Occurrence, partition behavior, source and ecological risk assessment of nitro-PAHs in the sediment and water of Taige Canal, China.

Nitrated polycyclic aromatic hydrocarbons (NPAHs) are widespread organic pollutants that possess carcinogenic and mutagenic properties, so they may pose a risk to the environment and human health. In this study, the concentrations of 15 NPAHs and 16 polycyclic aromatic hydrocarbons (PAHs) in 30 surface water samples and 26 sediment samples were measured in 2018 from the Taige Canal, one of the main rivers flowing into Taihu Lake, China. The total NPAH concentrations in water and sediment ranged from 14.7 to 235 ng/L and 22.9 to 96.5 ng/g dw, respectively. 9-nitrophenanthrene (nd-76.3 ng/L) was the dominant compound in surface water, while 2+3-nitrofluoranthene (1.73-18.1 ng/g dw) dominated in sediment. Among PAHs, concentration ranging from 1,097 to 2,981 ng/L and 1,089 to 4,489 ng/g dw in surface water and sediment, respectively. There was a strong positive correlation between the log octanol-water partition coefficient (Kow) and log sediment-water partition coefficient due to hydrophobic interaction. The fugacity fraction value increased with the decrease of log Kow, and chrysene was transferred from water into sediment. The residual NPAHs in surface water and sediment of the Taige Canal have partial correlation. Diesel engine and coal combustion emissions were probably the principal sources of NPAHs in surface water and sediment. The results of ecological risk assessment showed that some NPAHs in water (e.g, 1-nitropyrene and 6-nitrochrysene) and sediment (e.g., 2-nitrobiphenyl, 5-nitroacenaphthene, 9-nitrophenanthrene and 2+3-nitrofluoranthene) had moderate ecological risks, which should be of concern.

Occurrence of synthetic musks in the sediment-seawater system of the Yellow Sea and East China Sea during wet and dry seasons.

Synthetic musks are aroma compounds used worldwide as substitutes for natural musks, which have become ubiquitous pollutants in the environment. The land-based input and partition behavior of synthetic musks in sediments and seawater are important for understanding their fate in the marine environment. In this study, a total of 292 seawater and sediment samples from 146 sites of the Yellow Sea and East China Sea were collected during wet and dry seasons and used to determine four synthetic musks, tonalide, galaxolide, musk xylene and musk ketone. Only tonalide was detectable in 10.6% and 17.8% of seawater samples at a concentration range of 23.7-38.2 ng/L and 19.0-24.8 ng/L in wet season and dry season, respectively. In sediments, both galaxolide and tonalide were detectable, with a sum total synthetic musks concentration ranging from 1.4 to 36.6 ng/g dry weight (dw) in wet season and 1.0 to 14.1 ng/g dw in dry season. The concentration of tonalide in seawater was significantly higher in wet season than in dry season and the concentration of synthetic musks in sediments of some coastal areas also exhibited higher concentrations in wet season than in dry season. Fugacity analysis showed that tonalide in the Yellow Sea exhibited a trend of diffusion from sediment to seawater or a state of equilibrium, while no diffusion trend was observed in the East China Sea. The hazard quotient values for tonalide and galaxolide in sediment and seawater samples were lower than 0.1, indicating that they present a low ecological risk. This research provides novel insights that help understand the pollution status, diffusion behavior and ecological risk of synthetic musks in marine environments.

Microstructure and Mechanical Properties of a Medium-Mn Steel with 1.3 GPa-Strength and 40%-Ductility.

Steel designs with superior mechanical properties have been urgently needed in automotive industries to achieve energy conservation, increase safety, and decrease weight. In this study, the aging process is employed to enhance the yield strength (YS) by tailoring the distribution of V-rich precipitates and to improve ductility by producing high volume fractions of recrystallized ferrite in cold-rolled medium-Mn steel. A reliable method to acquire ultra-high strength (1.0-1.5 GPa), together with ductility (>40%), is proposed via utilizing non-recrystallized austenite and recrystallized ferrite. Similarly to conventional medium-Mn steels, the TRIP effect, along with the mild TWIP effect, is responsible for the main deformation mechanisms during tensile testing. However, the coupled influence of precipitation strengthening, grain refinement strengthening, and dislocation strengthening contributes to an increase in YS. The studied steel, aged at 650 °C for 5 h, demonstrates a YS of 1078 MPa, ultimate tensile strength (UTS) of 1438 MPa, and tensile elongation (TE) of 30%. The studied steel aged at 650 °C for 10 h shows a UTS of 1306 MPa and TE of 42%, resulting in the best product in terms of of UTS and TE, at 55 GPa·%. Such a value surpasses that of the previously reported medium-Mn steels containing equal mass fractions of various microalloying elements.

Bioleaching and removal of radiocesium in anaerobic digestion of biomass crops: Effect of crop type on partitioning of cesium.

Cultivation of biomass crops for energy production is a promising land-use for farmland abandoned owing to radionuclide fallout. However, radionuclides in soil are easily taken up in the crop. To understand phase partitioning of radiocesium Cs (RCs) during anaerobic digestion (AD) of crops, semi-continuous AD experiments were carried out using two types of RCs-contaminated crops. Analysis of fractionated digestate effluent revealed that AD of the crops released RCs into the water phase (up to 82 %), and the efficiency of RCs solubilization depended on crop biodegradability. Adsorption treatment for removal of RCs from the water phase of the digestate indicated a water-zeolite partition coefficient of 0.287 L/g. The efficiency of removal from the water phase was 90 % at an adsorbent dose of 30 g/L.