RESUMO
All-inorganic lead halide perovskites (CsPbX3, X = Cl, Br or I) are becoming increasingly important for energy conversion and optoelectronics because of their outstanding performance and enhanced environmental stability. Morphing perovskites into specific shapes and geometries without damaging their intrinsic functional properties is attractive for designing devices and manufacturing. However, inorganic semiconductors are often intrinsically brittle at room temperature, except for some recently reported layered or van der Waals semiconductors. Here, by in situ compression, we demonstrate that single-crystal CsPbX3 micropillars can be substantially morphed into distinct shapes (cubic, L and Z shapes, rectangular arches and so on) without localized cleavage or cracks. Such exceptional plasticity is enabled by successive slips of partial dislocations on multiple [Formula: see text] systems, as evidenced by atomic-resolution transmission electron microscopy and first-principles and atomistic simulations. The optoelectronic performance and bandgap of the devices were unchanged. Thus, our results suggest that CsPbX3 perovskites, as potential deformable inorganic semiconductors, may have profound implications for the manufacture of advanced optoelectronics and energy systems.
RESUMO
In recent years, the GPS wave buoy has been developed for in situ wave monitoring based on satellite GPS signals. Many research works have been completed on the GPS-based wave measurement technology and great progress has been achieved. The basic principle of the GPS wave buoy is to calculate the movement velocity of the buoy using the Doppler frequency shift of satellite GPS signals, and then to calculate the wave parameters from the movement velocity according to ocean wave theory. The shortage of the GPS wave buoy is the occasional occurrence of some unusual values in the movement velocity. This is mainly due to the fact that the GPS antenna is occasionally covered by sea water and cannot normally receive high-quality satellite GPS signals. The traditional solution is to remove these unusual movement velocity values from the records, which requires furthering extend the acquisition time of satellite GPS signals to ensure there is a large enough quantity of effective movement velocity values. Based on the traditional GPS wave measurement technology, this paper presents the algorithmic flow and proposes two improvement measures. On the one hand, the neural network algorithm is used to correct the unusual movement velocity data so that extending the acquisition time of satellite GPS signals is not necessary and battery power is saved. On the other hand, the Gaussian low-pass filter is used to correct the raw directional wave spectrum, which can further eliminate the influence of noise spectrum energy and improve the measurement accuracy. The on-site sea test of the SBF7-1A GPS wave buoy, developed by the National Ocean Technology Center in China, and the gravity-acceleration-type DWR-MKIII Waverider buoy are highlighted in this article. The wave data acquired by the two buoys are analyzed and processed. It can be seen from the processed results that the ocean wave parameters from the two kinds of wave buoys, such as wave height, wave period, wave direction, wave frequency spectrum, and directional wave spectrum, are in good consistency, indicating that the SBF7-1A GPS wave buoy is comparable to the traditional gravity-acceleration-type wave buoy in terms of its accuracy. Therefore, the feasibility and validity of the two improvement measures proposed in this paper are confirmed.
RESUMO
Diamond is not only the hardest material in nature, but is also an extreme electronic material with an ultrawide bandgap, exceptional carrier mobilities, and thermal conductivity. Straining diamond can push such extreme figures of merit for device applications. We microfabricated single-crystalline diamond bridge structures with ~1 micrometer length by ~100 nanometer width and achieved sample-wide uniform elastic strains under uniaxial tensile loading along the [100], [101], and [111] directions at room temperature. We also demonstrated deep elastic straining of diamond microbridge arrays. The ultralarge, highly controllable elastic strains can fundamentally change the bulk band structures of diamond, including a substantial calculated bandgap reduction as much as ~2 electron volts. Our demonstration highlights the immense application potential of deep elastic strain engineering for photonics, electronics, and quantum information technologies.