Surface atom knockout for the active site exposure of alloy catalyst.

The fine regulation of catalysts by the atomic-level removal of inactive atoms can promote the active site exposure for performance enhancement, whereas suffering from the difficulty in controllably removing atoms using current micro/nano-scale material fabrication technologies. Here, we developed a surface atom knockout method to promote the active site exposure in an alloy catalyst. Taking Cu3Pd alloy as an example, it refers to assemble a battery using Cu3Pd and Zn as cathode and anode, the charge process of which proceeds at about 1.1 V, equal to the theoretical potential difference between Cu2+/Cu and Zn2+/Zn, suggesting the electricity-driven dissolution of Cu atoms. The precise knockout of Cu atoms is confirmed by the linear relationship between the amount of the removed Cu atoms and the battery cumulative specific capacity, which is attributed to the inherent atom-electron-capacity correspondence. We observed the surface atom knockout process at different stages and studied the evolution of the chemical environment. The alloy catalyst achieves a higher current density for oxygen reduction reaction compared to the original alloy and Pt/C. This work provides an atomic fabrication method for material synthesis and regulation toward the wide applications in catalysis, energy, and others.

Transcriptomic and Metabolic Analysis Reveals Genes and Pathways Associated with Flesh Pigmentation in Potato (Solanum tuberosum) Tubers.

Anthocyanins, flavonoid pigments, are responsible for the purple and red hues in potato tubers. This study analyzed tubers from four potato cultivars-red RR, purple HJG, yellow QS9, and white JZS8-to elucidate the genetic mechanisms underlying tuber pigmentation. Our transcriptomic analysis identified over 2400 differentially expressed genes between these varieties. Notably, genes within the flavonoid biosynthesis pathway were enriched in HJG and RR compared to the non-pigmented JZS8, correlating with their higher levels of anthocyanin precursors and related substances. Hierarchical clustering revealed inverse expression patterns for the key genes involved in anthocyanin metabolism between pigmented and non-pigmented varieties. Among these, several MYB transcription factors displayed strong co-expression with anthocyanin biosynthetic genes, suggesting a regulatory role. Specifically, the expression of 16 MYB genes was validated using qRT-PCR to be markedly higher in pigmented HJG and RR versus JZS8, suggesting that these MYB genes might be involved in tuber pigmentation. This study comprehensively analyzed the transcriptome of diverse potato cultivars, highlighting specific genes and metabolic pathways involved in tuber pigmentation. These findings provide potential molecular targets for breeding programs focused on enhancing tuber color.

Microfluidic-Assisted Self-Assembly of Molecular Hydrogelator at Water-Water Interfaces for Continuous Fabrication of Supramolecular Microcapsules.

Control over the self-assembly of small molecules at specific areas is of great interest for many high-tech applications, yet remains a formidable challenge. Here, how the self-assembly of hydrazone-based molecular hydrogelators can be specifically triggered at water-water interfaces for the continuous fabrication of supramolecular microcapsules by virtue of the microfluidic technique is demonstrated. The non-assembling hydrazide- and aldehyde-based hydrogelator precursors are distributed in two immiscible aqueous polymer solutions, respectively, through spontaneous phase separation. In the presence of catalysts, hydrazone-based hydrogelators rapidly form and self-assemble into hydrogel networks at the generated water-water interfaces. Relying on the microfluidic technique, microcapsules bearing a shell of supramolecular hydrogel are continuously produced. The obtained microcapsules can effectively load enzymes, enabling localized enzymatic growth of supramolecular fibrous supramolecular structures, reminiscent of the self-assembly of biological filaments within living cells. This work may contribute to the development of biomimetic supramolecular carriers for applications in biomedicine and fundamental research, for instance, the construction of protocells.

An Adaptive and Automatic Power Supply Distribution System with Active Landmarks for Autonomous Mobile Robots.

With the development of automation and intelligent technologies, the demand for autonomous mobile robots in the industry has surged to alleviate labor-intensive tasks and mitigate labor shortages. However, conventional industrial mobile robots' route-tracking algorithms typically rely on passive markers, leading to issues such as inflexibility in changing routes and high deployment costs. To address these challenges, this study proposes a novel approach utilizing active landmarks-battery-powered luminous landmarks that enable robots to recognize and adapt to flexible navigation requirements. However, the reliance on batteries necessitates frequent recharging, prompting the development of an automatic power supply system. This system integrates omnidirectional contact electrodes on mobile robots, allowing to recharge active landmarks without precise positional alignment. Despite these advancements, challenges such as the large size of electrodes and non-adaptive battery charging across landmarks persist, affecting system efficiency. To mitigate these issues, this research focuses on miniaturizing active landmarks and optimizing power distribution among landmarks. The experimental results of this study demonstrated the effectiveness of our automatic power supply method and the high accuracy of landmark detection. Our power distribution calculation method can adaptively manage energy distribution, improving the system's persistence by nearly three times. This study aims to enhance the practicality and efficiency of mobile robot remote control systems utilizing active landmarks by simplifying installation processes and extending operational durations with adaptive and automatic power supply distribution.

Regulated Dual Defects of Bridging Organic and Terminal Inorganic Ligands in Iron-based Metal-Organic Framework Nodes for Efficient Photocatalytic Ammonia Synthesis.

Engineering advantageous defects to construct well-defined active sites in catalysts is promising but challenging to achieve efficient photocatalytic NH3 synthesis from N2 and H2O due to the chemical inertness of N2 molecule. Here, we report defective Fe-based metal-organic framework (MOF) photocatalysts via a non-thermal plasma-assisted synthesis strategy, where their NH3 production capability is synergistically regulated by two types of defects, namely, bridging organic ligands and terminal inorganic ligands (OH- and H2O). Specially, the optimized MIL-100(Fe) catalysts, where there are only terminal inorganic ligand defects and coexistence of dual defects, exhibit the respective 1.7- and 7.7-fold activity enhancement comparable to the pristine catalyst under visible light irradiation. As revealed by experimental and theoretical calculation results, the dual defects in the catalyst induce the formation of abundant and highly accessible coordinatively unsaturated Fe active sites and synergistically optimize their geometric and electronic structures, which favors the injection of more d-orbital electrons in Fe sites into the N2 π* antibonding orbital to achieve N2 activation and the formation of a key intermediate *NNH in the reaction. This work provides a guidance on the rational design and accurate construction of porous catalysts with precise defective structures for high-performance activation of catalytic molecules.

Plasma-Driven Efficient Conversion of CO2 and H2O into Pure Syngas with Controllable Wide H2/CO Ratios over Metal-Organic Frameworks Featuring In Situ Evolved Ligand Defects.

While the mild production of syngas (a mixture of H2 and CO) from CO2 and H2O is a promising alternative to the coal-based chemical engineering technologies, the inert nature of CO2 molecules, unfavorable splitting pathways of H2O and unsatisfactory catalysts lead to the challenge in the difficult integration of high CO2 conversion efficiency with produced syngas with controllable H2/CO ratios in a wide range. Herein, we report an efficient plasma-driven catalytic system for mild production of pure syngas over porous metal-organic framework (MOF) catalysts with rich confined H2O molecules, where their syngas production capacity is regulated by the in situ evolved ligand defects and the plasma-activated intermediate species of CO2 molecules. Specially, the Cu-based catalyst system achieves 61.9 % of CO2 conversion and the production of pure syngas with wide H2/CO ratios of 0.05 : 1-4.3 : 1. As revealed by the experimental and theoretical calculation results, the in situ dynamic structure evolution of Cu-containing MOF catalysts favors the generation of coordinatively unsaturated metal active sites with optimized geometric and electronic characteristics, the adsorption of reactants, and the reduced energy barriers of syngas-production potential-determining steps of the hydrogenation of CO2 to *COOH and the protonation of H2O to *H.

A Residual Network and FPGA Based Real-Time Depth Map Enhancement System.

Depth maps obtained through sensors are often unsatisfactory because of their low-resolution and noise interference. In this paper, we propose a real-time depth map enhancement system based on a residual network which uses dual channels to process depth maps and intensity maps respectively and cancels the preprocessing process, and the algorithm proposed can achieve real-time processing speed at more than 30 fps. Furthermore, the FPGA design and implementation for depth sensing is also introduced. In this FPGA design, intensity image and depth image are captured by the dual-camera synchronous acquisition system as the input of neural network. Experiments on various depth map restoration shows our algorithms has better performance than existing LRMC, DE-CNN and DDTF algorithms on standard datasets and has a better depth map super-resolution, and our FPGA completed the test of the system to ensure that the data throughput of the USB 3.0 interface of the acquisition system is stable at 226 Mbps, and support dual-camera to work at full speed, that is, 54 fps@ (1280 × 960 + 328 × 248 × 3).

Optimized DFT-spread OFDM based visible light communications with multiple lighting sources.

Discrete Fourier transform spread orthogonal frequency-division multiplexing (DFT-S-OFDM) has demonstrated its capability in reducing peak to average ratio (PAPR), while maintaining reliable transmissions. This paper investigates the application of DFT-S-OFDM technology in visible light communications (VLC), and reveals the mechanism on how a multiple lighting distributed layout affects its performance. In addition, an optimization approach of lighting layout is proposed through making a trade-off between the strong interfered areas and the maximum delay spread inside. Eventually, a Gbit/s DFT-S-OFDM based multiple lighting VLC downlink prototype is achieved for the first time in the form of real-time baseband modem and compact size components.

Experimental investigation on the nonlinear tolerance of root M-shaped pulse in spectrally efficient coherent transmissions.

We experimentally demonstrate improved intra-channel nonlinearity tolerance of the root M-shaped pulse (RMP) with respect to the root raised cosine (RRC) pulse in spectrally efficient 128 Gbit/s PDM-16QAM coherent transmission systems. In addition we evaluate the impact of dispersion map and fiber dispersion parameter on the intra-channel nonlinearity tolerance of the RRC pulse and the RMP via both simulation and experimentation. The RMP is shown to have a better nonlinear tolerance than the RRC pulse for most investigated scenarios except for links with zero residual dispersion percentage per span or the zero dispersion region of a fiber. Therefore, the RMP is suitable for extending the maximum reach of spectrally efficient coherent transmission systems in legacy links in addition to currently intensively studied standard single mode fiber (SSMF) based dispersion unmanaged links.

Experimental study of PAM-4, CAP-16, and DMT for 100 Gb/s short reach optical transmission systems.

Advanced modulation formats combined with digital signal processing and direct detection is a promising way to realize high capacity, low cost and power efficient short reach optical transmission system. In this paper, we present a detailed investigation on the performance of three advanced modulation formats for 100 Gb/s short reach transmission system. They are PAM-4, CAP-16 and DMT. The detailed digital signal processing required for each modulation format is presented. Comprehensive simulations are carried out to evaluate the performance of each modulation format in terms of received optical power, transmitter bandwidth, relative intensity noise and thermal noise. The performance of each modulation format is also experimentally studied. To the best of our knowledge, we report the first demonstration of a 112 Gb/s transmission over 10km of SSMF employing single band CAP-16 with EML. Finally, a comparison of computational complexity of DSP for the three formats is presented.

Polarization-interleave-multiplexed discrete multi-tone modulation with direct detection utilizing MIMO equalization.

Discrete multi-tone (DMT) modulation is an attractive modulation format for short-reach applications to achieve the best use of available channel bandwidth and signal noise ratio (SNR). In order to realize polarization-multiplexed DMT modulation with direct detection, we derive an analytical transmission model for dual polarizations with intensity modulation and direct diction (IM-DD) in this paper. Based on the model, we propose a novel polarization-interleave-multiplexed DMT modulation with direct diction (PIM-DMT-DD) transmission system, where the polarization de-multiplexing can be achieved by using a simple multiple-input-multiple-output (MIMO) equalizer and the transmission performance is optimized over two distinct received polarization states to eliminate the singularity issue of MIMO demultiplexing algorithms. The feasibility and effectiveness of the proposed PIM-DMT-DD system are investigated via theoretical analyses and simulation studies.

40 Gb/s CAP32 short reach transmission over 80 km single mode fiber.

We present a method to mitigate the chromatic dispersion (CD)-induced power fading effect (PFE) in high-speed and short-reach carrier-less amplitude and phase (CAP) systems using the degenerate four-wave mixing (DFWM) effect and a decision feedback equalizer (DFE). Theoretical and numerical investigations reveal that DFWM components produced by the interaction between the main carrier and the signal sideband help to mitigate PFE in direct detection systems. By optimizing the launch power, a maximum reach of 60 km in single mode fiber (SMF-e + ) at 1530nm is experimentally demonstrated for a 40 Gbit/s CAP32 system. In addition, we study the performance of a decision feedback equalizer (DFE) and a traditional linear equalizer (LE) in a channel with non-flat in-band frequency response. The superior PFE tolerance of DFE is experimentally validated, and thereby, the maximum reach is extended to 80 km. To the best of our knowledge, this is the twice the longest transmission distance reported so far for a single-carrier 40 Gbit/s CAP system around 1550 nm.

Digital subcarrier multiplexing for fiber nonlinearity mitigation in coherent optical communication systems.

In this work we experimentally investigate the improved intra-channel fiber nonlinearity tolerance of digital subcarrier multiplexed (SCM) signals in a single-channel coherent optical transmission system. The digital signal processing (DSP) for the generation and reception of the SCM signals is described. We show experimentally that the SCM signal with a nearly-optimum number of subcarriers can extend the maximum reach by 23% in a 24 GBaud DP-QPSK transmission with a BER threshold of 3.8 × 10(-3) and by 8% in a 24 GBaud DP-16-QAM transmission with a BER threshold of 2 × 10(-2). Moreover, we show by simulations that the improved performance of SCM signals is observed over a wide range of baud rates, further indicating the merits of SCM signals in baud-rate flexible agile transmissions and future high-speed optical transport systems.

Non-data-aided and universal cycle slip detection and correction for coherent communication systems.

We propose a simple non-data-aided (or unsupervised) and universal cycle slip detection and correction (CS-DC) technique based on locating the minimum of the sliding average of twice estimated phase noise. The CS-DC can be appended to any carrier phase estimation(CPE) technique and is modulation format independent. We analytically derive the probability density function of the CS detection metric and study how the sliding window length and detection threshold affects CS detection performance. Simulation results reveal significant cycle slips reduction for various modulation formats with a residual CS probability of 2 × 10-7 for single carrier system even in unrealistic highly nonlinear system setups. In addition, we show that a second stage of CS-DC with a different sliding window length can further reduce the cycle slip probability by at least an order of magnitude. We also show that CS-DC is tolerant to inter-channel nonlinearities and residue frequency offset effects. Overall, the proposed CS-DC technique can be used in conjunction to other CS reduction techniques to maximize the ability of CS mitigation in next generation optical transceivers.

Modulation-format-independent blind phase search algorithm for coherent optical square M-QAM systems.

Modulation format independence is one of the key challenges in digital signal processing (DSP) techniques for future elastic optical transmissions. We proposed a modulation-format-independent blind phase search (MFI-BPS) algorithm for square M-ary quadrature amplitude modulation (M-QAM) systems, in which modulation format recognition (MFR) and carrier phase estimation (CPE), are included and implemented both in a feed-forward manner. Comprehensive simulation and the experimental studies on 224 Gbit/s polarization multiplexing 16-QAM (PM-16QAM) systems demonstrate the feasibility and the effectiveness of the proposed MFI-BPS algorithm.

Low overhead and nonlinear-tolerant adaptive zero-guard-interval CO-OFDM.

We propose an adaptive channel estimation (CE) method for zero-guard-interval (ZGI) coherent optical (CO)-OFDM systems, and demonstrate its performance in a single channel 28 Gbaud polarization-division multiplexed ZGI CO-OFDM experiment with only 1% OFDM processing overhead. We systematically investigate its robustness against various transmission impairments including residual chromatic dispersion, polarization-mode dispersion, state of polarization rotation, sampling frequency offset and fiber nonlinearity. Both experimental and numerical results show that the adaptive CE-aided ZGI CO-OFDM is highly robust against these transmission impairments in fiber optical transmission systems.

Decision-aided sampling frequency offset compensation for reduced-guard-interval coherent optical OFDM systems.

We propose a decision-aided algorithm to compensate the sampling frequency offset (SFO) between the transmitter and receiver for reduced-guard-interval (RGI) coherent optical (CO) OFDM systems. In this paper, we first derive the cyclic prefix (CP) requirement for preventing OFDM symbols from SFO induced inter-symbol interference (ISI). Then we propose a new decision-aided SFO compensation (DA-SFOC) algorithm, which shows a high SFO tolerance and reduces the CP requirement. The performance of DA-SFOC is numerically investigated for various situations. Finally, the proposed algorithm is verified in a single channel 28 Gbaud polarization division multiplexing (PDM) RGI CO-OFDM experiment with QPSK, 8 QAM and 16 QAM modulation formats, respectively. Both numerical and experimental results show that the proposed DA-SFOC method is highly robust against the standard SFO in optical fiber transmission.

Spatiotemporal control over self-assembly of supramolecular hydrogels through reaction-diffusion.

Supramolecular self-assembly is ubiquitous in living system and is usually controlled to proceed in time and space through sophisticated reaction-diffusion processes, underpinning various vital cellular functions. In this contribution, we demonstrate how spatiotemporal self-assembly of supramolecular hydrogels can be realized through a simple reaction-diffusion-mediated transient transduction of pH signal. In the reaction-diffusion system, a relatively faster diffusion of acid followed by delayed enzymatic production and diffusion of base from the opposite site enables a transient transduction of pH signal in the substrate. By coupling such reaction-diffusion system with pH-sensitive gelators, dynamic supramolecular hydrogels with tunable lifetimes are formed at defined locations. The hydrogel fibers show interesting dynamic growing behaviors under the regulation of transient pH signal, reminiscent of their biological counterpart. We further demonstrate a proof-of-concept application of the developed methodology for dynamic information encoding in a soft substrate. We envision that this work may provide a potent approach to enable transient transduction of various chemical signals for the construction of new colloidal materials with the capability to evolve their structures and functionalities in time and space.

Facile Electret-Based Self-Powered Soft Sensor for Noncontact Positioning and Information Translation.

Noncontact sensors have demonstrated significant potential in human-machine interactions (HMIs) in terms of hygiene and less wear and tear. The development of soft, stable, and simply structured noncontact sensors is highly desired for their practical applications in HMIs. This work reports on electret-based self-powered noncontact sensors that are soft, transparent, stable, and easy to manufacture. The sensors contain a three-layer structure with a thickness of 0.34 mm that is fabricated by simply stacking a polymeric electret layer, an electrode layer, and a substrate layer together. The fabricated sensors show high charge-retention capability, keeping over 98% of the initial surface potential even after 90 h, and can accurately and repeatedly sense external approaching objects with impressive durability. The intensity of the detected signal shows a strong dependence on the distance between the object and the sensor, capable of sensing a distance as small as 2 mm. Furthermore, the sensors can report stable signals in response to external objects over 3000 cycles. By virtue of the signal dependence on distance, an intelligent noncontact positioning system is developed that can precisely detect the location of an approaching object. Finally, by integrating with eyeglasses, the transparent sensor successfully captures the movements of blinks for information translation. This work may contribute to the development of stable and easily manufactured noncontact soft sensors for HMI applications, for instance, assisting with communication for locked-in syndrome patients.

Experimental demonstration of 10 Gb/s multi-level carrier-less amplitude and phase modulation for short range optical communication systems.

Carrier-less amplitude and phase (CAP) modulation can be a good candidate for short range optical communications for considerable computational complexity reduction and simple system structure. In this paper, a detailed investigation on the digital filters in CAP modulation system is presented. An adaptive equalizer based on cascaded multi-modulus algorithm (CMMA) is used for the demodulation at the receiver. The impact of digital filter taps on system performance is investigated through comprehensive simulations and a 10 Gb/s CAP16 modulation system is demonstrated experimentally. The BER performance for different length of fiber link is measured. Compared with back-to-back (BTB) transmissions, 2 dB and 3.5 dB receiver power penalty are observed at BER of 10(-3) for 20 km and 40 km fiber link respectively. It clearly demonstrates the feasibility of the CAP16 modulation for the short range transmission systems.