Characteristics and sources of peroxyacetyl nitrate (PAN) in the rural North China Plain: Results from 1-year continuous observations.

Peroxyacetyl nitrate (PAN) is an important photochemical pollutant in the troposphere, whereas long-term measurements are scarce in rural areas in North China Plain (NCP), resulting in unclear seasonal variations and sources of PAN in rural NCP. In this study, we conducted a 1-year observation of PAN during 2021-2022 at the rural NCP site. The average concentrations of PAN were 1.10, 0.75, 0.65, and 0.88 ppbv in spring, summer, autumn, and winter, respectively, with a 1-year average of 0.81 ± 0.60 ppbv. Calculations indicate that the loss of PAN through thermal decomposition in summer accounts for 43.2% of the total formed PAN, which is an important reason for the low concentration of PAN in summer. We speculate that since the correlation between PAN and O3 in winter is significantly lower than that in other seasons, the observed regional transport of PAN cannot be ignored in winter. Through budget analysis, regional transport accounted for 12.8% and 55.9% of the observed PAN on the spring and winter pollution days, respectively, which showed that regional transport played key roles during the photochemical pollution of the rural NCP in winter. The potential source contribution function revealed that the transported PAN mainly comes from southern Hebei in spring. In winter, the transported PAN was mainly from Langfang, Hengshui, and southern Beijing. Our findings may aid in understanding PAN variations in different seasons in rural areas and highlight the impact of regional transport on the PAN budget.

A CNN-SVR model for NO2 profile prediction based on MAX-DOAS observations: The influence of Chinese New Year overlapping the 2020 COVID-19 lockdown on vertical distributions of tropospheric NO2 in Nanjing, China.

In this study, a hybrid model, the convolutional neural network-support vector regression model, was adopted to achieve prediction of the NO2 profile in Nanjing from January 2019 to March 2021. Given the sudden decline in NO2 in February 2020, the contribution of the Coronavirus Disease-19 (COVID-19) lockdown, Chinese New Year (CNY), and meteorological conditions to the reduction of NO2 was evaluated. NO2 vertical column densities (VCDs) from January to March 2020 decreased by 59.05% and 32.81%, relative to the same period in 2019 and 2021, respectively. During the period of 2020 COVID-19, the average NO2 VCDs were 50.50% and 29.96% lower than those during the pre-lockdown and post-lockdown periods, respectively. The NO2 volume mixing ratios (VMRs) during the 2020 COVID-19 lockdown significantly decreased below 400 m. The NO2 VMRs under the different wind fields were significantly lower during the lockdown period than during the pre-lockdown period. This phenomenon could be attributed to the 2020 COVID-19 lockdown. The NO2 VMRs before and after the CNY were significantly lower in 2020 than in 2019 and 2021 in the same period, which further proves that the decrease in NO2 in February 2020 was attributed to the COVID-19 lockdown. Pollution source analysis of an NO2 pollution episode during the lockdown period showed that the polluted air mass in the Beijing-Tianjin-Hebei was transported southwards under the action of the north wind, and the subsequent unfavorable meteorological conditions (local wind speed of < 2.0 m/sec) resulted in the accumulation of pollutants.

Quantifying Concentrations and Emissions of Hexachlorobutadiene - A New Atmospheric Persistent Organic Pollutant in northern China.

Hexachlorobutadiene (HCBD) was listed as a new persistent organic pollutant for global regulation under Stockholm Convention in 2015, and there has been scarce information on its atmospheric concentrations, distributions, and emission sources. HCBD air samples were collected and analyzed to characterize concentrations and distributions at high elevation and urban sites as well as emission source locations in Northern China. We found ambient concentrations of HCBD in Northern China averaged at 34 ± 16 and 36 ± 28 pptv at urban sites in Jinan and Tai'an, respectively, and 31 ± 21 pptv at a high-elevation site Mount Tai. HCBD concentrations at the high elevation and urban sites were found to be affected by long-range transport under the influence of the East Asian monsoon climate. Over potential sources areas, we found concentrations of 76 ± 33 pptv in a mixed factory park, 59 ± 21 pptv in a rubber plant and 74 ± 8 pptv in a municipal solid waste (MSW) landfill area, which were all several times higher than in urban sites. The large concentration gradient across the various environments revealed strong emission sources of HCBD, especially over MSW landfill and Cl-compound production and application areas. An emission rate of 9.2 × 104 kg/yr and an oxidation rate of 32.9 kg/yr for HCBD were estimated for the mixed factory park. OH and Cl are much more active in reaction with HCBD than other oxidants in the atmosphere. Dry deposition and oxidation removed about 5.3% and 0.04%, respectively, of the emitted, suggesting that ∼95% of the emitted HCBD remaining in the atmosphere and could be transported for redistribution. Our findings revealed significant emission sources of HCBD in northern China, which was in turn affected by major sources in East-central China. The regional influence of HCBD pollution warrants serious concerns and points to the need to develop mitigation strategies.

Understanding the inter-city causality and regional transport of atmospheric PM2.5 pollution in winter in the Harbin-Changchun megalopolis in China: A perspective from local and regional.

Harbin-Changchun megalopolis (HCM) is the typical cold urban agglomeration in China, where PM2.5 pollution is still serious in winter against the backdrop of continuous improvement in annual air quality in China. To further understand interactions of atmospheric pollution among HCM cities, inter-city causality and regional transport of PM2.5 in the winter in the HCM were comprehensively investigated by using convergent cross mapping (CCM) and CMAQ-BFM methods. CCM analysis results suggest strong bidirectional causal relationships between cities in the HCM, and the causality during polluted episodes were significantly larger than that during clean period. In addition, the influence on local PM2.5 from the HCM western cities were larger than that from cities in the southeast. Inter-city and regional transport contributions results demonstrated that although local emission were the largest contributors among 14 sub-regions for most HCM cities, interactions among cities were strong. Regional transport (42.8%-77.4%) largely contributes to HCM cities' PM2.5 concentrations. Among three regions outside the HCM, NMG (including part of inner Mongolia and Baicheng city in Jilin, 9.1%) was the largest contributor to the PM2.5 concentration in the whole HCM, followed by JLS (including Liaoning Province, Tonghua and Baishan cities in Jilin province, 5.1%) and HLJ (including cities of Heihe, Yichun, Jiamusi, Hegang, Shuangyashan, Jixi, Qitaihe in the Heilongjiang province, 3.8%). Regional transport contribution to the most HCM cities increased significantly from excellent to heavily polluted days. Furthermore, close relationships between transport paths/intensity and wind direction/speed in studied region suggests that we can quantitatively guide the regional joint emergency prevention and control before and during heavily polluted events based on regional weather forecasts in the future.

Fine particulate pollution driven by nitrate in the moisture urban atmospheric environment in the Pearl River Delta region of south China.

To identify potential sources of fine particles (PM2.5, with aerodynamic diameter (Da) ≤ 2.5 µm) in urban Dongguan of south China, a comprehensive campaign was carried out in the whole 2019. Hourly PM2.5 and its dominant chemical components including organic carbon (OC), elemental carbon (EC), water-soluble inorganic ions (WSIIs) and thirteen elements were measured using online instruments. Gaseous pollutants including NH3, HNO3, NO2, NO and O3 and meteorological parameters were also synchronously measured. PM2.5 was dominated by carbonaceous aerosols in summer and by WSIIs in the other seasons. PM2.5 and its dominant chemical components mostly peaked around noon (10:00-14:00 LST). Furthermore, high PM2.5 levels during the daytime were closely related with the increased NO3- levels. The high mass concentrations of NO3- in urban Dongguan during the daytime were likely related with regional transport of NO3- from suburban Dongguan, which was originated from the reaction between NO2 and O3 under the moisture condition during the nighttime. Seven major source factors for PM2.5 including secondary sulfate, ship emission, traffic emission, secondary nitrate, industrial processes, soil dust and coal combustion were identified by positive matrix factorization (PMF) analysis, which contributed 26 ± 14%, 16 ± 16%, 16 ± 10%, 14 ± 11%, 12 ± 11%, 8 ± 6% and 8 ± 6%, respectively, to annual PM2.5 mass concentration. Although secondary sulfate contributed much more than secondary nitrate to PM2.5 on annual basis, the latter exceeded the former source factor when daily PM2.5 mass concentration was higher than 60 µg m-3, indicating the critical role nitrate played in PM2.5 episode events.

Contributions of local emissions and regional background to summertime ozone in central China.

Source contributions and regional transport of maximum daily average 8-h (MDA8) O3 during a high O3 month (June 2019) in Henan province in central China are explored using a source-oriented Community Multiscale Air Quality (CMAQ) model. The monthly average MDA8 O3 exceeds ∼70 ppb in more than half of the areas and shows a clear spatial gradient, with lower O3 concentrations in the southwest and higher in the northeast. Significant contributions of anthropogenic emissions to monthly average MDA8 O3 concentrations of more than 20 ppb are predicted in the provincial capital Zhengzhou, mostly due to emissions from the transportation sector (∼50%) and in the areas in the north and northeast regions where industrial and power generation-related emissions are high. Biogenic emissions in the region only contribute to approximately 1-3 ppb of monthly average MDA8 O3. In industrial areas north of the province, their contributions reach 5-7 ppb. Two CMAQ-based O3-NOx-VOCs sensitivity assessments (the local O3 sensitivity ratios based on the direct decoupled method and the production ratio of H2O2 to HNO3) and the satellite HCHO to NO2 column density ratio consistently show that most of the areas in Henan are in NOx-limited regime. In contrast, the high O3 concentration areas in the north and at the city centers are in the VOC-limited or transition regimes. The results from this study suggest that although reducing NOx emissions to reduce O3 pollution in the region is desired in most areas, VOC reductions must be applied to urban and industrial regions. Source apportionment simulations with and without Henan anthropogenic emissions show that the benefit of local anthropogenic NOx reduction might be lower than expected from the source apportionment results because the contributions of Henan background O3 increase in response to the reduced local anthropogenic emissions due to less NO titration. Thus, collaborative O3 controls in neighboring provinces are needed to reduce O3 pollution problems in Henan effectively.

Impacts of synoptic circulation on surface ozone pollution in a coastal eco-city in Southeastern China during 2014-2019.

The coastal eco-city of Fuzhou in Southeastern China has experienced severe ozone (O3) episodes at times in recent years. In this study, three typical synoptic circulations types (CTs) that influenced more than 80% of O3 polluted days in Fuzhou during 2014-2019 were identified using a subjective approach. The characteristics of meteorological conditions linked to photochemical formation and transport of O3 under the three CTs were summarized. Comprehensive Air Quality Model with extensions was applied to simulate O3 episodes and to quantify O3 sources from different regions in Fuzhou. When Fuzhou was located to the west of a high-pressure system (classified as "East-ridge"), more warm southwesterly currents flowed to Fuzhou, and the effects of cross-regional transport from Guangdong province and high local production promoted the occurrence of O3 episodes. Under a uniform pressure field with a low-pressure system occurring to the east of Fuzhou (defined as "East-low"), stagnant weather conditions caused the strongest local production of O3 in the atmospheric boundary layer. Controlled by high-pressure systems over the mainland (categorized as "Inland-high"), northerly airflows enhanced the contribution of cross-regional transport to O3 in Fuzhou. The abnormal increases of the "East-ridge" and "Inland-high" were closely related to O3 pollution in Fuzhou in April and May 2018, resulting in the annual maximum number of O3 polluted days during recent years. Furthermore, the rising number of autumn O3 episodes in 2017-2019 was mainly related to the "Inland-high", indicating the aggravation of cross-regional transport and highlighting the necessity of enhanced regional collaboration and efforts in combating O3 pollution.

Modeling study on the roles of the deposition and transport of PM2.5 in air quality changes over central-eastern China.

The role of PM2.5 (particles with aerodynamic diameters ≤ 2.5 µm) deposition in air quality changes over China remains unclear. By using the three-year (2013, 2015, and 2017) simulation results of the WRF/CUACE v1.0 model from a previous work (Zhang et al., 2021), a non-linear relationship between the deposition of PM2.5 and anthropogenic emissions over central-eastern China in cold seasons as well as in different life stages of haze events was unraveled. PM2.5 deposition is spatially distributed differently from PM2.5 concentrations and anthropogenic emissions over China. The North China Plain (NCP) is typically characterized by higher anthropogenic emissions compared to southern China, such as the middle-low reaches of Yangtze River (MLYR), which includes parts of the Yangtze River Delta and the Midwest. However, PM2.5 deposition in the NCP is significantly lower than that in the MLYR region, suggesting that in addition to meteorology and emissions, lower deposition is another important factor in the increase in haze levels. Regional transport of pollution in central-eastern China acts as a moderator of pollution levels in different regions, for example by bringing pollution from the NCP to the MLYR region in cold seasons. It was found that in typical haze events the deposition flux of PM2.5 during the removal stages is substantially higher than that in accumulation stages, with most of the PM2.5 being transported southward and deposited to the MLYR and Sichuan Basin region, corresponding to a latitude range of about 24°N-31°N.

Chemical characteristics and regional transport of submicron particulate matter at a suburban site near Lanzhou, China.

Lanzhou, which is a valley city on the Loess Plateau, frequently suffered from aerosol pollution in recent years, especially in winter. However, the lack of understanding of factors governing aerosol pollution limits the implementation of effective emission policies in and around Lanzhou. To help solve this problem, an intensive field campaign was conducted at the SACOL site, which is a suburban site near Lanzhou, in winter 2018. The chemical characteristics and sources of submicron particulate matter (PM1) were investigated, and the influence of the topography around Lanzhou on aerosol pollution was examined. In the present study, the average PM1 mass concentration reached 25.6 ± 12.8 µg m-3, with 41.0% organics, 16.1% sulfate, 19.7% nitrate, 10.7% ammonium, 3.1% chloride, and 9.4% black carbon (BC). Three organic aerosol (OA) factors were identified with the positive matrix factorization (PMF) algorithm, including a biomass burning OA (BBOA, 13.6%), a coal combustion OA (CCOA, 34.2%), and an oxygenated OA (OOA, 52.2%). The significant relationships between organics, BC, and chloride and wind pattern suggested that the SACOL site was strongly influenced by regionally transported aerosols. Further analysis suggested that these aerosol regional transport events were caused by topography. Due to the limitation of the valley, aerosols accumulated in the valley. These accumulated aerosols were then transported to the SACOL site along the valley by prevailing winds. Our study highlights enhanced aerosol regional transport in valleys, which provides a new perspective for future studies on aerosol pollution in basins and valleys.

Contribution of local and surrounding area anthropogenic emissions to a high ozone episode in Zhengzhou, China.

This study analyzed an ozone pollution episode that occurred in the summer of 2020 in Zhengzhou, the provincial capital of Henan, China, and quantified the contribution of local and surrounding area anthropogenic emissions to this episode based on the Weather Research and Forecasting with Chemistry (WRF/Chem) model. Simulation results showed that the WRF/Chem model is well suited to simulate the ozone concentrations in this area. In addition, four simulation scenarios (removing the emissions from the northern Zhengzhou, southwestern Zhengzhou, Zhengzhou local and southeastern Zhengzhou) were conducted to explore the specific contributions of local emissions and emissions from surrounding areas within Henan to this ozone pollution episode. We found that contributions from the northern, local, southwestern, and southeastern regions were 6.1%, 5.9%, 1.7%, and 1.5%, respectively. The northern and local emissions of Zhengzhou (only emissions from Zhengzhou) were prominent contributors within the simulation areas. In other words, during this episode, most of the ozone pollution in Zhengzhou appeared to be transported in from regions outside Henan Province.

VOCs characteristics and their ozone and SOA formation potentials in autumn and winter at Weinan, China.

Frequent ozone and fine particulate matter (PM2.5) pollution have been occurring in the Guanzhong Plain in China. To effectively control the tropospheric ozone and PM2.5 pollution, this study performed measurements of 102 VOCs species from Sep.19-25 (autumn) and Nov.27-Dec. 8, 2017 (winter) at Weinan in the central Guanzhong Plain. The total volatile organic compounds (TVOCs) concentrations were 95.8 ± 30.6 ppbv in autumn and 74.4 ± 37.1 ppbv in winter. Alkanes were the most abundant group in both of autumn and winter, accounting for 33.5% and 39.6% of TVOCs concentrations, respectively. The levels of aromatics and oxygenated VOCs were higher in autumn than in winter, mainly due to changes in industrial activities and combustion strength. Photochemical reactivities and ozone formation potentials (OFPs) of VOCs were calculated by applying the OH radical loss rate (LOH) and maximum incremental reactivity (MIR) method, respectively. Results showed that Alkenes and aromatics were the key VOCs in term ozone formation in Weinan, which together contributed 59.6% ̶ 65.3% to the total LOH and OFP. Secondary organic aerosol formation potentials (SOAFP) of the measured VOCs were investigated by employing the fractional aerosol coefficient (FAC) method. Aromatics contributed 94.9% and 96.2% to the total SOAFP in autumn and winter, respectively. The regional transport effects on VOCs and ozone formation were investigated by using trajectory analysis and potential source contribution function (PSCF). Results showed that regional anthropogenic sources from industrial cities (Tongchuan, Xi'an city) and biogenic sources from Qinling Mountain influenced VOCs levels and OFP at Weinan. Future studies need to emphasize on meteorological factors and sources that impact on VOCs concentrations in Weinan.

Hourly organic tracers-based source apportionment of PM2.5 before and during the Covid-19 lockdown in suburban Shanghai, China: Insights into regional transport influences and response to urban emission reductions.

During the Covid-19 outbreak, strict lockdown measures led to notable reductions in transportation-related emissions and significantly altered atmospheric pollution characteristics in urban and suburban areas. In this work, we compare comprehensive online measurements of PM2.5 major components and organic molecular markers in a suburban location in Shanghai, China before lockdown (Dec. 28, 2019 to Jan. 23, 2020) and during lockdown (Jan. 24 to Feb. 9, 2020). The NOx levels declined sharply by 59% from 44 to 18 ppb during the lockdown, while O3 rose two times higher to 42 ppb. The PM2.5 level dropped from 64 to 49 µg m-3 (-24%). The major components all showed reductions, with the reduction of nitrate most prominent at -58%, followed by organics at -19%, and sulfate at -17%. Positive matrix factorization analysis identifies fourteen source factors, including nine primary sources and five secondary sources. The secondary sources consist of sulfate-rich factor, nitrate-rich factor, and three secondary organic aerosol (SOA) factors, with SOA_I being anthropogenic SOA, SOA_II associated with later generation products of organic oxidation, and SOA_III being biogenic SOA. The combined secondary sources contributed to 69% and 63% (40 and 22 µg m-3) of PM2.5 before and during lockdown, respectively, among which the reductions in the nitrate-rich (-55%) factor was the most prominent. Among primary sources, large reductions (>80%) were observed in contributions from industrial, cooking, and vehicle emissions. Unlike some studies reporting that the restriction during the Covid-19 resulted in enhanced secondary sulfate and SOA formation, we observed decreases in both secondary inorganic and SOA formation despite the overall elevated oxidizing capacity in the suburban site. Our results indicate that the formation change in secondary inorganic and organic compounds in response to substantial reductions in urban primary precursors are different for urban and suburban environments.

Identification of close relationship between large-scale circulation patterns and ozone-precursor sensitivity in the Pearl River Delta, China.

To curb the continuous deterioration of ozone (O3) pollution in China, identifying the O3-precursor sensitivity (OPS) and its driving factors is a prerequisite for formulating effective O3 pollution control measures. Traditional OPS identification methods have limitations in terms of spatiotemporal representation and timeliness; therefore, they are not appropriate for making OPS forecasts for O3 contingency control. OPS is not only influenced by local precursor emissions but is also closely related to meteorological conditions governed by large-scale circulation (LSC). In this study, a localized three-dimensional numerical modeling system was used to investigate the relationship between LSC and OPS in the Pearl River Delta (PRD) of China during September 2017, a month with continuous O3 pollution. Our results highlighted that there was a close relationship between LSC and OPS over the PRD, and the four dominant LSC patterns corresponded well to the NOx-limited, NOx-limited, VOC-limited, and transitional regimes, respectively. The clear linkage between LSC and OPS was mainly driven by the spatial heterogeneity of NOx and VOC emissions within and beyond the PRD along the prevailing winds under different LSC patterns. A conceptual model was developed to highlight the intrinsic causality between the LSC and OPS. Because current technology can accurately forecast LSC 48-72 h in advance, the LSC-based OPS forecast method provided us with a novel approach to guide contingency control and management measures to reduce peak O3 at a regional scale.

Distribution and transport characteristics of fine particulate matter in beijing with mobile lidar measurements from 2015 to 2018.

Accurately quantifying the concentration and transport flux of atmospheric fine particulate matter (PM2.5) is vital when attempting to thoroughly identify the pollution formation mechanism. In this study, the mobile lidar measurements in Beijing on heavily polluted days in December from 2015 to 2018 are presented. The lidar was mounted on a vehicle, which could perform measurements along designated routes. On the basis of mobile lidar measurements along closed circuits of the 6th Ring Road around Beijing, the spatial distribution and transport flux of PM2.5 in Beijing were determined with information of wind field. In the spatial distribution, both the concentration and transport of PM2.5 were revealed to be more significant in the southern section of Beijing. The regional transport layer at heights < 1.3 km plays an important role in pollution formation. The maximum transport flux reached 1600 µg/(m2*sec) on 11 December 2016. With the aerosol boundary layer height determined from the image edge detection (IED) method, the inter-annual variations of the aerosol boundary layer height (ABLH) were also analysed. The ABLH decreased from 0.73 to 0.46 km during the same heavy pollution period from 2015 to 2018. Increasingly adverse aerosol boundary layer (ABL) meteorological factors, including lower ABLH, light winds, temperature inversions, and accumulated moisture, have become necessary for pollution formation in Beijing.

Ambient volatile organic compounds at a receptor site in the Pearl River Delta region: Variations, source apportionment and effects on ozone formation.

We present the continuously measurements of volatile organic compounds (VOCs) at a receptor site (Wan Qing Sha, WQS) in the Pearl River Delta (PRD) region from September to November of 2017. The average mixing ratios of total VOCs (TVOCs) was 36.3 ± 27.9 ppbv with the dominant contribution from alkanes (55.5%), followed by aromatics (33.3%). The diurnal variation of TVOCs showed a strong photochemical consumption during daytime, resulting in the formation of ozone (O3). Five VOC sources were resolved by the positive matrix factorization (PMF) model, including solvent usage (28.6%), liquid petroleum gas (LPG) usage (24.4%), vehicle exhaust (21.0%), industrial emissions (13.2%) and gasoline evaporation (12.9%). The regional transport air masses from the upwind cities of south China can result in the elevated concentrations of TVOCs. Low ratios of TVOCs/NOx (1.53 ± 0.88) suggested that the O3 formation regime at WQS site was VOC-limited, which also confirmed by a photochemical box model with the master chemical mechanism (PBM-MCM). Furthermore, the observation on high-O3 episode days revealed that frequent O3 outbreaks at WQS were mainly caused by the regional transport of anthropogenic VOCs especially for aromatics and the subsequent photochemical reactions. This study provides valuable information for policymakers to propose the effective control strategies on photochemical pollution in a regional perspective.

Mitigated PM2.5 Changes by the Regional Transport During the COVID-19 Lockdown in Shanghai, China.

Intensive observations and WRF-Chem simulations are applied in this study to investigate the adverse impacts of regional transport on the PM2.5 (fine particulate matter; diameter ≤2.5 µm) changes in Shanghai during the Coronavirus Disease 2019 lockdown. As the local atmospheric oxidation capacity was observed to be generally weakened, strong regional transport carried by the frequent westerly winds is suggested to be the main driver of the unexpected pollution episodes, increasing the input of both primary and secondary aerosols. Contributing 40%-80% to the PM2.5, the transport contributed aerosols are simulated to exhibit less decreases (13.2%-21.8%) than the local particles (37.1%-64.8%) in urban Shanghai due to the lockdown, which largely results from the less decreased industrial and residential emissions in surrounding provinces. To reduce the influence of the transport, synergetic emission control, especially synergetic ammonia control, measures are proved to be effective strategies, which need to be considered in future regulations.

Characteristic analysis of continuous new particle formation events in Hefei: A case study of the May Day holiday in China.

Studying the characteristics of new particle formation (NPF) is conducive to exploring the impact of atmospheric particulate matter on the climate, environment, and human health. The particle number size distributions (5.6-560 nm) of aerosols were measured using a fast mobility particle sizer (FMPS) from 1 to 11 May 2019. The clean atmosphere was one of the basic conditions for the occurrence of this continuous new particle formation events. It started between 9:00 and 12:00, and it mainly ended after 20:00. The growth rate (GR) and condensation sink (CS) values in Hefei were 2.98 ± 0.97 nm·h-1 and (3.0 ± 0.4) × 10-2 s-1, respectively. Back trajectory clustering analysis revealed that the mass concentration of the air masses from the southeastern part of Henan Province and the southern part of Anhui Province surrounding the study area were relatively high. The analysis results of the potential source contribution function (PSCF) and the concentration weighted trajectory (CWT) methods show that in addition to local pollution, the long-distance transport of pollutants in the Yangtze River Delta (YRD) greatly contributed to the accumulation modal particulate concentration in Hefei. Moreover, the population affected by PM2.5 during the observation period reached 8.19 × 104, accounting for 1.08% to the total population in Hefei. The premature death cases associated with PM2.5 reached 8.35 × 102. This study is helpful to understand the main influencing factors of consecutive NPF events and the health risks of fine particles.

Evaluation of regional transport of PM2.5 during severe atmospheric pollution episodes in the western Yangtze River Delta, China.

During winter 2018, the 16 prefecture-level cities in Anhui Province, Western Yangtze River Delta region, China had very high PM2.5 concentrations and prolonged pollution days. The impact of regional transport in the formation, accumulation, as well as dispersion of fine particulate matter (PM2.5) in Anhui Province was very significant. This study quantified and analyzed the vertical transport of PM2.5 in three major cities (Hefei, Fuyang, and Suzhou) of Anhui Province in January and July 2018 using the Weather Research and Forecasting (WRF) model coupled with the Community Multiscale Air Quality (CMAQ) model. The results of the inter-regional transport of PM2.5 revealed the dominant transport pathways for the three cities. The flux mainly flowed into Fuyang from Henan (2.23 and 1.42 kt/day in January and July, respectively) and Bozhou (1.96 and 1.21 kt/day in January and July, respectively), while the main flux from Fuyang flowed into Henan (-2.15 kt/day) and Lu'an (-1.91 kt/day) in January and Henan (-0.34 kt/day) and Bozhou (-0.29 kt/day) in July. In addition, the dominant transport pathways and the heights at which they occurred were identified: the northwest-southeast and northeast-south pathways in both winter and summer at both lower (˂300 m) and higher (≥300 m) levels for Fuyang; the northwest-south and northeast-southwest pathways in winter (at both lower and upper levels) and northwest-east and northeast-southwest pathways in summer at lower and upper levels for Hefei; and the northwest-southeast and northeast-south pathways in both winter (from 50 m up to the top level) and summer (between 100 and 300 m) for Suzhou. Furthermore, the intensities of daily PM2.5 transport fluxes in Fuyang during the atmospheric pollution episode (APE1) were stronger than the monthly average. These results show that joint emission controls across multiple cities along the identified pathways are urgently needed to reduce winter episodes.

Vertical distributions of tropospheric SO2 based on MAX-DOAS observations: Investigating the impacts of regional transport at different heights in the boundary layer.

Information on the vertical distribution of air pollutants is essential for understanding their spatiotemporal evolution underlying urban atmospheric environment. This paper presents the SO2 profiles based on ground-based Multi-Axis Differential Optical Absorption Spectroscopy (MAX-DOAS) measurements from March 2018 to February 2019 in Hefei, East China. SO2 decrease rapidly with increasing heights in the warm season, while lifted layers were observed in the cold season, indicating accumulation or long-range transport of SO2 in different seasons might occur at different heights. The diurnal variations of SO2 were roughly consistent for all four seasons, exhibiting the minimum at noon and higher values in the morning and late afternoon. Lifted layers of SO2 were observed in the morning for fall and winter, implying the accumulation or transport of SO2 in the morning mainly occurred at the top of the boundary layer. The bivariate polar plots showed that weighted SO2 concentrations in the lower altitude were weakly dependent on wind, but in the middle and upper altitudes, higher weighted SO2 concentrations were observed under conditions of middle-high wind speed. Concentration weighted trajectory (CWT) analysis suggested that potential sources of SO2 in spring and summer were local and transported mainly occurred in the lower altitude from southern and eastern areas; while in fall and winter, SO2 concentrations were deeply affected by long-range transport from northwestern and northern polluted regions in the middle and upper altitudes. Our findings provide new insight into the impacts of regional transport at different heights in the boundary layer on SO2 pollution.

Temporal and spatial characteristics of PM2.5 transport fluxes of typical inland and coastal cities in China.

Local pollution and the cross-boundary transmission of pollutants between cities have an inevitable impact on the atmosphere. Quantitative assessments of the contribution of transport to pollution in inland and coastal cities are necessary for the implementation of practical, regional, and joint emission control strategies. In this study, the Comprehensive Air Quality Model (CAMx), together with the Weather Research and Forecasting model (WRF), was used to simulate the contributions to pollution of different cities in 2016. The monthly inflow, outflow, and net flux from the ground to the extended layers served as the three main indicators for the analysis of the interactions of PM2.5 transport between adjacent cities. Between inland and coastal cities, the magnitude of inflow and outflow are larger in the former than in the latter. The inflow flux in the inland cities (Beijing and Shijiazhuang) was 10.6 and 10.7 kt/day, respectively, while that in the coastal cities (Tianjin, Shanghai, Hefei, Nanjing, and Hangzhou) was 9.1, 3.3, 5.8, 4.4, and 3.7 kt/day, respectively. In terms of variation over the year, the strongest inflow in the BTH region occurred in April, followed by October, July, and January, while that in the coastal cities in YRD occurred in January, followed by October, April, and July. Therefore, based on the flux intensity calculations and the transport flux pathways, effective joint control measures can be provided with scientific support, and a better understanding of the evolutionary mechanism among inland and coastal cities can be acquired.