Portable Visual Photoelectrochemical Biosensor Based on a MgTi2O5/CdSe Heterojunction and Reversible Electrochromic Supercapacitor for Dual-Modal Cry1Ab Protein Detection.

Reversible electrochromic supercapacitors (ESCs) have attracted considerable interest as visual display screens. The use of ESCs in combination with a photoelectrochemical (PEC) biosensor promises to improve the detection efficiency. Herein, a visual PEC biosensor is developed by introducing a circuit module between a PEC-sensing platform (PSP) and a reversible ESC for Cry1Ab protein detection. In PSP, a type II MgTi2O5/CdSe heterojunction effectively drives charge separation by their cross-matched band gap structures, generating an amplified photocurrent. Next, the circuit module is designed to connect the PSP and ESC, realizing the signal conversion from photocurrent to voltage. ESC, as a visual display screen, produces reversible color changes with different voltages. As the concentration of Cry1Ab increases, the photocurrent decreases due to the specific binding between the aptamer and Cry1Ab in PSP, while the color of the reversible ESC changes from green to blue. To improve the integrity of the device, a portable PEC biosensor is further constructed via three-dimensional printing for dual-modal Cry1Ab protein detection, thus collecting both PEC and visual signals. The linear ranges are 0.3-3000 ng mL-1 for PEC mode and 1-1000 ng mL-1 for visual mode. This work presents a portable, efficient, sensitive, and visualized detection system, providing an important reference for practical visualization applications.

Photoelectrochemical aptasensor for sensitive detection of tetracycline in soil based on CdTe-BiOBr heterojunction: Improved photoactivity enabled by Z-scheme electron transfer pathway.

Exploring effective methods for tetracycline (TC) detection in soil has great significance because of its emerging environmental problem and increasing threat to soil quality and general public health worldwide. In this work, a sensitive photoelectrochemical (PEC) aptasensor toward TC detection was designed and constructed based on an efficient photosensitive material of Z-scheme CdTe-BiOBr heterojunction. Due to the sensitization of CdTe quantum dots (QDs) on the BiOBr nanoflowers, the photocurrent intensity of the CdTe-BiOBr heterojunction was enhanced about 5.0-fold and 8.0-fold than that of pure BiOBr and CdTe under visible-light irradiation, which was attributed to the low electron-hole combination efficiency, high visible light utilization efficiency, and high carrier density of the heterojunction. On the merits of the excellent PEC activity of the CdTe-BiOBr and the specificity of the aptamer, the proposed PEC aptasensor has the advantages of satisfying linear range (from 10 to 1500 pM), low detection limit (9.25 pM), good selectivity, and reproducibility. In addition, acceptable accuracy was obtained for TC detection in real soil sample, giving acceptable accuracy in comparison with the referenced high-performance liquid chromatography-diode array detector method, revealing a promising avenue for accurate and ultrasensitive estimation of other kinds of contaminants in the broad field of analysis.