RESUMO
The electronic configuration of transition metal centers and their ligands is crucial for redox reactions in metal catalysis and electrochemistry. We characterize the electronic structure of gas-phase nickel monohalide cations via nickel L2,3-edge X-ray absorption spectroscopy. Comparison with multiplet charge-transfer simulations and experimental spectra of selectively prepared nickel monocations in both ground- and excited-state configurations are used to facilitate our analysis. Only for [NiF]+ with an assigned ground state of 3Π can the bonding be described as predominantly ionic, while the heavier halides with assigned ground states of 3Π or 3Δ exhibit a predominantly covalent contribution. The increase in covalency is accompanied by a transition from a classical ligand field for [NiF]+ to an inverted ligand field for [NiCl]+, [NiBr]+, and [NiI]+, resulting in a leading 3d9 L̲ configuration with a ligand hole (L̲) and a 3d occupation indicative of nickel(I) compounds. Hence, the absence of a ligand hole in [NiF]+ precludes any ligand-based redox reactions. Additionally, we demonstrate that the shift in energy of the L3 resonance is reduced compared to that of isolated atoms upon the formation of covalent compounds.
RESUMO
Metal centers in transition metal-ligand complexes occur in a variety of oxidation states causing their redox activity and therefore making them relevant for applications in physics and chemistry. The electronic state of these complexes can be studied by X-ray absorption spectroscopy, which is, however, due to the complex spectral signature not always straightforward. Here, we study the electronic structure of gas-phase cationic manganese acetylacetonate complexes Mn(acac)1-3+ using X-ray absorption spectroscopy at the metal center and ligand constituents. The spectra are well reproduced by multiconfigurational wave function theory, time-dependent density functional theory as well as parameterized crystal field and charge transfer multiplet simulations. This enables us to get detailed insights into the electronic structure of ground-state Mn(acac)1-3+ and extract empirical parameters such as crystal field strength and exchange coupling from X-ray excitation at both the metal and ligand sites. By comparison to X-ray absorption spectra of neutral, solvated Mn(acac)2,3 complexes, we also show that the effect of coordination on the L3 excitation energy, routinely used to identify oxidation states, can contribute about 40-50% to the observed shift, which for the current study is 1.9 eV per oxidation state.
RESUMO
Oxidation states are integer in number but dn configurations of transition metal centers vary continuously in polar bonds. We quantify the shifts of the iron L3 excitation energy, within the same formal oxidation state, in a systematic L-edge X-ray absorption spectroscopy study of diatomic gas-phase iron(II) halide cations, [FeX]+,where X = F, Cl, Br, I. These shifts correlate with the electronegativity of the halogen, and are attributed exclusively to a fractional increase in population of 3d-derived orbitals along the series as supported by charge transfer multiplet simulations and density functional theory calculations. We extract an excitation energy shift of 420 meV ± 60 meV spanning the full range of possible 3d occupations between the most ionic bond in [FeF]+ and covalently bonded [FeI]+.