RESUMEN
The rapid development of the printing and dyeing industry has led to the production of a large amount of high-density printing and dyeing wastewater, and technology for its effective treatment has become a focus of research. To construct a polymeric adsorbent material with abundant functional groups for the efficient adsorption of dye wastewater, a novel magnetic sodium alginate/carboxymethylcellulose interpenetrating network gel sphere (Fe3O4@SA/CMC-Fe) was prepared by co-blending sodium alginate (SA) and sodium carboxymethylcellulose (CMC) with Fe3O4; Fe3O4@SA/CMC-Fe was characterized by SEM-EDS, XRD, TGA, FT-IR, UV-Vis, VSM, BET-BJH and XPS. Static adsorption experiments showed that the optimal rates for adsorption of DV 51 and DR 23 from solutions with neutral pH values by Fe3O4@SA/CMC-Fe were up to 96 %, the adsorption process exhibited a Langmuir adsorption isotherm, and the dynamic adsorption process was accurately described by the pseudo-second-order kinetic model. A thermodynamic study showed that the adsorption reactions were all spontaneous exothermic reactions with increasing entropy. The mechanism for adsorption of the dyes by Fe3O4@SA/CMC-Fe involved hydrogen bonding, complexation and electrostatic adsorption. In summary, Fe3O4@SA/CMC-Fe is a green, simple, recyclable and highly efficient magnetic adsorbent that is expected to be widely used in treating dye wastewaters over a wide pH range.