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Achieving a neutral/positive energy balance without compromising discharge standards is one of the main goals of wastewater treatment plants (WWTPs) in terms of sustainability. Aerobic granular sludge (AGS) technology promises high treatment performance with low energy and footprint requirement. In this study, high-rate activated sludge (HRAS) process was coupled to AGS process as an energy-efficient pre-treatment option in order to increase energy recovery from municipal wastewater and decrease the particulate matter load of AGS process. Three different feeding strategies were applied throughout the study. AGS system was fed with raw municipal wastewater, with the effluent of HRAS process, and with the mixture of the effluent of HRAS process and raw municipal wastewater at Stage 1, Stage 2 and Stage 3, respectively. Total suspended solids (TSS), chemical oxygen demand (COD), ammonia nitrogen (NH4+-N), and total phosphorus (TP) concentrations in the effluent were less than 10 mg/L, 60 mg/L, 0.4 mg/L, and 1.3 mg/L respectively at all stages. Fluctuations were observed in the denitrification performance due to changes in the influent COD/total nitrogen (TN) ratio. This study showed that coupling HRAS process with AGS process by feeding the AGS process with the mixture of HRAS process effluent and raw municipal wastewater could be an appropriate option for both increasing the energy recovery potential of WWTPs and enabling high effluent quality.
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Esgotos , Purificação da Água , Águas Residuárias , Reatores Biológicos , NitrogênioRESUMO
Leachate treatment is crucial in landfill management. As landfill ages, inert constituents and ammonia nitrogen concentration in leachate increases, which results in a decrease in biological treatability. In this study, a full-scale MBR treating leachate was dynamically modeled using ASM1. The investigated landfill has been serving for more than 25 years; thus, a decrease in biodegradable organic content and an increase in nitrogen content of the leachate is expected in the years ahead. The calibrated model predicted MLSS, effluent COD, and effluent TN concentrations with high accuracy. Following the calibration study, it was found that soluble inert COD and soluble inert organic nitrogen fractions were the primary reasons of high COD and TKN concentrations in the effluent, respectively. The validated model of the full-scale MBR system treating leachate can be a useful tool to understand the limitations of the system. Soluble inert constituents of the leachate that pass through the membrane necessiate additional treatment processes for discharge into surface water bodies.
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Poluentes Químicos da Água , Amônia , Reatores Biológicos , Nitrogênio , Poluentes Químicos da Água/análiseRESUMO
Aerobic granules contain microorganisms that are responsible for carbon, nitrogen, and phosphorus removal in aerobic granular sludge (AGS) process in which aerobic/anoxic/anaerobic layers (from surface to core) occur in a single granule. Optimizing the aerobic granular sludge (AGS) process for granulation and efficient nutrient removal can be challenging. The aim of this study was to examine the impact of settling prior to AGS process on granulation and treatment performance of the process. For this purpose, synthetic wastewater mimicking municipal wastewater was fed directly (Stage 1), and after primary sedimentation (Stage 2) to a laboratory-scale AGS system. In full-scale wastewater treatment plants, primary sedimentation is used to remove particulate organic matter and produce primary sludge which is sent to anaerobic digesters to produce biogas. Performances obtained in both stages were compared in terms of treatment efficiency, granule settling behavior, and granule morphology. Granulation was achieved in both stages with more than 92% chemical oxygen demand (COD) removal efficiencies in each stage. High nutrient removal was obtained in Stage 1 since anaerobic phase was long enough (i.e., 50 min) to hydrolyze particulate matter to become available for PAOs. Primary sedimentation caused a decrease in influent organic load and COD/N ratio, as a result, low nitrogen and phosphorus removal efficiencies were observed in Stage 2 compared to Stage 1. With this study, the effect of the primary sedimentation on the biological removal performance of AGS process was revealed. COD requirement for nutrient removal in AGS systems should be assessed by considering energy generation via biogas production from primary sedimentation sludge.
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Esgotos , Águas Residuárias , Aerobiose , Biocombustíveis , Reatores Biológicos , Nitrogênio , Fósforo , Esgotos/química , Eliminação de Resíduos LíquidosRESUMO
Anaerobic co-digestion of fat-oil-grease (FOG) and food waste (FW) with sewage sludge (SS) in wastewater treatment plants is a method used to increase biogas production. In this study, digestion scenarios were compared using plant-wide modeling and life cycle assessment: Scenario-0 (mono-digestion of waste-activated sludge (WAS)), Scenario-1 (co-digestion of WAS with FOG), and Scenario-2 (co-digestion of WAS with FW). Scenario-0, with the highest energy use and landfilling of FOG/FW, has the worst environmental impact. Scenario-1 and Scenario-2 minimize the environmental load by energy recovery and avoiding landfilling of organic waste. Scenario-wise, the change in greenhouse gas (GHG) emissions from treatment was negligible. However, due to the impact of landfilling, GHG emissions in Scenario-0 were 21% and 30% higher than in Scenario-1 and 2, respectively. The environmental benefit of anaerobic co-digestion of FOG/FW with SS is not only in the contribution to energy production but also in the recycling of organic waste.
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Gases de Efeito Estufa , Eliminação de Resíduos , Animais , Esgotos , Perda e Desperdício de Alimentos , Alimentos , Metano/análise , Hidrocarbonetos , Biocombustíveis/análise , Estágios do Ciclo de Vida , Digestão , Anaerobiose , Reatores BiológicosRESUMO
The paper reports the results of an experimental study aimed at comparing two configurations of a full-scale wastewater treatment plant (WWTP): conventional activated sludge (CAS) and oxic-settling-anaerobic process (OSA) with intermittent aeration (IA). A comprehensive monitoring campaign was carried out to assess multiple parameters for comparing the two configurations: carbon and nutrient removal, greenhouse gas emissions, respirometric analysis, and sludge production. A holistic approach has been adopted in the study with the novelty of including the carbon footprint (CF) contribution (as direct, indirect and derivative emissions) in comparing the two configurations. Results showed that the OSA-IA configuration performed better in total chemical oxygen demand (TCOD) and ortho-phosphate (PO4-P) removal. CAS performed better for Total Suspended Solids (TSS) removal showing a worsening of settling properties for OSA-IA. The heterotrophic yield coefficient and maximum growth rate decreased, suggesting a shift to sludge reduction metabolism in the OSA-IA configuration. Autotrophic biomass showed a reduced yield coefficient and maximum growth yield due to the negative effects of the sludge holding tank in the OSA-IA configuration on nitrification. The OSA-IA configuration had higher indirect emissions (30.5 % vs 21.3 % in CAS) from additional energy consumption due to additional mixers and sludge recirculation pumps. The CF value was lower for OSA-IA than for CAS configuration (0.36 kgCO2/m3 vs 0.39 kgCO2/m3 in CAS).
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The objective of this study is to develop a mechanistic model to predict the long-term dynamic performance of High-Rate Activated Sludge (HRAS) process, including the removal of carbon (COD), nitrogen (N), and phosphorus (P). The model was formulated with inspiration from Activated Sludge Models No. 1 and 3 (ASM1 and ASM3) to incorporate essential mechanisms, such as adsorption and storage substrate, specific to HRAS systems. A stepwise protocol was followed for calibration with dynamic data from a pilot-scale HRAS plant. Sensitivity analysis identified influential model parameters, including maximum specific growth rate (µ), growth yield (YH), storage yield (YSTO), storage rate (kSTO), decay rate (b), and half saturation of the readily biodegradable substrate for growth (KS1). The calibrated model achieved prediction efficiencies above the normalized Mean Absolute Error (MAE) of 70 % for mixed liquor suspended solids (MLSS), total chemical oxygen demand (TCOD), soluble COD (SCOD), particulate COD (XCOD), total nitrogen (TN), ammonia nitrogen (SNH), total phosphorus (TP), soluble TP (STP), and particulate TP (XTP). Uncertainty analysis revealed that SCOD was underestimated. Based on the dynamic profiles of uncertainty bands and observed data, there is potential for improving the estimation of dynamic behavior in STP. The observed discrepancies may be attributed to variations in wastewater characteristics during the monitoring period, particularly concerning the phosphorus (P) fractions of the readily biodegradable substrate (SS) and soluble inerts (SI), which were not considered as dynamically changing parameters in the model.
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Greenhouse gas (GHG) emissions from wastewater treatment plants (WWTPs) can affect climate change and must be measured and reduced. Mathematical modelling is an attractive solution to get a tool for GHG mitigation. However, although many efforts have been made to create reliable tools that can simulate "sustainable" full-scale WWTP operation, these studies are not considered complete enough to include GHG emissions and energy consumption of biological processes under long-term dynamic conditions. In this study, activated sludge model no. 1 (ASM1) was modified to model nitrous oxide (N2O) emissions with a plant-wide modelling approach. The model is novel compared to the state of the art since it includes three steps denitrification, all N2O production pathways and its stripping in an ASM1. The model has been calibrated and validated through long-term water quality and short-term N2O emissions data collected from Corleone (Italy) WWTP. Different dissolved oxygen (DO) concentrations and return sludge (RAS) ratios were tested with dynamic simulations to optimise the full-scale WWTP. The scenarios have been compared synergistically with effluent quality, direct GHG emissions, and energy footprint by the water-energycarbon coupling index (WECCI). This modelling study is novel as it fully covers long-term calibration/validation of the model with N2O measurements and tests the dynamic optimisation. Decision-makers and operators can use this new model to optimise GHG emissions and treatment costs.
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Gases de Efeito Estufa , Purificação da Água , Águas Residuárias , Esgotos , Modelos Teóricos , Óxido Nitroso/análiseRESUMO
A trade-off between greenhouse emissions (direct and indirect) and operational costs in the water treatment sector is of great importance, although only few literature studies exist. The paper presents a comprehensive experimental study on a Membrane Bioreactor (MBR) pilot plant at the Water Resource Recovery Facility of Palermo University (Italy). The MBR pilot plant was aimed at reducing carbon footprint while producing water suitable for water reuse in agriculture. Multiple scenarios were assessed to unveil the best operational variables including the assessment of the reclaimed water quality index for water reuse. Results showed the lowest operational costs for the MBR of 5.05 cent/m3 with Class B according to 741/2020 European legislation. Results revealed optimised values, in terms of airflow rate and backwash frequency, of 0.8 m3/m2/h and 12 times/h, respectively. The highest N2O emission was measured in correspondence of scenario S5 (airflow rate of 1.6 m3/m2/h) with 0.40 mg N2O-N/m2/h in agreement with previous literature studies. The obtained results could effectively address the operators to find a trade-off between operational costs and water quality.
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Gases de Efeito Estufa , Humanos , Eliminação de Resíduos Líquidos , União Europeia , Agricultura , ItáliaRESUMO
Bulking and foaming are extreme filamentous bacterial growths that present serious challenges for the biological leachate treatment process. The current study evaluates the performance of long-term full-scale membrane bioreactor (MBR) treating landfill leachate, specifically focusing on filamentous bacteria overgrowth in the bioreactors. The influence of the variation in leachate structure and operational conditions on floc morphology and filamentous bacteria overgrowth were analyzed for 11 months of operation of the full-scale MBR system. The average chemical oxygen demand (COD) and NH4-N removal efficiencies of the system were 87.8 ± 4% and 99.5 ± 0.7%. However, incomplete denitrification was observed when the F/M ratio was low. The high C/N ratio was observed to enhance the frequency of small flocs. Furthermore, a poor to medium diversity of the microbial community was observed. Haliscomenobacter hydrossis, Microthrix parvicella, and Type 021N were found as the most numerous filamentous organisms. Paramecium spp., Euplotes spp., and Aspidisca spp. were found in small quantities. The limited concentration of PO4-P in the leachate compared to high COD and NH4-N concentrations most probably caused phosphate deprivation and increased abundance of identified filamentous microorganisms. This work is the first study in Türkiye that investigates the bulking and foaming problem in full-scale MBR that treats landfill leachate. Hence, it may provide some pioneering perspectives into landfill leachate remediation by monitoring the hybrid biological system.
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Actinobacteria , Microbiota , Poluentes Químicos da Água , Bactérias , Reatores BiológicosRESUMO
A mathematical correlation between biomass kinetic and membrane fouling can improve the understanding and spread of Membrane Bioreactor (MBR) technology, especially in solving the membrane fouling issues. On this behalf, this paper, produced by the International Water Association (IWA) Task Group on Membrane modelling and control, reviews the current state-of-the-art regarding the modelling of kinetic processes of biomass, focusing on modelling production and utilization of soluble microbial products (SMP) and extracellular polymeric substances (EPS). The key findings of this work show that the new conceptual approaches focus on the role of different bacterial groups in the formation and degradation of SMP/EPS. Even though several studies have been published regarding SMP modelling, there still needs to be more information due to the highly complicated SMP nature to facilitate the accurate modelling of membrane fouling. The EPS group has seldom been addressed in the literature, probably due to the knowledge deficiency concerning the triggers for production and degradation pathways in MBR systems, which require further efforts. Finally, the successful model applications showed that proper estimation of SMP and EPS by modelling approaches could optimise membrane fouling, which can influence the MBR energy consumption, operating costs, and greenhouse gas emissions.
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Matriz Extracelular de Substâncias Poliméricas , Membranas Artificiais , Reatores Biológicos/microbiologia , Bactérias , Biomassa , Esgotos/microbiologiaRESUMO
Biogas production from anaerobic sludge digestion plays a central role for wastewater treatment plants to become more energy-efficient or even energy-neutral. Dedicated configurations have been developed to maximize the diversion of soluble and suspended organic matter to sludge streams for energy production through anaerobic digestion, such as A-stage treatment or chemically enhanced primary treatment (CEPT) instead of primary clarifiers. Still, it remains to be investigated to what extent these different treatment steps affect the sludge characteristics and digestibility, which may also impact the economic feasibility of the integrated systems. In this study, a detailed characterization has been performed for sludge obtained from primary clarification (primary sludge), A-stage treatment (A-sludge) and CEPT. The characteristics of all sludges differed significantly from each other. The organic compounds in primary sludge consisted mainly of 40% of carbohydrates, 23% of lipids, and 21% of proteins. A-sludge was characterized by a high amount of proteins (40%) and a moderate amount of carbohydrates (23%), and lipids (16%), while in CEPT sludge, organic compounds were mainly 26% of proteins, 18% of carbohydrates, 18% of lignin, and 12% of lipids. The highest methane yield was obtained from anaerobic digestion of primary sludge (347 ± 16 mL CH4/g VS) and A-sludge (333 ± 6 mL CH4/g VS), while it was lower for CEPT sludge (245 ± 5 mL CH4/g VS). Furthermore, an economic evaluation has been carried out for the three systems, considering energy consumption and recovery, as well as effluent quality and chemical costs. Energy consumption of A-stage was the highest among the three configurations due to aeration energy demand, while CEPT had the highest operational costs due to chemical use. Energy surplus was the highest by the use of CEPT, resulting from the highest fraction of recovered organic matter. By considering the effluent quality of the three systems, CEPT had the highest benefits, followed by A-stage. Integration of CEPT or A-stage, instead of primary clarification in existing wastewater treatment plants, would potentially improve the effluent quality and energy recovery.
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Esgotos , Eliminação de Resíduos Líquidos , Esgotos/química , Eliminação de Resíduos Líquidos/métodos , Águas Residuárias , Metano/metabolismo , Carboidratos , Lipídeos , Reatores Biológicos , AnaerobioseRESUMO
Coagulants such as aluminum sulfate (Al2(SO4)3 (alum)) and ferric chloride (FeCl3) used in water treatment plants (WTPs) led to the generation of sludge that is usually disposed to landfills. However, the utilization of WTP sludge is being encouraged by authorities to achieve sustainable development. This study aims to investigate WTP sludge utilization in a pilot-scale high-rate activated sludge (HRAS) system as a substitute for conventional coagulants. Based on jar tests, the iron sludge was selected for pilot-scale testing due to its superior ability to enhance the treatment efficiency of the HRAS process compared to alum sludge. Iron sludge addition (20.1 ± 1.6 mg dry sludge/L wastewater) slightly improved the removal efficiency of particulate chemical oxygen demand (pCOD) from 74 % to 81 % (p-value: 0.014). Iron sludge addition had a distinct effect on the sludge characteristics of the HRAS process. The average median particle size (d50) increased from 96 ± 3 to 163 ± 14 µm (p-value<0.00) with the addition of iron sludge, which improved the settleability of the HRAS process sludge. However, the biochemical methane potential (BMP) of the HRAS process sludge decreased by 8.9 % (p-value<0.00) after iron sludge addition. In a scenario analysis of WTP sludge use in a hypothetical HRAS plant, the effluent quality index (EQI), an indicator of environmental impact, was calculated and the cost related to the operation (the transfer and landfill disposal of WTP and HRAS process sludge, energy and chemical consumption of the HRAS plant) was estimated. As a result, using WTP sludge in the HRAS plant did not significantly affect the EQI of the plant but decreased overall cost by 11 %. The results showed that the use of WTP sludge as a coagulant in wastewater treatment could achieve mutual benefits for WTPs and WWTPs and have the potential to realize the circular economy model.
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Esgotos , Purificação da Água , Eliminação de Resíduos Líquidos/métodos , Ferro , Purificação da Água/métodosRESUMO
Water is crucial for economic development since it interacts with the agricultural, production, and energy sectors. However, the increasing demand and climate change put pressure on water sources. This paper argued the necessity of using reclaimed water for irrigation within the scope of a circular economy. The barriers (i.e., technological and economic, institutional/regulatory, and social) to water reuse practices were revealed. Lessons on how to overcome the barriers were learned from good practices. The roadmaps adopted in the European Union for the transition towards the circular economy were reviewed. It has been observed that these roadmaps are generally on the circularity of solid wastes. However, water is too important for the economy to be ignored in the transition towards circular economy. Research needs and perspective for a comprehensive roadmap to widen water-smart solutions such as water reuse were drawn.
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Águas Residuárias , Água , Agricultura , Resíduos SólidosRESUMO
The study aims to recover nitrogen from wastewater by employing ultrafiltration membrane in water reuse for agriculture purpose. To such aim, a new reclaimed water quality index (RWQI) is proposed and applied including an innovative protocol for its assessment. Specifically, the influence of filtration and backwashing times for an ultrafiltration system aimed to nutrient recovery has been analyzed. The final goal was to pin down the trade-off between operation costs and effluent quality. Results show that backwashing time play a crucial role in reducing the operation costs; indeed, low values (i.e., 0.5 min) lead to an increase in the number of required chemical cleanings and consequently operation costs (namely, up to 0.042 /m3). The compromise among effluent quality and operation costs has been obtained for 7 min and 1 min, filtration and backwashing, respectively.