Feasibility experimental study on plugging leakage in goaf based on two-phase foam.

Air leakage in goaf often leads to coal spontaneous combustion (CSC), which not only directly affects the safety production of mines but also causes significant environmental damage. Therefore, effectively sealing the airflow in goaf is crucial for preventing CSC. Feasibility experiments on using two-phase foam to seal air leakage in goaf were conducted, leveraging the advantages of large flow rate, wide diffusion range, and good accumulation characteristics of two-phase foam. The research results indicate that continuous injection of foam into loose media with maintained ventilation can completely seal the air leakage, with the foam capable of withstanding wind pressures of nearly 600 Pa. When the foam is used for one-time sealing with a length of 2 m, it remains effective for 60 min, and the sealing effectiveness improves with longer distances sealed against air leakage. Numerical simulation analysis and field measurements of airflow leakage in mine working faces reveal that effectively sealing the airflow passage in the goaf behind the corner of the return airway is crucial for preventing CSC. Two methods are proposed for sealing external airflow during coal mining: foam injection using a point drilling method near the heading and an incremental buried pipe injection method. Finally, the feasibility of two-phase foam sealing technology for goaf airflow leakage is analyzed from multiple perspectives including sealing effectiveness, practicality, economy, foaming process, and engineering implementation. The research findings provide new insights into goaf sealing technology, aiding in addressing safety and environmental issues caused by spontaneous combustion in goaf areas.

Effect of Liquid Nitrogen Freeze-Thaw Cycles on Pore Structure Development and Mechanical Properties of Coal.

To improve the mining efficiency of coalbed methane, liquid nitrogen freeze-thawing experiments were performed to improve coal seam permeability and to study its influence on coal pore structure development and mechanical properties. Mechanical properties and nuclear magnetic resonance tests of coal samples were performed with 0, 5, 10, and 15 freeze-thaw cycles of liquid nitrogen. The results show that the number of freeze-thaw cycles caused the change of uniaxial compressive strength and elastic modulus of coal, and the change effect decreased significantly after 11-15 freeze-thaw cycles. Between 0 and 5 freeze-thaw cycles, the base growth rate of the transverse relaxation time T 2 spectral area of the full pore of coal is 44.1%, and that of the transverse relaxation time T 2 spectral area of adsorption pore is 71.5%. After 6-10 freeze-thaw cycles, the fixed base growth rate of the transverse relaxation time T 2 spectral area of the full hole of coal is 269.0%, and the chain growth rate is 156.2%. In this stage, the chain growth rate of the transverse relaxation time T 2 spectral area of the seepage hole is 198.4%, which is mainly the growth of seepage hole volume. After 11-15 freeze-thaw cycles, the chain growth rate of the full pore of coal transverse relaxation time T 2 spectrum area is 20.1%, the chain growth rate of adsorption pore is 4.8%, the chain growth rate of seepage pore is 22.2%, and the growth rate of the pore volume is greatly reduced. Comparing the changes of pore and coal mechanical properties in different pore sizes, it can be seen that the change of adsorption pore volume has a greater impact on coal mechanical properties.

Variation features of unfrozen water content of water-saturated coal under low freezing temperature.

To determine the unfrozen water content variation characteristics of coal from the low temperature freezing based on the good linear relationship between the amplitude of the nuclear magnetic resonance (NMR) signal and movable water, pulsed NMR technology was used to test water-saturated coal samples and analyze the relationship between the unfrozen water content, the temperature and pore pressure during freeze-thaw from a microscopic perspective. Experimental results show that the swelling stress of the ice destroys the original pore structure during the freezing process, causing the melting point of the pore ice to change, so the unfrozen water content during the melting process presents a hysteresis phenomenon. When phase equilibrium has been established in the freezing process, the unfrozen water is mainly the film water on the pore surface and pore water in pores with pore radius below 10 nm. At this time, the freezing point of the water in the system decreases exponentially as the temperature increases. The micropores of the coal samples from the Jiulishan Coalmine are well-developed, and the macropores and fractures are relatively small, with most pores having a pore radius between 0.1 and 10 nm. The pore water freezing point gradually decreases with the pore radius. When the pore radius decreases to 10 nm, the freezing point of pore water starts to decrease sharply with the decreasing pore radius. When the pore radius reaches 1.54 nm, the pore water freezing point changes as fast as 600 ℃/nm.

Study on Temperature Variation and Pore Structure Evolution within Coal under the Effect of Lilquid Nitrogen Mass Transfer.

Liquid nitrogen freezing, which is an effective permeability enhancement technology, has been applied to the extraction of oil, shale gas, and coalbed methane (CBM). This study is aimed at revealing the effect of liquid nitrogen mass transfer on the temperature variation and pore structure evolution within coal. To achieve this aim, first, temperature measurement tests under the action of liquid nitrogen freezing were conducted on saturated and dried coal samples, respectively. Next, the coal samples were subjected to nuclear magnetic resonance and computer tomography tests before and after liquid nitrogen cold soaking to further explore the mechanism of coal temperature variation from a microscopic perspective. The results show that the action of liquid nitrogen mass transfer can accelerate coal temperature variation through coal pore structure and pore water phase change. The thermal stress and frost heave force generated by liquid nitrogen cold soaking exceed the tensile strength of the coal sample, which directly causes crack initiation, expansion, and connection. The mass transfer of liquid nitrogen has a significant promoting effect on pore development. This study provides the technical support necessary for the efficient exploitation of CBM resources and the improvement of CBM extraction rate.

The Temperature Field Evolution and Water Migration Law of Coal under Low-Temperature Freezing Conditions.

This study examines the evolution law of the coal temperature field under low-temperature freezing conditions. The temperature inside coal samples with different water contents was measured in real-time at several measurement points in different locations inside the sample under the condition of low-temperature medium (liquid nitrogen) freezing. The temperature change curve was then used to analyse the laws of temperature propagation and the movement of the freezing front of the coal, which revealed the mechanism of internal water migration in the coal under low-temperature freezing conditions. The results indicate that the greater the water content of the coal sample, the greater the temperature propagation rate. The reasons for this are the phase change of ice and water inside the coal during the freezing process; the increase in the contact area of the ice and coal matrix caused by the volume expansion; and the joint action of the two. The process of the movement of the freezing front is due to the greater adsorption force of the ice lens than that of the coal matrix. Thus, the water molecules adsorbed in the unfrozen area of the coal matrix migrate towards the freezing front and form a new ice lens. Considering the temperature gradient and water content of the coal samples, Darcy's permeation equation and water migration equation for the inside of the coal under freezing conditions were derived, and the segregation potential and matrix potential were analysed. The obtained theoretical and experimental results were found to be consistent. The higher the water content of the coal samples, the smaller the matrix potential for the hindrance of water migration. Furthermore, the larger the temperature gradient, the larger the segregation potential, and the faster the water migration rate.

Correction to "Study on Temperature Variation and Pore Structure Evolution within Coal under the Effect of Liquid Nitrogen Mass Transfer".

[This corrects the article DOI: 10.1021/acsomega.1c02331.].