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Annu Rev Biochem ; 86: 825-843, 2017 06 20.
Artículo en Inglés | MEDLINE | ID: mdl-28399656

RESUMEN

Small-molecule fluorophores, such as fluorescein and rhodamine derivatives, are critical tools in modern biochemical and biological research. The field of chemical dyes is old; colored molecules were first discovered in the 1800s, and the fluorescein and rhodamine scaffolds have been known for over a century. Nevertheless, there has been a renaissance in using these dyes to create tools for biochemistry and biology. The application of modern chemistry, biochemistry, molecular genetics, and optical physics to these old structures enables and drives the development of novel, sophisticated fluorescent dyes. This critical review focuses on an important example of chemical biology-the melding of old and new chemical knowledge-leading to useful molecules for advanced biochemical and biological experiments.


Asunto(s)
Fluoresceínas/síntesis química , Colorantes Fluorescentes/síntesis química , Sondas Moleculares/síntesis química , Etiquetas de Fotoafinidad/síntesis química , Rodaminas/síntesis química , Animales , Bacterias/metabolismo , Técnicas de Química Sintética , Fluoresceínas/historia , Fluoresceínas/metabolismo , Colorantes Fluorescentes/historia , Colorantes Fluorescentes/metabolismo , Historia del Siglo XIX , Historia del Siglo XX , Historia del Siglo XXI , Humanos , Microscopía Fluorescente , Sondas Moleculares/historia , Sondas Moleculares/metabolismo , Etiquetas de Fotoafinidad/historia , Etiquetas de Fotoafinidad/metabolismo , Rodaminas/historia , Rodaminas/metabolismo
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