RESUMO
A new rhodamine 6G derivative R1 has been synthesized by condensation of rhodamine hydrazide and 6-hydroxymethyl-pyridine using microwave-assisted reaction. Naked-eye colorimetric and photo physical studies show the synthesized compound is selectively sensing Cu2+ in CH3CN/H2O (9:1, v/v) solution. Upon coordination with Cu2+ ion, the spirolactam of R1 is opened, which results in a formation of highly fluorescent complex and change in color of the solution. The Job's plot indicates 1:2 binding stoichiometry between Cu2+ ion and R1. Limit of detection for Cu2+ was determined to be 1.23 µM. The sensor was successfully applied to fluorescent imaging of Cu2+ ion in living cells.
RESUMO
Rhodamine 6G dyes are low-cost, highly soluble fluorescent dyes frequently utilized as laser dyes, chemical sensors, and as tracer dyes in the determination of the direction and rate of flow of water. In this study, the photophysical properties of three rhodamine 6G dyes, bearing phenyl (P15), furan (P41), and 5-hydroxymethyl furan (P45), and their metal complexes were investigated using ultraviolet-visible (UV-vis) spectroscopy, fluorescence spectroscopy, fluorescence lifetime, and Fourier transform infrared (FTIR) measurements. Rhodamine 6G dyes and their complexes were subsequently applied as sensitizing dyes in the fabrication of dye-sensitized solar cells, and the solar to electric power efficiency and electrochemical impedance spectroscopy measurements were performed. The solar to electric power efficiency values of the metal complexes of the rhodamine 6G dyes were higher than those of the devices fabricated with only rhodamine dyes without copper (II). The most significant change was observed in rhodamine P41 with a 30% increase in solar to electric power efficiency when the dye was conjugated to the copper ion.