Natural marmatite photocatalyst for treatment of mineral processing wastewater to help zero wastewater discharge.

Mineral processing wastewater (MPW) with large discharge and high toxicity affects environmental safety, and the realizing zero discharge of MPW is of great significance for reducing environmental pollution, saving water resources, and promoting the sustainable development of the mining industry. In this study, we reported natural marmatite (NM) as a low-cost and efficient photocatalyst for the treatment of MPW to help zero wastewater discharge. The photocatalytic activity of NM was evaluated by the removal of total organic carbon (TOC) from MPW under visible-light illumination, and the optimal degradation conditions were discussed. Results showed that superoxide free radicals (·O2-) were the dominant active species responsible for organic pollutants degradation, and 74.25% TOC removal was obtained after 120 min reaction under the optimum treatment conditions. Meanwhile, the wastewater treated by NM photocatalysis can be reused in the flotation system without adverse impact on the product index. Based on these findings, a model of zero wastewater discharge for flotation with the help of photocatalytic treatment was established, it indicated that the water of the whole system can be balanced without affecting the ore dressing index, which showed that visible light-driven photocatalyst has a promising application prospect in the treatment and recycling of industrial wastewater.

Out of Thin Air? Catalytic Oxidation of Trace Aqueous Aldehydes with Ambient Dissolved Oxygen.

Water reuse is expanding due to increased water scarcity. Water reuse facilities treat wastewater effluent to a very high purity level, typically resulting in a product water that is essentially deionized water, often containing less than 100 µg/L organic carbon. However, recent research has found that low-molecular-weight aldehydes, which are toxic electrophiles, comprise a significant fraction of the final organic carbon pool in recycled wastewater in certain treatment configurations. In this manuscript, we demonstrate oxidation of trace aqueous aldehydes to their corresponding acids using a heterogeneous catalyst (5% Pt on C), with ambient dissolved oxygen serving as the terminal electron acceptor. Mass balances are essentially quantitative across a range of aldehydes, and pseudo-first-order reaction kinetics are observed in batch reactors, with kobs varying from 0.6 h-1 for acetaldehyde to 4.6 h-1 for hexanal, while they are low for unsaturated aldehydes. Through kinetic and isotopic labeling experiments, we demonstrate that while oxygen is essential for the reaction to proceed, it is not involved in the rate-limiting step, and the reaction appears to proceed primarily through a base-promoted ß-hydride elimination mechanism from the hydrated gem-diol form of the corresponding aldehyde. This is the first report we are aware of that demonstrates useful abiotic oxidation of a trace organic contaminant using dissolved oxygen.

Treating and reusing wastewater generated by the washing operations in the non-hazardous plastic solid waste recycling process: Advanced method vs. conventional method.

The effectiveness of an advanced treatment of wastewater generated by non-hazardous plastic solid waste (PSW) washing, based on the Sequencing Batch Biofilter Granular Reactor (SBBGR), was assessed in terms of gross parameters, removal efficiencies and sludge production. The proposed treatment was also compared with the conventional treatment, which was based on primary and secondary treatments, using the activated sludge process, performed by Recuperi Pugliesi, a leading company in the plastic recycling industry located in Bari, Italy. The company produces low-density polyethylene (LDPE) regenerated granules from PSW used in agricultural and floricultural greenhouse activities and industrial packaging after a washing stage in the aqueous phase. The latter generates large volumes of wastewater, the conventional treatment of which is characterised by large quantities of sludge and the associated disposal problems. Under steady-state conditions, the SBBGR provided impressive removal efficiencies regarding the main gross parameters (over 90% for COD and TKN, over 99% for BOD5, TSS, VSS and NH3, and over 80% for TN) with a statistically better effluent quality than that of the conventional treatment. The SBBGR effluent quality was modelled in terms of washing water characteristics by using generalized additive models (GAMs). The SBBGR treatment was characterised by a specific sludge production five times lower than that of the conventional treatment (0.21 kg TSS vs. 1.0 kg TSS per m3 of wastewater treated). Compared with the conventional treatment, the proposed process showed a five-fold reduction in the cost of sludge disposal, which saved 50% of the operating cost.

A novel integrated single-stage anaerobic co-digestion and oxidation ditch-membrane bioreactor system for food waste management and building wastewater recycling.

This study is to develop a novel integrated single-stage anaerobic co-digestion and oxidation ditch membrane bioreactor (SAC/OD-MBR) for food waste and building wastewater recycling. The co-digestion of food waste (FW) from a canteen with waste sludge (WS) from OD-MBR was performed with the proportion of FW:WS at 10:1 by weight. The liquid digestate from the co-digestion process was further co-treated with building wastewater in the OD-MBR system for water reuse purpose. Maximum methane content of 65.2% in biogas as well as average specific methane yield of 0.24 gCH4/gVS could be obtained with anaerobic co-digestion of food waste and waste sludge from OD-MBR with HRT of 24 h and horizontal flow velocity of 0.3 m/s. The observed main methanogen species in this co-digestion process were Methanoculleus bourgensis and Methanoculleus palmolei. For co-treatment of liquid digestate and building wastewater with the OD-MBR, it was found that HRT of 24 h and horizontal flow velocity of 0.3 m/s could achieve highest COD and nitrogen removal efficiencies. HRT can be considered as a main key parameter to promote nitrification activity inside the OD-MBR system. Moreover, treated effluent from the SAC/OD-MBR could comply with the water reuse standard for garden and landscape application in the university campus. Furthermore, the techno-economic analysis indicates that this proposed system has a high potential of total cost savings and other indirect benefits. Therefore, the prototype SAC/OD-MBR can be an alternative system for food waste management and wastewater recycling for building application.

Estimation of the water cycle related to shale gas production under high data uncertainties: Dutch perspective.

The potential water demand for fracturing fluids along with the possible flowback and produced water production is assessed for the Dutch Posidonia shale. Total water demand estimated for 25 years of the field development using historic data from the U.S. plays varies between 12.2 and 36.9 Mm3. The maximal annual water consumption of 0.95-2.88 Mm3 is expected in the peak years of shale gas production. These figures are much lower than the availability of any potential water sources, which include drinking water, fresh and brackish groundwater, river water, effluents of wastewater treatment plants (WWTP) and sea water. River water is considered the most promising water source for fracturing fluids in the Dutch Posidonia shale based on its availability (>6·104 Mm3/year) and quality (only bacterial composition needs to be controlled). Total wastewater production for the whole period of the field development is estimated between 6.6 and 48.0 Mm3. Wastewater recycling can cover significant part of the source water demand for fracturing fluid. However, high mineral content of the wastewater as well as temporal and spatial discrepancies between wastewater production and water demand will form obstacles for wastewater recycling. The assessment framework developed in this study may be applied for other shale gas fields with high uncertainties regarding subsurface properties, connate formation water characteristics and future legislative framework.

Microalgal wastewater recycling: Suitability of harvesting methods and influence on growth mechanisms.

Wastewater recycling helps address the challenge of microalgae biomass commercialization by allowing for efficient resource recovery. In this study, three conventional harvesting methods, including centrifugation, microfiltration, and flocculation sedimentation, were investigated to explore the effects of harvesting methods on the characteristics of recycled wastewater and the growth of microalgae to select a suitable harvesting method for the microalgal wastewater recycling system. During the wastewater recycling process, the least amount of accumulated substances was exhibited in the wastewater recycled by microfiltration, followed by centrifugation, and the most by flocculation sedimentation. After 4 batches of cultivation, microalgal biomass harvested from centrifugation wastewater and microfiltration wastewater was 21.26 % and 13.54 % higher than that from flocculation wastewater, respectively. Lipids, carbohydrates and pigments were all increased by varying degrees. Additionally, flocculation sedimentation was not suitable for the microalgal wastewater recycling process since the low residual nutrients, high salinity, and excessive algal organic matter severely inhibited the growth of microalgae. Under the regulation of phytohormones, microalgae increased their energy reserves, enhanced photosynthesis, and improved their defense capability to resist the increasing abiotic stress. This study provides scientific support for the selection of suitable harvesting technology during the microalgal wastewater recycling process.

Efficient removal of antibiotics from water resources is a public health priority: a critical assessment of the efficacy of some remediation strategies for antibiotics in water.

This review discusses the fundamental principles and mechanism of antibiotic removal from water of some commonly applied treatment techniques including chlorination, ozonation, UV-irradiation, Fenton processes, photocatalysis, electrochemical-oxidation, plasma, biochar, anaerobicdigestion, activated carbon and nanomaterials. Some experimental shortfalls identified by researchers such as certain characteristics of degradation agent applied and the strategies explored to override the identified limitations are briefly discussed. Depending on interactions of a range of factors including the type of antibiotic compound, operational parameters applied such as pH, temperature and treatment time, among other factors, all reviewed techniques can eliminate or reduce the levels of antibiotic compounds in water to varying extents. Some of the reviewed techniques such as anaerobic digestion generally require longer treatment times (up to 360, 193 and 170 days, according to some studies), while others such as photocatalysis achieved degradation within short contact time (within a minimum of 30, but up to 60, 240, 300 and 1880 minutes, in some cases). For some treatment techniques such as ozonation and Fenton, it is apparent that subjecting compounds to longer treatment times may improve elimination efficiency, whereas for some other techniques such as nanotechnology, application of longer treatment time generally meant comparatively minimal elimination efficiency. Based on the findings of experimental studies summarized, it is apparent that operational parameters such as pH and treatment time, while critical, do not exert sole or primary influence on the elimination percentage(s) achieved. Elimination efficiency achieved rather seems to be due more to the force of a combination of several factors.

A promising microalgal wastewater cyclic cultivation technology: Dynamic simulations, economic viability, and environmental suitability.

The microalgal wastewater cyclic cultivation technology (AWC2T) proposed in this study helps address the challenges surrounding water scarcity and ecological sustainability in a clean, resource-efficient, and affordable manner. A novel microalgae growth model (AGM) elucidating the growth mechanisms of microalgae in the AWC2T system was established for dynamic simulations and design optimization. The recycled wastewater accelerated the growth rate of microalgae, and increased biomass and lipids content by 11% and 37.65%, respectively, after 8 batches of cultivation. The accumulated soluble algae products (SAPs) enhanced microalgae growth by providing nutrients and regulating metabolism. In addition, scenario simulations illustrated the excellent long-term performance of the AWC2T system. 100% recycling of microalgal wastewater could save 0.3% N and 54.36% P. The techno-economic analysis (TEA) and life cycle assessment (LCA) explored how economic and sustainability principles can be embedded into the life cycle of microalgae production. The AWC2T led to outcomes vastly superior to non-cyclic technology by enabling the high-level recovery of resources, providing substantial benefits, enhancing contingency and risk resistance, and offsetting a host of unintended environmental effects.

Evaluation of a novel integrated membrane biological aerated filter for water reclamation: A practical experience.

The use of treated wastewater in addition to solving the problem of water shortage, can increase soil fertility and reduce the use of chemical fertilizers. We aim to provide a high-quality effluent to feed membrane system, reduce treatment costs and enhance the efficiency of wastewater recycling. All experiments were conducted on a novel integrated membrane biological aerated filter (IMBAF) consisting of a down flow cylindrical biological aerated filter (BAF) filled by silica and a novel sand-coated polystyrene granules (SCP), followed by ultrafiltration (UF) and reverse osmosis (RO) membranes. IMBAF reactor, with 73.6 L volume, was operated for 270 days (in three 90-day stages) with different conditions of returning backwash water. Accordingly, BAF generated high quality water for feeding UF membrane with 94.2%, 68%, 54.4%, 91.2%, and 99.95% of turbidity, 5-day biochemical oxygen demand (BOD5), chemical oxygen demand (COD), oil and grease (O&G), fecal coliform (FC) removal, respectively. At the end of stage 3, 99.88% of influent was recycled by UF and only 0.12% was disposed of as sludge. The BAF and UF module efficiently promote the quality of water entering RO system. After 75 days of continuous operation, the increase in trans-membrane pressure (TMP) and also decrease in RO membrane permeability were about 14% and 9.4%, respectively, indicating low clogging of the membrane. The use of BAF structure designed in this study increases the wastewater recycling rate, decreases membrane clogging and thereby reduces the costs of concentrate disposal and chemical cleaning.

Biochemical wastewater from landfill leachate pretreated by microalgae achieving algae's self-reliant cultivation in full wastewater-recycling chain with desirable lipid productivity.

Heightened awareness of additional pretreatment for wastewater, has driven studies towards building a full wastewater-recycling chain wherein the wastewater pretreatment is performed by microalgae themselves. We applied biochemical wastewater from landfill leachate with added K2HPO4 (BWLL + P) directly to microalgal cultivation. The results showed that the pretreatment provided by the 1st cultivation reduced suspended solids by nearly half, greatly boosting microalgal growth, which thus yielded 1.06 g/L of dry mass and 87.06 mg/L·d of biomass productivity. From the 2nd to the 4th cultivation, lipid accumulation in BWLL + P was 1.12-1.27 times and 1.95-2.36 times higher than in BG11 and BWLL, respectively, mainly attributed to the comfortable environment engendered by the microalgal pretreatment and the organic carbon in the wastewater. Strikingly, the biodiesel production fed with BWLL + P could save 99% of the cost compared with in BG11. In combination, our pioneering full wastewater-recycling chain achieved microalgae's self-reliant cultivation, with wastewater nourishment.