic Ir(III) complexes is enhanced significantly under ultraviolet (UV) light and AM 1.5 G one-sun irradiation owing to the intense UV absorption capacity and photo durability of the ILs. A device containing the Ir(III) complex-based ILs retained â¼60% of its initial PCE after UV irradiation, whereas the control device retained only â¼20%.
RESUMEN
In conventional fullerene-based organic photovoltaics (OPVs), in which the excited electrons from the donor are transferred to the acceptor, the electron charge transfer state (eECT) that electrons pass through has a great influence on the device's performance. In a bulk-heterojunction (BHJ) system based on a low bandgap non-fullerene acceptor (NFA), however, a hole charge transfer state (hECT) from the acceptor to the donor has a greater influence on the device's performance. The accurate determination of hECT is essential for achieving further enhancement in the performance of non-fullerene organic solar cells. However, the discovery of a method to determine the exact hECT remains an open challenge. Here, we suggest a simple method to determine the exact hECT level via deconvolution of the EL spectrum of the BHJ blend (ELB). To generalize, we have applied our ELB deconvolution method to nine different BHJ systems consisting of the combination of three donor polymers (PM6, PBDTTPD-HT, PTB7-Th) and three NFAs (Y6, IDIC, IEICO-4F). Under the conditions that (i) absorption of the donor and acceptor are separated sufficiently, and (ii) the onset part of the external quantum efficiency (EQE) is formed solely by the contribution of the acceptor only, ELB can be deconvoluted into the contribution of the singlet recombination of the acceptor and the radiative recombination via hECT. Through the deconvolution of ELB, we have clearly decided which part of the broad ELB spectrum should be used to apply the Marcus theory. Accurate determination of hECT is expected to be of great help in fine-tuning the energy level of donor polymers and NFAs by understanding the charge transfer mechanism clearly.
RESUMEN
A charge transport layer based on transition metal-oxides prepared by an anhydrous sol-gel method normally requires high-temperature annealing to achieve the desired quality. Although annealing is not a difficult process in the laboratory, it is definitely not a simple process in mass production, such as roll-to-roll, because of the inevitable long cooling step that follows. Therefore, the development of an annealing-free solution-processable metal-oxide is essential for the large-scale commercialization. In this work, a room-temperature processable annealing-free "aqueous" MoO x solution is developed and applied in non-fullerene PBDB-T-2F:Y6 solar cells. By adjusting the concentration of water in the sol-gel route, an annealing-free MoO x with excellent electrical properties is successfully developed. The PBDB-T-2F:Y6 solar cell with the general MoO x prepared by the anhydrous sol-gel method shows a low efficiency of 7.7% without annealing. If this anhydrous MoO x is annealed at 200 °C, the efficiency is recovered to 17.1%, which is a normal value typically observed in conventional structure PBDB-T-2F:Y6 solar cells. However, without any annealing process, the solar cell with aqueous MoO x exhibits comparable performance of 17.0%. In addition, the solar cell with annealing-free aqueous MoO x exhibits better performance and stability without high-temperature annealing compared to the solar cells with PEDOT:PSS.
RESUMEN
Porphyrin derivatives have recently emerged as hole transport layers (HTLs) because of their electron-rich characteristics. Although several successes with porphyrin-based HTLs have been recently reported, achieving excellent solar cell performance, the chances to improve this further by molecular engineering are still open. In this work, Zn porphyrin (PZn)-based HTLs were developed by conjugating fluorinated triphenylamine (FTPA) wings at the perimeter of the PZn core for low-temperature perovskite solar cells (L-PSCs). The fluorinated PZn-HTLs (PZn-2FTPA and PZn-3FTPA) exhibited superior HTL properties compared to the nonfluorinated one (PZn-TPA). Moreover, their deeper highest occupied molecular orbital energy levels were beneficial for boosting open-circuit voltages, and their enhanced face-on stacking improved the hole transport properties. The L-PSC using PZn-2FTPA achieved the highest performance of 18.85%. Thus far, this result is one of the highest reported power conversion efficiencies among the PSCs using porphyrin-based HTLs.
RESUMEN
Although the combination of wide band gap polymer donors and narrow band gap small-molecule acceptors achieved state-of-the-art performance as bulk heterojunction (BHJ) active layers for organic solar cells, there have been only several of the wide band gap polymers that actually realized high-efficiency devices over >10%. Herein, we developed high-efficiency, low-energy-loss fullerene-free organic solar cells using a weakly crystalline wide band gap polymer donor, PBDTTPD-HT, and a nonfullerene small-molecule acceptor, ITIC. The excessive intermolecular stacking of ITIC is efficiently suppressed by the miscibility with PBDTTPD-HT, which led to a well-balanced nanomorphology in the PBDTTPD-HT/ITIC BHJ active films. The favorable optical, electronic, and energetic properties of PBDTTPD-HT with respect to ITIC achieved panchromatic photon-to-current conversion with a remarkably low energy loss (0.59 eV).