Low-Cost Magnesium-Based Thermoelectric Materials: Progress, Challenges, and Enhancements.

Magnesium-based thermoelectric (TE) materials have attracted considerable interest due to their high ZT values, coupled with their low cost, widespread availability, nontoxicity, and low density. In this review, we provide a succinct overview of the advances and strategies pertaining to the development of Mg-based materials aimed at enhancing their performance. Following this, we delve into the major challenges posed by the severe working conditions, such as high temperature and thermal cycling, which adversely impact the behavior and long-term stability of the TE modules. Challenges include issues like the lack of mechanical strength, chemical instability, and unreliable contact. Subsequently, we focus on the key methodologies aimed at addressing these challenges to facilitate the broader application of the TE modules. These include boosting the mechanical strength, especially the toughness, through grain refining and additions of second phases. Furthermore, strategies targeted at enhancing the chemical stability through coatings and modifying the microstructure, as well as improving the contact design and materials, are discussed. In the end, we highlight the perspectives for boosting the practical applications of Mg-based TE materials in the future.

High-Temperature Oxidation Behaviour of CrSi Coatings on 316 Austenitic Stainless Steel.

In this study, a closed-field unbalanced magnetron sputtering system, which is environmentally friendly and has high deposition efficiency, was used to deposit CrSi coatings on 316 austenitic stainless steel. This system utilised separate Cr and Si targets, and the appropriate content of Cr and Si of the coatings was adjusted by changing the currents applied to the targets. A series of CrSi coatings with different Si/Cr ratios were produced, and their oxidation behaviour at elevated temperatures was investigated. By analysing the weight gain, surface morphology and microstructure, composition and phase constituents, the oxidation behaviour at 600 °C, 700 °C and 800 °C was investigated and the optimized coating to protect the stainless steel has been identified. The outcome of the research indicated that a small amount of Si (between 4-7 at.%) in Cr coatings is effective in protecting the austenitic stainless steel against oxidation at high temperatures, while a high Si content (around 10 at.% or more) makes the coating more brittle and prone to cracking or delamination during oxidation at 800 °C.

Characterization of Magnetron Sputtered BiTe-Based Thermoelectric Thin Films.

Thermoelectric (TE) technology attracts much attention due to the fact it can convert thermal energy into electricity and vice versa. Thin-film TE materials can be synthesized on different kinds of substrates, which offer the possibility of the control of microstructure and composition to higher TE power, as well as the development of novel TE devices meeting flexible and miniature requirements. In this work, we use magnetron sputtering to deposit N-type and P-type BiTe-based thin films on silicon, glass, and Kapton HN polyimide foil. Their morphology, microstructure, and phase constituents are studied by SEM/EDX, XRD, and TEM. The electrical conductivity, thermal conductivity, and Seebeck coefficient of the thin film are measured by a special in-plane advanced test system. The output of electrical power (open-circuit voltage and electric current) of the thin film is measured by an in-house apparatus at different temperature gradient. The impact of deposition parameters and the thickness, width, and length of the thin film on the power output are also investigated for optimizing the thin-film flexible TE device to harvest thermal energy.