Kondo-Induced Giant Isotropic Negative Thermal Expansion.

Negative thermal expansion is an unusual phenomenon appearing in only a handful of materials, but pursuit and mastery of the phenomenon holds great promise for applications across disciplines and industries. Here we report use of x-ray spectroscopy and diffraction to investigate the 4f-electronic properties in Y-doped SmS and employ the Kondo volume collapse model to interpret the results. Our measurements reveal an unparalleled decrease of the bulk Sm valence by over 20% at low temperatures in the mixed-valent golden phase, which we show is caused by a strong coupling between an emergent Kondo lattice state and a large isotropic volume change. The amplitude and temperature range of the negative thermal expansion appear strongly dependent on the Y concentration and the associated chemical disorder, providing control over the observed effect. This finding opens avenues for the design of Kondo lattice materials with tunable, giant, and isotropic negative thermal expansion.

Surface-dominated conduction up to 240 K in the Kondo insulator SmB6 under strain.

SmB6 is a strongly correlated mixed-valence Kondo insulator with a newly discovered surface state, proposed to be of non-trivial topological origin. However, the surface state dominates electrical conduction only below T∗ ≈ 4 K (ref. ), limiting its scientific investigation and device application. Here, we report the enhancement of T∗ in SmB6 under the application of tensile strain. With 0.7% tensile strain we report surface-dominated conduction at up to a temperature of 240 K, persisting even after the strain has been removed. This can be explained in the framework of strain-tuned temporal and spatial fluctuations of f-electron configurations, which might be generally applied to other mixed-valence materials. We note that this amount of strain can be induced in epitaxial SmB6 films via substrate in potential device applications.

Vanishing RKKY interactions in Ce-based cage compounds.

We report the results of thermodynamic measurements in external magnetic field of the cubic Ce-based cage compounds CeT2Cd20(T= Ni,Pd). Our analysis of the heat-capacity data shows that the Γ7doublet is the ground state multiplet of the Ce3+ions. Consequently, for the Γ7doublet it can be theoretically shown that the Ruderman-Kittel-Kasuya-Yosida interaction between the localized Ce moments mediated by the conduction electrons, must vanish at temperatures much lower than the energy separating the ground state doublet from the first excited Γ8quartet. Our findings provide an insight as to why no long range order has been observed in these compounds down to temperatures in the milliKelvin range.

Strong magnetic fluctuations in a superconducting state of CeCoIn5.

We show results on the vortex core dissipation through current-voltage measurements under applied pressure and magnetic field in the superconducting phase of CeCoIn{5}. We find that as soon as the system becomes superconducting, the vortex core resistivity increases sharply as the temperature and magnetic field decrease. The sharp increase in flux-flow resistivity is due to quasiparticle scattering on critical antiferromagnetic fluctuations. The strength of magnetic fluctuations below the superconducting transition suggests that magnetism is complementary to superconductivity and therefore must be considered in order to fully account for the low-temperature properties of CeCoIn{5}.

Electron cotunneling into a Kondo lattice.

Motivated by recent experimental interest in tunneling into heavy-electron materials, we present a theory for electron tunneling into a Kondo lattice. The passage of an electron into a Kondo lattice is accompanied by a simultaneous spin flip of the localized moments via cotunneling mechanism. We compute the tunneling current with the large-N mean field theory. In the absence of disorder, differential tunneling conductance exhibits two peaks separated by the hybridization gap. Disorder effects lead to the smearing of the gap resulting in a Fano line shape.

Spectroscopic signatures of nonequilibrium pairing in atomic fermi gases.

We determine the radio-frequency (rf) spectra for nonstationary states of a fermionic condensate produced by a rapid switch of the scattering length. The rf spectrum of the nonequilibrium state with constant BCS order parameter has two features in contrast with equilibrium where there is a single peak. The additional feature reflects the presence of excited pairs in the steady state. In the state characterized by periodically oscillating order parameter, the rf-absorption spectrum contains two sequences of peaks spaced by the frequency of oscillations. Satellite peaks appear due to a process where a rf photon in addition to breaking a pair emits or absorbs oscillation quanta.

Quantum critical end point for the Kondo volume collapse model.

The Kondo volume collapse describes valence transitions in f-electron metals and is characterized by a line of first order transitions in the pressure-temperature phase plane terminated at critical end points. We analyze the quantum critical end point, when the lower end point is tuned to T=0, and determine the specific heat, thermal expansion, and compressibility. We find that the inclusion of quantum critical fluctuations leads to a novel bifurcation of the first order phase line. Finally, we show that critical strain fluctuations can cause both, superconductivity and non-Fermi liquid behavior near the critical point.