Multi-stimuli responsive photonic hydrogel based on a novel photonic crystal template containing gold nanorods.

Multi-stimuli responsive photonic hydrogels (MRPHs) fabricated by doping nanoparticles into hydrogels show promising potential value in the fields of visual detection and drug delivery. However, complicated surface chemical modification is selected to improve the compatibility between nanoparticles and a pre-gel solution of hydrogel. Herein, we developed a simple and convenient vertical deposition method to prepare a novel photonic crystal (PC) template containing gold nanorods (Au NRs) (Au NRs/PC template), which could respond to near-infrared (NIR) light due to the conversion capability of Au NRs from NIR light to heat. Additionally, carboxyl groups on the surface of polystyrene (PS) colloids endowed the Au NRs/PC template with pH-stimulus responsiveness. Based on the Au NRs/PC template, MRPH film was fabricated by infiltrating the pre-gel solution of poly(N-isopropylacrylamide) (PNIPAM) hydrogel into the gap of a 'sandwich' structure through capillary forces and then polymerizing at 25 °C for 24 h. The obtained MRPH film could respond to NIR light, pH and temperature. Under the irradiation of NIR light, only the irradiated position lost structural color while the film volume had no distinct change. With the increase of ambient temperature, the whole MRPH film completely lost structural color and shrank significantly, which was greatly different from the phenomenon irradiated by NIR light. Besides, the structural color of the MRPH film exhibited a red shift from green to orange-red as the pH increased. Overall, both the Au NRs/PC template and the MRPH film may have potential applications in visual detection, due to their multi-stimuli responsiveness.

Assessment of Pedestrians' Head and Lower Limb Injuries in Tram-Pedestrian Collisions.

Analysis of pedestrians' head and lower limb injuries at the tissue level is lacking in studies of tram-pedestrian collisions. The purpose of this paper therefore to investigate the impact response process and severity of pedestrians' injuries in tram-pedestrian collisions, using the Total Human Model for Safety (THUMS) pedestrian human body model together with the tram FE model. Two full-scale tram-pedestrian dummy crash tests were performed to validate the FE model, and the total correlation and analysis (CORA) score of head acceleration yielded values of 0.840 and 0.734, confirming a strong agreement between the FE-simulated head responses and the experimental head kinematics. The effects of different tram speeds and impact angles on pedestrians' impact response injuries and the differences were further analyzed. The results indicate that direct impact of the lower limb with the tram's obstacle deflector leads to lower limb bone shaft fractures and knee tissue damage. Neck fling contributed to worsened head injury. Coup contusions were the predominant type of brain contusion, surpassing contrecoup contusions, while diffuse axonal injury was mainly concentrated in the collision-side region of the brain. Pedestrians' injuries are influenced by tram velocity and impact angle: higher tram velocities increase the risk of lower limb and head injuries. The risk of head injury for pedestrians is higher when the impact angle is negative, while lower limb injuries are more significant when the impact angle is 0°. This study provides practical guidance for enhancing tram safety and protecting pedestrians.

Validated numerical unrestrained occupant-seat crash scenarios for high-speed trains integrating experimental, computational, and inverse methods.

OBJECTIVE: Occupant impact safety is critical for train development. This paper proposes a systematic procedure for developing validated numerical occupant crash scenarios for high-speed trains by integrating experimental, computational, and inverse methods. METHODS: As the train interior is the most potentially injury-causing factor, the material properties were acquired by mechanical tests, and constitutive models were calibrated using inverse methods. The validity of the seat material constitutive model was further verified via drop tower tests. Finite element (FE) and multibody (MB) models of train occupant-seat interactions in frontal impact were established in LS-DYNA and MADYMO software, respectively, using the experimentally acquired materials/mechanical characteristics. Three dummy sled crash tests with different folding table and backrest configurations were conducted to validate the numerical occupant-seat models and to further assess occupant injury in train collisions. The occupant impact responses between dummy tests and simulations were quantitatively compared using a correlation and analysis (CORA) objective rating method. RESULTS: Results indicated that the experimentally calibrated numerical seat-occupant models could effectively reproduce the occupant responses in bullet train collisions (CORA scores >80%). Compared with the train seat-occupant MB model, the FE model could simulate the head acceleration with slightly more acceptable fidelity, however, the FE model CORA scores were slightly less than for the MB models. The maximum head acceleration was 30 g but the maximum HIC score was 17.4. When opening the folding table, the occupant's chest injury was not obvious, but the neck-table contact and "chokehold" may potentially be severe and require further assessment. CONCLUSIONS: This study demonstrates the value of experimental data for occupant-seat model interactions in train collisions and provides practical help for train interior safety design and formulation of standards for rolling stock interior passive safety.