Environmental impact of metal halide perovskite solar cells and potential mitigation strategies: A critical review.

Metal halide perovskite solar cells (PSCs) have gained extensive attention in the field of solar photovoltaic technology over the past few years. Despite being a remarkable alternative to fossil fuels, solar cells may have detrimental effects on the environment and human health owing to the use of toxic materials during manufacturing. Although modern metal-halide-based PSCs are stable and have encapsulation to prevent the release of potentially toxic materials into the environment, their destruction due to strong winds, hail, snow, landslides, fires, or waste disposal can result in the exposure of these materials to the environment. This may lead to the contamination of soil and groundwater, and uptake of potentially toxic elements by plants, subsequently affecting humans and other living organisms via food chain contamination. Despite worldwide concern, the environmental and ecotoxicological impacts of metal-halide-based PSCs have not been comprehensively surveyed. This review summarizes and critically evaluates the current status of metal-halide-based PSC production and its impact on environmental sustainability, food security, and human health. Furthermore, safe handling and disposal methods for the waste generated from metal-halide-based PSCs are proposed, with a focus on recycling and reuse. Although some studies have suggested that the amount of lead released from metal halide PSCs is far below the maximum permissible levels in most soils, a clear conclusion cannot be reached until real contamination scenarios are assessed under field conditions. Precautions must be taken to minimize environmental contamination throughout the lifecycle of PSCs until nontoxic and similarly performing alternative solar photovoltaic products are developed.

Effects of microplastics on the terrestrial environment: A critical review.

Microplastics are emerging contaminants and there has been growing concern regarding their impacts on aquatic and terrestrial environments. This review provides a comprehensive overview of the current knowledge regarding the sources, occurrences, fates, and risks associated with microplastic contamination in terrestrial environments. This contamination occurs via multiple sources, including primary microplastics (including synthetic materials) and secondary microplastics (derived from the breakdown of larger plastic particles). Microplastic contamination can have both beneficial and detrimental effects on soil properties. Additionally, microplastics have been shown to interact with a wide array of contaminants, including pesticides, persistent organic pollutants, heavy metals, and antibiotics, and may act as a vector for contaminant transfer in terrestrial environments. Microplastics and their associated chemicals can be transferred through food webs and may accumulate across multiple trophic levels, resulting in potential detrimental health effects for humans and other organisms. Although several studies have focused on the occurrence and impacts of microplastic contamination in marine environments, their sources, fate, transport, and effects in terrestrial environments are less studied and not well understood. Therefore, further research focusing on the fate, transport, and impacts of microplastics in relation to soil properties, polymer composition and forms, and land-use types is needed. The development of standardized and harmonized methods for analyzing microplastics in soil-plant ecosystems is essential. Future work should also consider the many interactions of microplastics with soil quality and ecotoxicological impacts on biota in the context of global environmental change.

Challenges and opportunities in sustainable management of microplastics and nanoplastics in the environment.

The accumulation of microplastics (MPs) and nanoplastics (NPs) in terrestrial and aquatic ecosystems has raised concerns because of their adverse effects on ecosystem functions and human health. Plastic waste management has become a universal problem in recent years. Hence, sustainable plastic waste management techniques are vital for achieving the United Nations Sustainable Development Goals. Although many reviews have focused on the occurrence and impact of micro- and nanoplastics (MNPs), there has been limited focus on the management of MNPs. This review first summarizes the ecotoxicological impacts of plastic waste sources and issues related to the sustainable management of MNPs in the environment. This paper then critically evaluates possible approaches for incorporating plastics into the circular economy in order to cope with the problem of plastics. Pollution associated with MNPs can be tackled through source reduction, incorporation of plastics into the circular economy, and suitable waste management. Appropriate infrastructure development, waste valorization, and economically sound plastic waste management techniques and viable alternatives are essential for reducing MNPs in the environment. Policymakers must pay more attention to this critical issue and implement appropriate environmental regulations to achieve environmental sustainability.

Applied Machine Learning for Prediction of CO2 Adsorption on Biomass Waste-Derived Porous Carbons.

Biomass waste-derived porous carbons (BWDPCs) are a class of complex materials that are widely used in sustainable waste management and carbon capture. However, their diverse textural properties, the presence of various functional groups, and the varied temperatures and pressures to which they are subjected during CO2 adsorption make it challenging to understand the underlying mechanism of CO2 adsorption. Here, we compiled a data set including 527 data points collected from peer-reviewed publications and applied machine learning to systematically map CO2 adsorption as a function of the textural and compositional properties of BWDPCs and adsorption parameters. Various tree-based models were devised, where the gradient boosting decision trees (GBDTs) had the best predictive performance with R2 of 0.98 and 0.84 on the training and test data, respectively. Further, the BWDPCs in the compiled data set were classified into regular porous carbons (RPCs) and heteroatom-doped porous carbons (HDPCs), where again the GBDT model had R2 of 0.99 and 0.98 on the training and 0.86 and 0.79 on the test data for the RPCs and HDPCs, respectively. Feature importance revealed the significance of adsorption parameters, textural properties, and compositional properties in the order of precedence for BWDPC-based CO2 adsorption, effectively guiding the synthesis of porous carbons for CO2 adsorption applications.

New mechanistic insight into rapid adsorption of pharmaceuticals from water utilizing activated biochar.

The presence of emerging pollutants especially hazardous chemicals and pharmaceuticals in aquatic environments is a matter of grave concern to human health and the environment. In this study, coffee bean waste (CBW) was utilized to synthesize pristine (CBW550) and activated (CBW550HPO) biochars for the elimination of diclofenac (DF) and levofloxacin (LEV) from water. A facile two-step approach was used to synthesize CBW550HPO using chemical pretreatment and pyrolysis under N2 purging. BET results of CBW550HPO revealed that chemical pretreatment increased surface area by approximately 160 times compared to CBW550. The calculated ID/IG ratio from Raman spectra confirmed that CBW550HPO had a high functionalized surface. Different operational parameters such as contact time, pH, adsorbent dose, ionic strength, and adsorbate concentration were studied and optimized. Maximum Langmuir adsorption capacity of CBW550HPO was found to be 61.17 and 110.70 mg/g for DF and LVX, respectively. Experimental results demonstrated that presence of NaCl in solution enhanced DF removal efficiency due to the salting-out effect. Electrostatic attraction, π-π bonding, and hydrophobic interaction were prominently responsible mechanisms for the adsorption of DF and LVX. Furthermore, continuous-flow mode studies confirmed that CBW550HPO can be successfully utilized in large-scale treatment applications.

Adsorption and visible-light photocatalytic degradation of organic pollutants by functionalized biochar: Role of iodine doping and reactive species.

Here we developed the functionalized biochar as low-cost and heavy metal-free photocatalysts via a facile iodine doping method, which exhibit efficient adsorption and visible-light-driven photocatalytic degradation of representative organic pollutants, phenol and tetracycline. On one hand, iodine doping elevates the adsorption via creating extra pores, e.g., the adsorbed amounts of phenol by iodine-doped WSP and OSR biochar are increased by 161.8% and 146.3%, respectively, which in turn facilitates the photocatalytic oxidation of the adsorbed pollutants. On the other hand, iodine doping leads to the strong photo-induced excitation and remarkably reduced charge carrier transfer resistance, boosting the photocatalytic activity of iodine-doped biochar by more than 20 orders towards organic pollutants (e.g., phenol) degradation. The systematic analysis of reactive species reveals the active roles of O2-, H2O2, 1O2, OH, electrons, and holes in photocatalytic process and identifies O2- to be the major contributor. This work affords a facile approach to generating porous and visible-light-driven photocatalyst from biomass for efficient adsorbing and degrading organic pollutants, opening up an avenue to turn biowaste into biomaterials for sustainable environmental remediation.

Review on upgrading organic waste to value-added carbon materials for energy and environmental applications.

Value-added materials such as biochar and activated carbon that are produced using thermo-chemical conversion of organic waste have gained an emerging interest for the application in the fields of energy and environment because of their low cost and unique physico-chemical properties. Organic waste-derived materials have multifunctional abilities in the field of environment for capturing greenhouse gases and remediation of contaminated soil and water as well as in the field of energy storage and conversion. This review critically evaluates and discusses the current thermo-chemical approaches for upgrading organic waste to value-added carbon materials, performance enhancement of these materials via activation and/or surface modification, and recent research findings related to energy and environmental applications. Moreover, this review provides detailed guidelines for preparing high-performance organic waste-derived materials and insights for their potential applications. Key challenges associated with the sustainable management of organic waste for ecological and socio-economic benefits and potential solutions are also discussed.

Redox-mediated changes in the release dynamics of lead (Pb) and bacterial community composition in a biochar amended soil contaminated with metal halide perovskite solar panel waste.

This study explored the redox-mediated changes in a lead (Pb) contaminated soil (900 mg/kg) due to the addition of solar cell powder (SC) and investigated the impact of biochar derived from soft wood pellet (SWP) and oil seed rape straw (OSR) (5% w/w) on Pb immobilization using an automated biogeochemical microcosm system. The redox potential (Eh) of the untreated (control; SC) and biochar treated soils (SC + SWP and SC + OSR) ranged from -151 mV to +493 mV. In SC, the dissolved Pb concentrations were higher under oxic (up to 2.29 mg L-1) conditions than reducing (0.13 mg L-1) conditions. The addition of SWP and OSR to soil immobilized Pb, decreased dissolved concentration, which could be possibly due to the increase of pH, co-precipitation of Pb with FeMn (hydro)oxides and pyromorphite, and complexation with biochar surface functional groups. The ability and efficiency of OSR for Pb immobilization were higher than SWP, owing to the higher pH and density of surface functional groups of OSR than SWP. Biochar enhanced the relative abundance of Proteobacteria irrespective of Eh changes, while the relative abundance of Bacteroidota increased under oxidizing conditions. Overall, we found that both OSR and SWP immobilized Pb in solar panel waste contaminated soil under both oxidizing and reducing redox conditions which may mitigate the potential risk of Pb contamination.

Converting food waste into soil amendments for improving soil sustainability and crop productivity: A review.

One-third of the annual food produced globally is wasted and much of the food waste (FW) is unutilized; however, FW can be valorized into value-added industrial products such as biofuel, chemicals, and biomaterials. Converting FW into soil amendments such as compost, vermicompost, anaerobic digestate, biofertilizer, biochar, and engineered biochar is one of the best nutrient recovery and FW reuse approaches. The soil application of FW-based amendments can improve soil fertility, increase crop production, and reduce contaminants by altering soil's chemical, physical, microbial, and faunal properties. However, the efficiency of the amendment for improving ecosystem sustainability depends on the type of FW, conversion method, application rate, soil type, and crop type. Engineered biochar/biochar composite materials produced using FW have been identified as promising amendments for soil remediation, reducing commercial fertilizer usage, and increasing soil nutrient use efficiency. The development of quality standards and implementation of policies and regulations at all stages of the food supply chain are necessary to manage (reduce and re-use) FW.

Preparation and thermal conductivity enhancement of a paraffin wax-based composite phase change material doped with garlic stem biochar microparticles.

The addition of thermally conductive nanomaterials is an effective strategy for increasing the thermal conductivity of phase change materials (PCMs). However, nanomaterials are expensive and may significantly reduce the latent heat capacity of PCMs. In this study, low-cost and eco-friendly biochar microparticles were prepared from garlic stems, a common food waste in Singapore. The thermal properties of paraffin wax (PW) doped with 1, 3, and 5 wt% garlic stem biochar (GSB) microparticles were investigated. The GSB microparticles prepared at 700 °C had three-dimensional porous and two-dimensional flake-like structures, which contributed to the formation of additional heat transfer pathways in the PW. The addition of 5 wt% GSB microparticles enhanced the thermal conductivity of PW by 27.3% and 7.2% in the solid and liquid phases, respectively. The T-history test revealed that the melting and solidification rates of PW improved by 90 and 115 s, respectively. The improved heat transfer performance was mainly ascribed to the high degree of graphitization and the interconnected porous carbon structure of the GSB microparticles. The phase change temperatures of PW were slightly changed upon the addition of GSB microparticles, and the latent heat capacity was only reduced by 6.1%. These results suggest that the GSB microparticles can be used as a potential alternative to other nanoadditives such as metal- and metal oxide-based nanoadditives.

Biochar utilisation in the anaerobic digestion of food waste for the creation of a circular economy via biogas upgrading and digestate treatment.

A wood waste-derived biochar was applied to food-waste anaerobic digestion to evaluate the feasibility of its utilisation to create a circular economy. This biochar was first purposed for the upgrading of the biogas from the said anaerobic digestion, before treating and recovering the nutrients in the solid fraction of the digestate, which was finally employed as a biofertilizer for the organic cultivation of three green leafy vegetables: kale, lettuce and rocket salad. Whilst the amount of CO2 the biochar could absorb from the biogas was low (11.17 mg g-1), it could potentially be increased by modifying through physical and chemical methods. Virgin as well as CO2-laden biochar were able to remove around 31% of chemical oxygen demand, 8% of the ammonia and almost 90% of the total suspended solids from the digestate wastewater, which was better than a dewatering process via centrifugation but worse than the industry standard of a polytetrafluoroethylene membrane bioreactor. Nutrients were recovered in the solid fraction of the digestate residue filtered by the biochar, and utilised as a biofertilizer that performed similarly to a commercial complete fertilizer in terms of aerial fresh weight growth for all three vegetables cultivated. Contingent on the optimal upgrading of biogas, the concept of a circular economy based on biochar and anaerobic digestion appears to be feasible.

Carbon dioxide capture in biochar produced from pine sawdust and paper mill sludge: Effect of porous structure and surface chemistry.

The CO2 concentration in the atmosphere is increasing and threatening the earth's climate. Selective CO2 capture at large point sources will help to reduce the CO2 emissions to the atmosphere. Biochar with microporous structure could be a potential material to capture CO2. The impact of feedstock type, pyrolysis temperature and steam activation of biochars were evaluated for CO2 adsorption capacity. Pine sawdust biochars were produced at 550 °C, and steam activated for 45 min at the same temperature after completing the pyrolysis (PS550 and PSS550). Paper mill sludge biochars were produced at 300 and 600 °C (PMS300 and PMS600). The CO2 adsorption capacity of biochars was tested at 25 °C using a volumetric sorption analyzer. Pine sawdust biochars showed significantly higher CO2 adsorption capacity than paper mill sludge biochars due to high surface area and microporosity. Pine sawdust biochars were then evaluated for dynamic adsorption under representative post-combustion flue gas concentration conditions (15% CO2, 85% N2) using a breakthrough rig. Both materials showed selective CO2 uptake over N2 which is the major component along with CO2 in flue gas. PSS550 had slightly higher CO2 adsorption capacity (0.73 mmol g^-1 vs 0.67 mmol g^-1) and CO2 over N2 selectivity (26 vs 18) than PS550 possibly due to increase of microporosity, surface area, and oxygen containing basic functional groups through steam activation. Pine sawdust biochar is an environmentally friendly and low-cost material to capture CO2.

Gasification biochar from biowaste (food waste and wood waste) for effective CO2 adsorption.

Biochar is newly proposed as an innovative and cost-effective material to capture CO2. In this study, biochar was produced from feedstock mixtures of food waste and wood waste (i.e., 20%:80% WFW20, 30%:70% WFW30 and 40%:60% WFW40) by gasification. The two biochar adsorbents containing the highest percentage of food waste, i.e., WFW40-K and WFW40-KC, were activated by KOH and KOH + CO2, respectively. The biochar adsorbents were then tested for CO2 adsorption at room temperature of 25 °C by using a volumetric sorption analyzer. The WFW20 showed the highest CO2 adsorption capacity, while higher percentage of food waste in the feedstock was unfavorable for the CO2 adsorption. The presence of N and S on the biochar surface was the primary contributor to the high CO2 uptake on WFW20. The development of micropores by KOH activation significantly increased the CO2 adsorption on WFW40-K, but KOH + CO2 activation could not further increase the development of micropores and subsequent CO2 adsorption. Moreover, WFW40-K showed >99% recyclability during 10 consecutive adsorption-desorption cycles. The biochars derived from biowaste (food waste and wood waste) could be effective adsorbents for CO2 capture by providing green solution for food waste recycling.