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It is an urgent problem to realize reliable microwave absorption materials (MAMs) with low density. To address this issue, a series of controlled experiments w ere carried out, which indicated that the tubular structure enables excellent microwave absorption properties with a lower powder filling rate. This performance is attributable to the combined dielectric and magnetic loss mechanisms provided by Co/C and the interface polarization facilitated by multiple heterogeneous interfaces. Particularly, Co@C nanotubes, benefiting from the enhanced heterointerface polarization due to their abundant specific surface area and the reduced electron migration barrier induced by their 1D stacked structure, effectively achieved a dual enhancement of dielectric loss and polarization loss at lower powder filling ratios. Furthermore, the magnetic coupling effect of magnetic nanoparticle arrays in tubular structures is demonstrated by micromagnetic simulation, which have been few reported elsewhere. These propertied enable Co@C nanotubes to achieve minimum reflection loss and maximum effective absorption broadband values of 61.0 dB and 5.5 GHz, respectively, with a powder filling ratio of 20 wt% and a thickness of 1.94 mm. This study reveals the significance of designing 1D structures in reducing powder filling ratio and matching thickness, providing valuable insights for developing MAMs with different microstructures.
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The excellent performance of electromagnetic wave absorbers primarily depends on the coordination among components and the rational design of the structure. In this study, a series of porous fibers with carbon nanotubes uniformly distributed in the shape of pine leaves are prepared through electrospinning technique, one-pot hydrothermal synthesis, and high-temperature catalysis method. The impedance matching of the nanofibers with a porous structure is optimized by incorporating melamine into the spinning solution, as it undergoes gas decomposition during high-temperature calcination. Moreover, the electronic structure can be modulated by controlling the NH4F content in the hydrothermal synthesis process. Ultimately, the Ni/Co/CrN/CNTs-CF specimen (P3C NiCrN12) exhibited superior performance, while achieving a minimum reflection loss (RLmin) of -56.18 dB at a thickness of 2.2 mm and a maximum absorption bandwidth (EABmax) of 5.76 GHz at a thickness of 2.1 mm. This study presents an innovative approach to fabricating lightweight, thin materials with exceptional absorption properties and wide bandwidth by optimizing the three key factors influencing electromagnetic wave absorption performance.
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Pristine and Dy substituted MnFe2O4,MnFe2-xDyxO4(x= 0.00, 0.02, 0.04, 0.06, 0.08 & 0.10) were successfully synthesized by sol-gel method to investigate the dielectric properties of the system. MnFe2O4exhibits a high dielectric permittivity of order 104which is further augmented by 60% through Dy substitution. This is owing to the rise in interfacial polarization resulting from localized states, dipolar polarization arising from the multiple valence states of Fe and Mn ions, atomic polarization due to structural distortion induced by strain, and electronic polarization stemming from the concentration of free charge carriers. The enhancement of induced strain, mixed valence ratio of Fe2+/Fe3+and Mn4+/Mn2+, localized states, and free charge carrier concentration are confirmed from the XRD, XPS, and optical studies, respectively. The dielectric relaxation mechanism of MnFe2-xDyxO4follows a modified Havriliak-Negami relaxation model with conductivity contribution. Complex impedance analyses further validate the contribution of grain-grain boundary mechanisms to the dielectric properties confirmed through Nyquist plots. A comprehensive analysis of conductivity reveals the significant impact of Dy substitution on the electrical conductivity of MnFe2O4. This influence is strongly related to the variations in the concentration of free charge carriers within the MnFe2-xDyxO4system. The understanding of the underlying physics governing the dielectric properties of Dy-substituted MnFe2O4not only enhances the fundamental knowledge of material behavior but also opens new avenues for the design and optimization of advanced electronic and communication devices.
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Hollow carbon spheres are potential candidates for lightweight microwave absorbers. However, the skin effect of pure carbon-based materials frequently induces a terrible impedance mismatching issue. Herein, small-sized NiO/Ni particles with heterojunctions on the N-doped hollow carbon spheres (NHCS@NiO/Ni) are constructed using SiO2 as a sacrificing template. The fabricated NHCS@NiO/Ni displayed excellent microwave absorbability with a minimum reflection loss of -44.04 dB with the matching thickness of 2 mm and a wider efficient absorption bandwidth of 4.38 GHz with the thickness of 1.7 mm, superior to most previously reported hollow absorbers. Experimental results demonstrated that the excellent microwave absorption property of the NHCS@NiO/Ni are attributed to balanced dielectric loss and optimized impedance matching characteristic due to the presence of NiO/Ni heterojunctions. Theoretical calculations suggested that the redistribution of charge at the interfaces and formation of dipoles induced by N dopants and defects are responsible for the enhanced conduction and polarization losses of NHCS@NiO/Ni. The simulations for the surface current and power loss densities reveal that the NHCS@NiO/Ni has- applicable attenuation ability toward microwave under the practical application scenario. This work paves an efficient way for the reasonable design of small-sized particles with well-defined heterojunctions on hollow nanostructures for high-efficiency microwave absorption.
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The rational design of lightweight, broad-band, and high-performance microwave absorbers is urgently required for addressing electromagnetic pollution issue. Metal single atoms (M-SAs) absorbers receive considerable interest in the field of microwave absorption due to the unique electronic structures of M-SAs. However, the simultaneous engineering of the morphology and electronic structure of M-SAs based absorbers remains challenging. Herein, a template-assisted method is utilized to fabricate isolated Co-SAs on N-doped hollow carbon spheres (NHCS@Co-SAs) for high-performance microwave absorption. The combination of atomically dispersed Co sites and hollow supports endows NHCS@Co-SAs with excellent microwave absorption properties. Typically, at an ultralow filler content of 8 wt%, the minimum reflection loss and effective absorption bandwidth of the NHCS@Co-SAs are up to -44.96 dB and 5.25 GHz, respectively, while the absorbing thickness is only 2 mm. Theoretical calculations and experimental results indicate that the impedance matching characteristic and dielectric loss of the NHCSs can be tuned via the introduction of M-SAs, which are responsible for the excellent microwave absorption properties of NHCS@Co-SAs. This work provides an atomic-level insight into the relationship between the electronic states of absorbers and their microwave absorption properties for developing advanced microwave absorbers.
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Polyimide is a potential material for high-performance printed circuit boards because of its chemical stability and excellent thermal and mechanical properties. Flexible printed circuit boards must have a low static dielectric constant and dielectric loss to reduce signal loss in high-speed communication devices. Engineering the molecular structure of polyimides with large pendant groups is a strategy to reduce their dielectric constant. However, there is no systematic study on how the large pendant groups influence electrical energy loss. We integrated all-atomic molecular dynamics and semi-empirical quantum mechanical calculations to examine the influence of pendant groups on polymer chain anisotropy and electrical energy loss at high frequencies. We analyzed the radius of gyration, relative shape anisotropy, dipole moment, and degree of polarization of the selected polyimides (TPAHF, TmBPHF, TpBPHF, MPDA, TriPMPDA, m-PDA, and m-TFPDA). The simulation results show that anisotropy perpendicular to chain direction and local chain rigidity correlate to electrical energy loss rather than dipole moment magnitudes. Polyimides with anisotropic pendant groups and significant local chain rigidity reduce electrical energy loss. The degree of polarization correlated well with the dielectric loss with a moderate computational cost, and difficulties in directly calculating the dielectric loss were circumvented.
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The construction of multi-component composites has become an attractive strategy for high-performance microwave absorption through balancing the magnetic and dielectric loss. However, the influences of different components on absorption performance are ambiguous, which has inevitably hampered the widespread applications of microwave absorbents. Herein, we rationally designed the multi-component absorbers of N-doped carbon composited with Fe/Fe3C nanoparticles, and systematically investigated the impacts of Fe/Fe3C nanoparticles and Fe-Nxmoieties on the microwave-absorbing capacities. It is found that the coexisitence of Fe/Fe3C and Fe-Nxis indispensable to realize the strong microwave absorption ability by simultaneously enhancing the dielectric and magnetic loss in the frequency range of 2-18 GHz. As expected, our optimal absorber dispersed in paraffin with a filler loading of 15 wt% exhibits the minimum reflection loss (RLmin) value of -49 dB and the maximum effective absorption bandwidth (BWeff) value of 4.2 GHz at a low thickness. Our work specifies the importance and influence of the coexistence between the Fe-Nxconfigurations and Fe/Fe3C nanoparticles in the carbon-based composites for the superior microwave absorption and inspires the future fabrication of extraordinary materials in the electromagnetic field.
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This work describes an easy and effective process for preparing a homogeneous polybutadiene (PB) dielectric elastomer with improved actuated strain by utilizing a photochemical thiol-ene click reaction. The carboxyl groups and various ester groups are used for grafting on the PB. Since the length of the alkyl chains of the ester groups will significantly influence the polarities of the carbonyl groups and hydrogen bonding effect, the influence of polarity and hydrogen bonding effect on the dielectric properties and mechanical properties of the modified polybutadienes is carefully discussed. Very interestingly, it is found that the increment of dielectric constant of PB modified by carboxyl groups is the lowest one compared to other modified PBs with the ester groups. Meanwhile, the modified PBs with the ester groups could achieve pretty low dielectric loss factor, and finally, a high dielectric constant (3.6), low dielectric loss factor (0.0005), and large actuated strain (≈25%) of the modified polybutadienes could be achieved by the modified PBs with butyl acrylate groups. This work provides a simple and effective method for the designing and synthesizing of a homogeneous high electromechanical performance dielectric elastomer with high dielectric constant and low dielectric loss.
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Butadienos , Elastómeros , Elastómeros/química , Enlace de Hidrógeno , Compuestos de SulfhidriloRESUMEN
Capacitive equipment refers to its insulation design using the principle of capacitance of electrical equipment, mainly by a variety of different capacitive components in series. Most of the equipment in the substation is capacitive equipment. Once an insulation failure occurs, it will lead to extremely serious consequences. Monitoring grid overvoltage and insulation degradation of capacitive equipment is an effective means to ensure the stable operation of the power system. Therefore, in order to enhance the health management of capacitive equipment, including transformers, bushings, and current transformers, and to mitigate the risk of severe failures, it is imperative to conduct broad-spectrum frequency-domain online monitoring of overvoltages, dielectric losses, and partial discharge. However, the current monitoring work requires the utilization of multiple detection apparatuses. Aiming at the disadvantage that the existing inspection is not well integrated and requires a combination of multiple devices. This paper proposes a smart grid overvoltage identification system that utilizes partial discharge (PD) signals in correlation with dielectric loss detection. The system achieves synchronous detection of dielectric loss and high-frequency partial discharge by synchronously and in real-time acquiring four current signals from the power grid, enhancing the integration level of the hardware system.
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The dielectric loss angle can better reflect the overall insulation level of mining cables, so it is necessary to implement reliable and effective online monitoring of the dielectric loss angle of mining cables. In order to improve the monitoring accuracy of the dielectric loss angle tan δ of mining cables, a low-frequency dielectric loss angle online monitoring method combining signal injection method and double-end synchronous measurement method is proposed in this paper. Firstly, the superiority of the low-frequency signal in improving the detection accuracy of dielectric loss angle is explained, and the feasibility of the low-frequency signal injection method is analyzed. Secondly, the cable leakage is calculated using the double-terminal synchronous measurement method to measure the core current at the first and last ends of the cable, and the phase sum of the voltage at the first and last ends is selected as the reference phase quantity to realize the effective calculation of the dielectric loss angle tan δ of the cable. Then, the simulation model for online monitoring of dielectric loss angle of mining cable is built, and the feasibility of the online monitoring method proposed in this paper is verified by combining the simulation results. Finally, the theoretical and simulation analysis of the monitoring error of dielectric loss angle of mining cable is carried out.
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CdxNi0.5-xCu0.2Zn0.3Fe2O4 (0 ≤ x ≤ 0.50) ferrite with a spinel structure was prepared using the sol-gel self-propagation method. The effects of Cd2+ doping on the structure, morphology, dielectric, and magnetic properties of Ni-Cu-Zn ferrite were examined using XRD, SEM, EDX, FTIR, MPMS, and dielectric tests. The cubic spinel structure was verified by XRD and FTIR analyses. The crystallite size and particle size information of the samples were obtained with XRD and SEM analysis. The sample particle size belonged to a class of nanoscale materials with a particle size range of 1-100 nm. The minor difference between the grain size and particle size indicated that the sample nanoparticles were composed of numerous microcrystals. The EDX spectra indicated that the samples contained all stoichiometric elements. MPMS was used to measure the hysteresis lines of the samples. According to the hysteresis line, the saturation magnetization intensity (Ms), coercivity (Hc), and magnetic moment (µB) of the sample increased and then decreased with the increase in cadmium concentration. The magnetization strength (Ms) is between 4-67 emu/g, and the coercivity (Hc) is between 9-46 Oe. The curves of the real part of the dielectric constant (ε'), the imaginary part of the dielectric constant (εâ³), and the loss factor (tanδ) with frequency were measured in the frequency range 100 Hz-100 kHz by means of an impedance analyzer. The complex modulus spectrum was analyzed to understand the dynamics of the conduction process.
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In this work, Eu2O3-doped (CaCu3Ti4O12)x of low dielectric loss have been fabricated using both conventional (CS) and microwave sintering (MWS), where x = Eu2O3 = 0.1, 0.2, and 0.3, respectively. According to X-ray diffraction (XRD) and scanning electron microscope (SEM) reports, increasing the concentration of Eu3+ in the CCTO lattice causes the grain size of the MWS samples to increase and vice versa for CS. The X-ray photoelectron spectroscopy (XPS) delineated the binding energies and charge states of the Cu2+/Cu+ and Ti4+/Ti3+ transition ions. Energy dispersive spectroscopy (EDS) analysis revealed no Cu-rich phase along the grain boundaries that directly impacts the dielectric properties. The dielectric characteristics, which include dielectric constant (ε) and the loss (tan δ), were examined using broadband dielectric spectrometer (BDS) from 10 to 107 Hz at ambient temperature. The dielectric constant was >104 and >102 for CS and MWS samples at x > 0.1, respectively, with the low loss being constant even at high frequencies due to the effective suppression of tan δ by Eu3+. This ceramic of low dielectric loss has potential for commercial applications at comparatively high frequencies.
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Europio , Microondas , Cerámica , Grano Comestible , Espectroscopía de FotoelectronesRESUMEN
Although transition metal carbides/carbonitrides (MXenes) exhibit immense potential for electromagnetic wave (EMW) absorption, their absorbing ability is hindered by facile stacking and high permittivity. Layer stacking and geometric structures are expected to significantly affect the conductivity and permittivity of MXenes. However, it is still a formidable task to simultaneously regulate layer stacking and microstructure of MXenes to realize high-performance EMW absorption. Herein, a simple and viable strategy using electrostatic adsorption is developed to integrate 2D Ti3 C2 Tx MXene nanosheets into 3D hollow bowl-like structures with tunable layer stacking thickness. Density functional theory calculations indicate an increase in the density of states of the d orbital from the Ti atom near the Fermi level and the generation of additional electrical dipoles in the MXene nanosheets constituting the bowl walls upon reducing the layer stacking thickness. The hollow MXene bowls exhibit a minimum reflection loss (RLmin ) of -53.8 dB at 1.8 mm. The specific absorbing performance, defined as RLmin (dB)/thickness (mm)/filler loading (wt%), exceeds 598 dB mm-1 , far surpassing that of the most current MXene and bowl-like materials reported in the literature. This work can guide future exploration on designing high-performance MXenes with "lightweight" and "thinness" characteristics for superior EMW absorption.
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Dielectric loss is an important way to eliminate electromagnetic pollution. In order to achieve high dielectric loss, a graphene film reduced graphene oxide-N doped graphene (rGO-NG) was constructed from graphene oxide-Ni@polydopamine (GO-Ni@PDA) via thein situsynthesis of hollow graphene spheres between graphene sheets. Thisin situwas achieved by means of electrostatic self-assembly and metal-catalyzed crystallization. Owing to the synergetic effect of multi-nanocavities and multi-defects, the prepared rGO-NG film shows an average shielding effectiveness (SE) of 50.0 dB in the range of 8.2-12.4 GHz with a thickness of 12.2µm, and the SE reflection is only 7.3 dB on average. It also exhibits an average dielectric loss tangent (tanδ) of 23.1, which is 26 and 105 times higher than those of rGO and rGO-Ni, respectively. This work provides a simple but effective route to develop high performance graphene-based materials for application as an electromagnetic interference shielding film in today's electronic devices.
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Two dimensional (2D) CsPb2Br5have been successfully synthesized via the chemical precipitation method. Detailed structural, morphological, optical, and dielectric studies of these materials have been performed. These 2D CsPb2Br5plates (of thickness around 200-300 nm) are ascribed to a tetragonal lattice system withI4/mcmspace group. The dielectric attributes such as dielectric constant, electrical modulus, loss factor, and the DC, and AC conductivities, are observed to be varying appreciably with temperature over an extensive frequency window of 10 Hz-50 MHz. The Nyquist plots are investigated using the Maxwell-Wagner equivalent circuit model, which shows the impact of grains and grain boundaries on the overall impedance. Both the free charge conductivity and space charge increase with an increment in temperature, as revealed from the modified Cole-Cole plot. The relaxation time and relaxation mechanism of 2D CsPb2Br5are estimated using the Kohlrausch-Williams-Watts equation. Variation in DC conductivity and relaxation time, as a function of temperature, closely resembles Arrhenius' behavior. Value of activation energy calculated from the DC conductivity corroborates with the same derived from relaxation time. The observation of high dielectric constant and nominal dielectric loss for CsPb2Br5perovskite offers enormous potential in energy harvesting and storage devices.
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Insulator diagnostics is still a topical issue. No one has yet found out how to accurately determine the condition of all insulators and decide when replacement or maintenance is required. Insulators are one of the main components of a transmission and distribution system and must withstand high voltages in all weather conditions. Moisture and dirt are the main factors influencing the insulating properties of insulators. This article deals with the effect of pollution on a porcelain insulator. An Omicron MI 600 measuring system monitors the changes in the dielectric loss factor and leakage current in a wide frequency range (10 Hz to 1 kHz) to evaluate the contamination level. We applied three high voltage levels (5 kV, 7.5 kV, and 10 kV) to the porcelain insulator to monitor changes in the mentioned quantities with various frequencies. The measurement results confirmed the usability of the dielectric loss factor and leakage current for the diagnosis of insulator pollution. The dielectric loss factor showed more promising results than the leakage current.
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Tiempo (Meteorología)RESUMEN
Insulators are one of the many components responsible for the reliability of electricity supply as part of transmission and distribution lines. Failure of the insulator can cause considerable economic problems that are much greater than the insulator cost. When the failure occurs on the transmission line, a large area can be without electricity supply or other transmission lines will be overloaded. Because of the consequences of the insulator's failure, diagnostics of the insulator plays a significant role in the reliability of the power supply. Basic diagnostic methods require experienced personnel, and inspection requires moving in the field. New diagnostic methods require online measurement if it is possible. Diagnostic by measuring the leakage current flowing on the surface of the insulator is well known. However, many other quantities can be used as a good tool for diagnostics of insulators. We present in this article results obtained on the investigated porcelain insulators that are one of the most used insulation materials for housing the insulator's core. Leakage current, dielectric loss factor, capacity, and electric charge are used as diagnostic quantities to investigate porcelain insulators in different pollution conditions and different ambient relative humidity. Pollution and humidity are the main factors that decrease the insulator´s electric strength and reliability.
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Suministros de Energía Eléctrica , Electricidad , Contaminación Ambiental , Humedad , Reproducibilidad de los ResultadosRESUMEN
Carbon-based carbides have attracted tremendous attention for electromagnetic energy attenuation due to their adjustable dielectric properties, oxidation resistance, and good chemical stability. Herein, we reasonably regulate the growth of dopamine hydrochloride on the surface of the Mo-glycerate (Mo-GL) microsphere and then transform the resultant Mo-polydopamine (Mo-PD) microsphere into a dual-shell Mo2C/C (DS-Mo2C/C) microsphere in a high-temperature pyrolysis process under an inert atmosphere. It is found that the pyrolysis temperature plays an important role in the graphitization degree of the carbon matrix and internal architecture. The fabrication of a dual-shell structure can be propitious to the optimization of impedance matching, and the introduction of Mo2C nanoparticles also prompts the accumulation of polarization loss. When the pyrolysis temperature reaches 800 °C, the optimized composite of DS-Mo2C/C-800 exhibits good EM absorption performance in the frequency range of 2.0-18.0 GHz. DS-Mo2C/C-800's qualified bandwidth can reach 4.4 GHz at a matching thickness of 1.5 mm, and the integrated qualified bandwidth (QBW) even exceeds 14.5 GHz with a thickness range of 1.5-5.0 mm. The positive effects of the dual-shell structure and Mo2C nanoparticles on EM energy attenuation may render the DS-Mo2C/C microsphere as a promising candidate for lightweight and broad bandwidth EM absorption materials in the future.
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Absorción de Radiación , Pirólisis , Microesferas , Carbono , AtmósferaRESUMEN
Considering the electromagnetic protection needs of important ground buildings, exploring the electromagnetic wave (EMW) absorption performance of manganese ore powder (MOP) building materials is an effective way to overcome its low added value and difficulty in popularizing. Here, choosing filling ratios commonly used in building materials such as autoclaved bricks, MOP/paraffin samples with 20%, 40%, and 60% mass fraction of MOP were prepared, and electromagnetic properties were analyzed at 2−18 GHz using the coaxial method. The results show that 60 wt% sample has the best absorption performance, with a minimum reflection loss (RLmin) value of −22.06 dB at 15.04 GHz, and the effective absorption bandwidth (EAB, RL < −10 dB) reaches 4.16 GHz at a 7.65 mm absorber thickness, covering most of the Ku-band region. The excellent microwave absorption performance of MOP is due to its multi-oxide forming multi-interface structure and rough surface, which can not only form abundant dipole and interfacial polarization under the action of EMW, but also reflect and scatter the incident EMW, prolong the transmission path, and enhanced the absorption of microwaves. This study demonstrates that MOP building materials can have excellent microwave absorption properties, thus becoming a new way to address harmful manganese residue; for example, autoclaved bricks, which can not only improve the added value of manganese residue building materials but also can be consumed on a large scale. It provides a new idea to solve the harm of manganese residue.
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Manganeso , Microondas , Polvos , Dióxido de SilicioRESUMEN
Dielectric loss from different interfacial layers in the superconducting circuit and from external environment may cause superconducting qubit decoherence. Compared to modeling the entire device at once with a numerical solver, quantitatively formulating the dielectric loss can both describe all loss mechanisms and make the optimization more transparent. In this paper, we first analyze the expression formula of dielectric loss, and obtain a design scheme that can reduce the dielectric loss of qubits. That is, we replace the straight junction wires with the tapered junction wires. Based on this scheme, we perform a simulation to optimize the design of junction wires. Finally, a real experiment is conducted to verify our design. The results show that both the T1 time and T2 time of qubits are significantly improved.