Hydrogen Storage by Reduction of CO2 to Synthetic Hydrocarbons.

The storage of renewable energy is crucial for the substitution of fossil fuels with renewable energy. Hydrogen is the first step in the conversion of electricity from renewable sources to an energy carrier. However, hydrogen is technically and economically challenging to store, but can be converted with CO2 from the atmosphere or oceans to hydrocarbons. The heterogeneously catalyzed gas phase reaction and the electrochemical CO2 reduction are reviewed and the application of a new type of reactor is described. The mechanism of the gas phase CO2 reduction on a heterogeneous catalyst is shown in detail and the function of the supported catalyst is explained. Finally, an economic estimation on the cost of synthetic methane is presented which leads to a cost of 0.3 CHF/kWh in CH4.

Sorption enhanced CO2 methanation.

The transformation from the fatuous consumption of fossil energy towards a sustainable energy circle is most easily marketable by not changing the underlying energy carrier but generating it from renewable energy. Hydrocarbons can be principally produced from renewable hydrogen and carbon dioxide collected by biomass. However, research is needed to increase the energetic and economic efficiency of the process. We demonstrate the enhancement of CO2 methanation by sorption enhanced catalysis. The preparation and catalytic activity of sorption catalysts based on Ni particles in zeolites is reported. The functioning of the sorption catalysis is discussed together with the determination of the reaction mechanism, providing implications for new ways in catalysis.