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Analyzing the autocorrelation function of the fluorescence intensity, we demonstrate that these nanoemitters are characterized by a short value of the mean duration of bright periods (ten to a few hundreds of microseconds). The comparison of the results obtained for samples with different geometries shows that not only the shell thickness is crucial but also the shape of the dot-in-rods. Increasing the shell aspect ratio results in shorter bright periods suggesting that surface traps impact the stability of the fluorescence intensity.
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We investigate graphene-based optical absorbers that exploit guided mode resonances (GMRs) attaining theoretically perfect absorption over a bandwidth of few nanometers (over the visible and near-infrared ranges) with a 40-fold increase of the monolayer graphene absorption. We analyze the influence of the geometrical parameters on the absorption rate and the angular response for oblique incidence. Finally, we experimentally verify the theoretical predictions in a one-dimensional, dielectric grating by placing it near either a metallic or a dielectric mirror, thus achieving very good agreement between numerical predictions and experimental results.
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A one-dimensional dielectric grating, based on a simple geometry, is proposed and investigated to enhance light absorption in a monolayer graphene exploiting guided mode resonances. Numerical findings reveal that the optimized configuration is able to absorb up to 60% of the impinging light at normal incidence for both TE and TM polarizations resulting in a theoretical enhancement factor of about 26 with respect to the monolayer graphene absorption (≈2.3%). Experimental results confirm this behavior showing CVD graphene absorbance peaks up to about 40% over narrow bands of a few nanometers. The simple and flexible design points to a way to realize innovative, scalable and easy-to-fabricate graphene-based optical absorbers.
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Images of semiconductor "dot-in-rods" and their small clusters are studied by measuring the second-order correlation function with a spatially resolving intensified CCD camera. This measurement allows one to distinguish between a single dot and a cluster and, to a certain extent, to estimate the number of dots in a cluster. A more advanced measurement is proposed, based on higher-order correlations, enabling more accurate determination of the number of dots in a small cluster. Nonclassical features of the light emitted by such a cluster are analyzed.
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Flexible and bendable electronics are gaining a lot of interest in these last years. In this scenario, compact antennas on flexible substrates represent a strategical technological step to pave the way to a new class of wearable systems. A crucial issue to overcome is represented by the poor radiation properties of compact antennas, especially in the case of flexible and thin substrates. In this paper, we propose an innovative design of a miniaturized evolved patch antenna whose radiation properties have been enhanced with a Split Ring Resonator (SRR) placed between the top and the ground plane. The antenna has been realized on a flexible and biocompatible substrate polyethylene naphthalate (PEN) of 250 µm by means of a new fabrication protocol that involves a three-layer 3D-inkjet printing and an alignment step. The antenna has been characterized in terms of the scattering parameter S11 and the radiation pattern showing a good agreement between simulations and measurements.
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Eletrônica , Tecnologia sem Fio , ComunicaçãoRESUMO
Herein we describe the realization of nanowalled polymeric microtubes through a novel and versatile approach combining the layer-by-layer (LbL) deposition technique, the self-rolling of hybrid polymer/semiconductor microtubes and the subsequent removal of the semiconductor template. The realized channels were characterized in detail using scanning electron and atomic force microscopes. Additionally, we report on the incorporation of a dye molecule within the nanowalls of such microtubes, demonstrating a distribution of the fluorescence signal throughout the whole channel volume. This approach offers the possibility to tailor the properties of micro/nanotubes in terms of size, wall thickness and composition, thus enabling their employment for several applications.
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Colorimetric and electrochemical (bio)sensors are commonly employed in wearable platforms for sweat monitoring; nevertheless, they suffer from low stability of the sensitive element. In contrast, mass-(bio)sensors are commonly used for analyte detection at laboratory level only, due to their rigidity. To overcome these limitations, a flexible mass-(bio)sensor for sweat pH sensing is proposed. The device exploits the flexibility of piezoelectric AlN membranes fabricated on a polyimide substrate combined to the sensitive properties of a pH responsive hydrogel based on PEG-DA/CEA molecules. A resonant frequency shift is recorded due to the hydrogel swelling/shrinking at several pH. Our device shows a responsivity of about 12 kHz/pH unit when measured in artificial sweat formulation in the pH range 3-8. To the best of our knowledge, this is the first time that hydrogel mass variations are sensed by a flexible resonator, fostering the development of a new class of compliant and wearable devices.
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In integrated optics the radiation modes represent a negative aspect regarding the propagation of guided modes. They characterize the losses of the substrate region but can contribute to enhance the guided modes by considering the coupling through properly designed gratings arranged at the core/substrate interface. By tailored gratings, the radiation modes become propagating modes and increase the guided power inside the waveguide guiding region. This enhancement is useful especially in low intensity processes such as second harmonic chi(2) conversion process. For this purpose, we analyze accurately the radiation modes contribution in a chi(2) GaAs/AlGaAs nonlinear waveguide where second harmonic signal is characterized by a low power intensity. This analysis considers a new design approach of multiple grating which enhances a fundamental guided mode at lambda(FU) =1.55 microm and a codirectional second harmonic guided mode at lambda(SH) =0.775 microm. In particular we analyze the second harmonic conversion efficiency by studying the coupling effect of three gratings. The combined effects of the gratings provide an efficient second harmonic field conversion. Design considerations, based on the coupled mode equations analysis, are theoretically discussed. A good agreement between analytical and numerical results is observed.
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Algoritmos , Desenho Assistido por Computador , Modelos Teóricos , Refratometria/instrumentação , Simulação por Computador , Desenho de Equipamento , Análise de Falha de Equipamento , Luz , Dinâmica não Linear , Refratometria/métodos , Reprodutibilidade dos Testes , Espalhamento de Radiação , Sensibilidade e EspecificidadeRESUMO
Vascular grafts are artificial conduits properly designed to substitute a diseased blood vessel. However prosthetic fail can occur without premonitory symptoms. Continuous monitoring of the system can provide useful information not only to extend the graft's life but also to optimize the patient's therapy. In this respect, various techniques have been used, but all of them affect the mechanical properties of the artificial vessel. To overcome these drawbacks, an ultrathin and flexible smart patch based on piezoelectric Aluminum Nitride (AlN) integrated on the extraluminal surface of the prosthesis is presented. The sensor can be conformally wrapped around the external surface of the prosthesis. Its design, mechanical properties and dimensions are properly characterized and optimized in order to maximize performances and to avoid any interference with the graft structure during its activity. The sensorized graft is tested in vitro using a pulsatile recirculating flow system that mimics the physiological and pathological blood flow conditions. In this way, the ability of the device to measure real-time variations of the hemodynamics parameters has been tested. The obtained high sensitivity of 0.012 V Pa-1 m-2, joint to the inherent biocompatibility and non-toxicity of the used materials, demonstrates that the device can successfully monitor the prosthesis functioning under different conditions, opening new perspectives for real-time vascular graft surveillance.
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Compostos de Alumínio/química , Eletricidade , Enxerto Vascular , Simulação por Computador , Análise de Elementos Finitos , Difração de Raios XRESUMO
We present in this work the scalar potential formulation of second harmonic generation process in chi((2)) nonlinear analysis. This approach is intrinsically well suited to the applications of the concept of circuit analysis and synthesis to nonlinear optical problems, and represents a novel alternative method in the analysis of nonlinear optical waveguide, by providing a good convergent numerical solution. The time domain modeling is applied to nonlinear GaAs asymmetrical waveguide with dielectric discontinuities in the hypothesis of quasi phase matching condition in order to evaluate the efficiency conversion of the second harmonic signal. The accuracy of the modeling is validated by the good agreement with the published experimental results. The effective dielectric constant method allows to extend the analysis also to 3D optical waveguides.
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Arsenicais/química , Desenho Assistido por Computador , Gálio/química , Modelos Teóricos , Óptica e Fotônica/instrumentação , Simulação por Computador , Desenho de Equipamento , Análise de Falha de Equipamento , Luz , Espalhamento de RadiaçãoRESUMO
This work introduces a new simulation approach to the evaluation of the time-domain electromagnetic (EM) field useful in the modeling of tapered waveguide for the Photonic Crystal Slab (PCS) coupling. Only solutions of two scalar Helmholtz-equations are used in the evaluation of electric and magnetic Hertzian-potentials that yields the EM field and the frequency response of the tapered waveguide. By considering simultaneously an analytical and a numerical approximation it is possible to reduce the computational burden. In order to compare the computational time we analyze the 2D structure by also using the Finite Difference Time Domain (FDTD) method and by the 3D Finite Element Method (FEM). The method is applied by starting from design criteria of the tapered structures in order to set the correct geometrical and physical parameters, and considers the field-perturbation effect in proximity of the dielectric discontinuities by generators modeling.
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To enhance today's artificial flow sensing capabilities in aerial and underwater robotics, future robots could be equipped with a large number of miniaturized sensors distributed over the surface to provide high resolution measurement of the surrounding fluid flow. In this work we show a linear array of closely separated bio-inspired micro-electro-mechanical flow sensors whose sensing mechanism is based on a piezoresistive strain-gauge along a stress-driven cantilever beam, mimicking the biological superficial neuromasts found in the lateral line organ of fishes. Aiming to improve state-of-the-art flow sensing capability in autonomously flying and swimming robots, our artificial lateral line system was designed and developed to feature multi-parameter freestream flow measurements which provide information about (1) local flow velocities as measured by the signal amplitudes from the individual cantilevers as well as (2) propagation velocity, (3) linear forward/backward direction along the cantilever beam orientation and (4) periodicity of pulses or pulse trains determined by cross-correlating sensor signals. A real-time capable cross-correlation procedure was developed which makes it possible to extract freestream flow direction and velocity information from flow fluctuations. The computed flow velocities deviate from a commercial system by 0.09 m s(-1) at 0.5 m s(-1) and 0.15 m s(-1) at 1.0 m s(-1) flow velocity for a sampling rate of 240 Hz and a sensor distance of 38 mm. Although experiments were performed in air, the presented flow sensing system can be applied to underwater vehicles as well, once the sensors are embedded in a waterproof micro-electro-mechanical systems package.
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Biomimética/instrumentação , Peixes/fisiologia , Sistema da Linha Lateral/fisiologia , Sistemas Microeletromecânicos/instrumentação , Reologia/instrumentação , Transdutores de Pressão , Animais , Biomimética/métodos , Sistemas Computacionais , Desenho de Equipamento , Análise de Falha de Equipamento , Mecanorreceptores/fisiologia , Reprodutibilidade dos Testes , Sensibilidade e EspecificidadeRESUMO
The authors have recently demonstrated the enhancement of the quantum dot laser modal gain, linearly scaling with the number of stacked QD layers. These results allowed the achievement of multi-quantum dot (MQD) lasers, the zero-dimensional counterpart of MQW lasers, with a modal gain as high as 42 cm(-1), in a seven-layer structure. A detailed investigation of the structural and optical properties was performed on laser structures with three, five and seven QD layers. Such an investigation clearly shows that the high uniformity of QD layer features is responsible for the linear increase of the modal gain and its high value.
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Engineering the spectral properties of fluorophores, such as the enhancement of luminescence intensity, can be achieved through coupling with surface plasmons in metallic nanostructures. This process, referred to as metal-enhanced fluorescence, offers promise for a range of applications, including LEDs, sensor technology, microarrays and single-molecule studies. It becomes even more appealing when applied to colloidal semiconductor nanocrystals, which exhibit size-dependent optical properties, have high photochemical stability, and are characterized by broad excitation spectra and narrow emission bands. Other approaches have relied upon the coupling of fluorophores (typically organic dyes) to random distributions of metallic nanoparticles or nanoscale roughness in metallic films. Here, we develop a new strategy based on the highly reproducible fabrication of ordered arrays of gold nanostructures coupled to CdSe/ZnS nanocrystals dispersed in a polymer blend. We demonstrate the possibility of obtaining precise control and a high spatial selectivity of the fluorescence enhancement process.