Recent Development of Anion Exchange Membrane Fuel Cells and Performance Optimization Strategies: A Review.

Anion exchange membrane fuel cells (AEMFCs) are the most promising low-temperature fuel cells and have received extensive attention. Compared to PEMFCs, the cost per unit of power can be significantly reduced for AEMFCs because, in theory, they allow the usage of non-precious metal catalysts and low-cost cell components. Owing to the development of advanced materials and performance improvement strategies, AEMFCs have achieved new records in both initial performance and durability. However, the high performance currently achieved is contingent on certain conditions, e. g., high Pt loading, large gas flowrates, and operation in pure O2 , which are far from practical applications. Therefore, the transition to commercially relevant performance and durability is the next goal of AEMFCs. This paper reviews the performance data of H2 -fueled AEMFCs since 2010 and summarizes possible performance optimization schemes, which can provide useful insights for developing next-generation AEMFCs.

Work Efficiency and Economic Efficiency of Actual Driving Test of Proton Exchange Membrane Fuel Cell Forklift.

A 3.5 tonne forklift containing proton exchange membrane fuel cells (PEMFCs) and lithium-ion batteries was manufactured and tested in a real factory. The work efficiency and economic applicability of the PEMFC forklift were compared with that of a lithium-ion battery-powered forklift. The results showed that the back-pressure of air was closely related to the power density of the stack, whose stability could be improved by a reasonable control strategy and membrane electrode assemblies (MEAs) with high consistency. The PEMFC powered forklift displayed 40.6% higher work efficiency than the lithium-ion battery-powered forklift. Its lower use-cost compared to internal engine-powered forklifts, is beneficial to the commercialization of this product.

Pre-combustion CO2 capture by transition metal ions embedded in phthalocyanine sheets.

Transition metal (TM) embedded two-dimensional phthalocyanine (Pc) sheets have been recently synthesized in experiments [M. Abel, S. Clair, O. Ourdjini, M. Mossoyan, and L. Porte, J. Am. Chem. Soc. 133, 1203 (2010)], where the transition metal ions are uniformly distributed in porous structures, providing the possibility of capturing gas molecules. Using first principles and grand canonical Monte Carlo simulations, TMPc sheets (TM = Sc, Ti, and Fe) are studied for pre-combustion CO(2) capture by considering the adsorptions of H(2)/CO(2) gas mixtures. It is found that ScPc sheet shows a good selectivity for CO(2), and the excess uptake capacity of single-component CO(2) on ScPc sheet at 298 K and 50 bar is found to be 2949 mg/g, larger than that of any other reported porous materials. Furthermore, electrostatic potential and natural bond orbital analyses are performed to reveal the underlying interaction mechanisms, showing that electrostatic interactions as well as the donation and back donation of electrons between the transition metal ions and the CO(2) molecules play a key role in the capture.

Double layer capacitance of anode/solid-electrolyte interfaces.

The double layer of electrode/electrolyte interfaces plays a fundamental role in determining the performance of solid state electrochemical cells. The double layer capacitance is one of the most-studied descriptors of the double layer. This work examines a case study on lanthanum strontium vanadate (LSV)/yttria-stabilized zirconia (YSZ) interfaces exposed in solid oxide fuel cell anode environment. The apparent double layer capacitance is obtained from impedance spectroscopy. The intrinsic double layer capacitance is evaluated based on Stern's method in conjunction with the Volta potential analysis across LSV/YSZ interfaces. Both the apparent and the intrinsic double layer capacitances exhibit right-skewed volcano patterns, when the interfaces are subjected to anodic biases from 0 to 150 mV. The apparent double layer capacitance is about one order of magnitude larger than the intrinsic double layer capacitance. This discrepancy roots in the inconsistent surface areas that are involved. This analysis of capacitance would provide a more realistic TPB estimate of a working solid-state electrochemical device.

Molecular interaction and properties of poly(ether ether ketone)/liquid crystalline polymer blends incorporated with functionalized carbon nanotubes.

Multi-walled carbon nanotubes (MWCNTs) were functionalized with a carboxyl group (-COOH) to achieve better interfacial adhesions with both phases of the poly(ether ether ketone) (PEEK) and liquid crystalline polymer (LCP) in their blend. These strong interfacial interactions among the functionalized MWCNTs, PEEK and LCP improved the mechanical properties of the polymer blend. Three different weight percentages (0.6%, 1.2% and 1.8%) of acid modified CNTs were used with PEEK-LCP blend, for the preparation of nanocomposites. In PEEK-LCP blend, the ratio of PEEK and LCP was maintained as 10:6 respectively. The tensile strength and modulus of the composites were improved by 51% and 73% respectively with the incorporation of only 1.2% of MWCNT-COOH as compared to the unfilled PEEK/LCP blend. Moreover, careful studies of the molecular interaction, morphological, dynamic mechanical and thermal properties confirmed that a better miscibility between PEEK and LCP had been constituted in the presence of MWCNT-COOH. Therefore, it was found that the functionalized MWCNTs not only played the traditional role as reinforcing filler, but also performed a novel role as a compatibilizer for the PEEK/LCP blends.

The role of functionalized carbon nanotubes in a PA6/LCP blend.

Multi-walled carbon nanotubes (MWCNTs) were carboxyl-functionalized in order to improve their dispersion in a polymer matrix. The carboxyl-functionalized MWCNTs (i.e., MWCNT-COOH) were added into a blend matrix consisting of polyamide 6 (PA6) and liquid crystalline polymer (LCP) (PA6:LCP = 80:20 in weight) to make ternary composites. The effects of MWCNT-COOH on the rheological, physical, morphological, thermal, mechanical, and electrical properties of the ternary composites have been examined systematically. The dispersion of MWCNTs in the polymer matrix and their interactions with the polymers (i.e., PA6 and LCP) were found to be the most important factors affecting all properties. The functionalization of MWCNTs resulted in the significant improvement in their dispersion in the polymer matrix and largely enhanced the interactions of MWCNTs with the polymer matrix. The functionalized MWCNTs acted not only as reinforcement fillers but also as a compatibilizer that could enhance the interfacial adhesion between PA6 and LCP. Interestingly, the packing density of the polymer matrix was greatly increased by adding MWCNT-COOH.

High Electrochemical Performance of Bi2WO6/Carbon Nano-Onion Composites as Electrode Materials for Pseudocapacitors.

Bi2WO6/CNO (CNO, carbon nano-onion) composites are synthesized via a facile low-cost hydrothermal method and are used pseudocapacitor electrode material. X-ray diffraction (XRD), Fourier transform infrared spectra (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N2 adsorption-desorption techniques, and X-ray photoelectron spectroscopy (XPS) measurements are used to characterize the synthesized composite powders. The electrochemical performances of the composite electrodes are studied by cycle voltammetry, charge-discharge, and electrochemical impedance spectroscopy. The results indicate that the specific capacitance of the Bi2WO6/CNO composite materials reaches up to 640.2 F/g at a current density of 3 mA/cm2 and higher than that of pristine Bi2WO6, 359.1 F/g. The capability of the prepared pseudocapacitor remains 90.15% after 1,000 cycles of charge-discharge cycling measurement. The cell performance and stability can be enhanced by further optimization and modification of the composition and microstructure of the electrode of the cell.

Improvement of properties of polyetherimide/liquid crystalline polymer blends in the presence of functionalized carbon nanotubes.

This article reports the effect of functionalized multiwall carbon nanotubes (MWNT-COOH) on the morphological, dynamic mechanical, mechanical and thermal properties of polyetherimide (PEI)/liquid crystalline polymer (LCP) (Vectra A950) blends. The chemical modification of carbon nanotube enhanced the compatibility and the miscibility between PEI and LCP in the composites. Addition of functionalized MWNTs into the blend improved the thermal, mechanical and dynamic mechanical properties of the composite due to the presence of strong interfacial interaction between the polymer matrixes and the nanotubes in polymer composites. The glass transition temperature (from tan delta) increased from 208 degrees C to 245 degrees C with the addition of 1.8 wt% functionalized MWNTs in the blend of PEI/LCP. The tensile strength of the composite with 1.8 wt% MWNT-COOH was enhanced by 61% and 44% as compared to PEI/LCP blend and pure PEI. The functional groups on the MWNTs surface played an important role in accelerating both the dispersion of MWNTs and the interfacial adhesion in the composites compared to raw MWNTs.

Effect of carbon nanotubes and processing methods on the properties of carbon nanotube/polypropylene composites.

The effect of multi-walled carbon nanotubes (MWCNTs) and processing methods on the morphological, crystalline, dynamic mechanical, mechanical and electrical properties of MWCNT/polypropylene (PP) composites has been investigated by using field emission scanning electron microscopy (SEM), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), tensile and electric conductivity tests. The MWCNTs have been functionalized covalently and noncovalently for better dispersion in the PP matrix. A homogeneous dispersion of MWCNTs was achieved in the PP matrix as evidenced by scanning electron microscopy. Differential scanning calorimetric (DSC) results confirmed that the incorporation of the MWCNTs effectively enhanced the crystallization of the PP matrix through heterogeneous nucleation. The glass transition temperature increased from 8 degrees C for the pure PP to 26 degrees C for the composite with 10 wt% MWCNT-COOH. The present investigation revealed that the mechanical, thermal as well as electrical properties of carbon nanotubes filled polymer composites were strongly dependent on the state of dispersion, mixing and processing methods.

Be12O12 Nano-cage as a Promising Catalyst for CO2 Hydrogenation.

An efficient conversion of CO2 into valuable fuels and chemicals has been hotly pursued recently. Here, for the first time, we have explored a series of M12x12 nano-cages (M = B, Al, Be, Mg; X = N, P, O) for catalysis of CO2 to HCOOH. Two steps are identified in the hydrogenation process, namely, H2 activation to 2H*, and then 2H* transfer to CO2 forming HCOOH, where the barriers of two H* transfer are lower than that of the H2 activation reaction. Among the studied cages, Be12O12 is found to have the lowest barrier in the whole reaction process, showing two kinds of reaction mechanisms for 2H* (simultaneous transfer and a step-wise transfer with a quite low barrier). Moreover, the H2 activation energy barrier can be further reduced by introducing Al, Ga, Li, and Na to B12N12 cage. This study would provide some new ideas for the design of efficient cluster catalysts for CO2 reduction.

Heterogeneous catalytic conversion of CO2: a comprehensive theoretical review.

The conversion of CO2 into fuels and useful chemicals has been intensively pursued for renewable, sustainable and green energy. However, due to the negative adiabatic electron affinity (EA) and large ionization potential (IP), the CO2 molecule is chemically inert, thus making the conversion difficult under normal conditions. Novel catalysts, which have high stability, superior efficiency and low cost, are urgently needed to facilitate the conversion. As the first step to design such catalysts, understanding the mechanisms involved in CO2 conversion is absolutely indispensable. In this review, we have summarized the recent theoretical progress in mechanistic studies based on density functional theory, kinetic Monte Carlo simulation, and microkinetics modeling. We focus on reaction channels, intermediate products, the key factors determining the conversion of CO2 in solid-gas interface thermocatalytic reduction and solid-liquid interface electrocatalytic reduction. Furthermore, we have proposed some possible strategies for improving CO2 electrocatalysis and also discussed the challenges in theory, model construction, and future research directions.

Graphene-based materials for energy conversion.

With the depletion of conventional energy sources, the demand for renewable energy and energy-efficient devices continues to grow. As a novel 2D nanomaterial, graphene attracts considerable research interest due to its unique properties and is a promising material for applications in energy conversion and storage devices. Recently, the fabrication of fuel cells and solar cells using graphene for various functional parts has been studied extensively. This research news summarizes and compares the advancements that have been made and are in progress in the utilization of graphene-based materials for energy conversion.

Poly(vinyl alcohol) nanocomposites filled with poly(vinyl alcohol)-grafted graphene oxide.

We present a novel approach to the fabrication of advanced polymeric nanocomposites from poly(vinyl alcohol) (PVA) by incorporation of PVA-grafted graphene oxide. In this work, we have synthesized PVA-grafted graphene oxide (PVA-g-GO) for the strong interfacial adhesion of graphene oxide (GO) to the PVA matrix. It was found that the mechanical properties of PVA were greatly improved by incorporating PVA-g-GO. For example, the tensile strength and Young's modulus of the PVA nanocomposite films containing 1 wt % net GO in the PVA-g-GO significantly increased by 88 and 150%, respectively, as compared to unfilled PVA. The elongation at break was also increased by 22%, whereas the GO/PVA nanocomposite containing 1 wt % pristine GO was decreased by 15%. Therefore, the presence of the PVA-g-GO in the PVA matrix could make the PVA not only stronger but also tougher. The strong interfacial adhesion between PVA-g-GO and the PVA matrix was attributed to the good compatibility between PVA-g-GO and the matrix PVA as well as the hydrogen-bonding between them.