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BACKGROUND: Marginal misfit and surface roughness of customized implant abutments is critical for restorative success. However, little is known about the comparison of misfit and surface roughness of CAD-CAM Zirconium oxide (ZrO), selective laser melting (SLM) Cobalt Chrome (CoCr) and preformed abutments. The aim of the study is to investigate the relation of misfit and micro-roughness of selective laser melting (SLM), preformed and CAD-CAM implant abutments. METHODS: Thirty internal connection, endosseous dental implants (Ø 4.0 mm x 10 mm, Dentium) were mounted in Polymethyl methacrylate vertically. Ten preformed Titanium alloy (Ti) abutments with 1 mm soft tissue height and Ø 4.5 mm were included as controls. Ten each of Y-TZP and SLM-CoCr, abutment/crowns were fabricated using CAD-CAM milling (CAD-CAM-ZrO) and SLM techniques. Surface micro-roughness (Ra) of the fabricated implant abutment/crown was evaluated with a 3D optical non-contact microscope. All implant restorations were torqued to implants (30 Ncm) using a Tohnichi BTGE digital torque gauge and were analyzed with Bruker micro-CT (Skyscan 1173) to detect micro-gaps at pre-selected points at implant abutment interface. The Ra and misfit data were compared using ANOVA, Tukey-Kramer, Kruskal-Wallis test and Pearson correlation (p < 0.05). RESULTS: Mean Ra among SLM CoCr abutments [0.88 (0.09) µm] were lower than CAD-CAM-ZrO and higher than preformed Ti abutments. Horizontal misfit among SLM-CoCr [45.43 (9.41) µm] and preformed Ti [36.87 (13.23) µm] abutments was not statistically different (p > 0.05). Misfit was significantly higher in Y-TZP samples compared to SLM-CoCr (p = 0.031) and preformed Ti abutments (p = 0.01). Preformed Ti abutments showed significantly lower misfit compared to SLM-CoCr abutments (p = 0.01). A positive linear correlation was observed between the surface roughness (Ra) and vertical misfit (r = 0.61, p < 0.05). CONCLUSION: SLM CoCr abutments showed rough surface compared to preformed Ti abutments, while horizontal misfit was comparable among SLM-CoCr and preformed abutments. Misfit was significantly greater in Y-TZP abutments, compared to SLM and preformed abutments. SLM abutment fabrication technique needs further improvement to provide better fit and surface topography.
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Ligas de Cromo , Desenho Assistido por Computador , Coroas , Dente Suporte , Projeto do Implante Dentário-Pivô , Lasers , Propriedades de Superfície , Titânio , Zircônio , Zircônio/química , Titânio/química , Ligas de Cromo/química , Humanos , Planejamento de Prótese Dentária , Adaptação Marginal DentáriaRESUMO
A series of poly(ethylene-co-vinyl alcohol)/titanium dioxide (PEVAL/TiO2) nanocomposites containing 1, 2, 3, 4 and 5 wt% TiO2 were prepared by the solvent casting method. These prepared hybrid materials were characterized by Fourier-transform infrared (FT-IR), X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA) and scanning electron microscopy (SEM). The pores and their interconnections inside these nanocomposites were created using naphthalene microparticles used as a porogen after having been extracted by sublimation under a high vacuum at temperatures slightly below the glass transition temperature. A cellular activity test of these hybrid materials was performed on human gingival fibroblast cells (HGFs) in accordance with ISO 10993-5 and ISO 10993-12 standards. The bioviability (cell viability) of HGFs was evaluated after 1, 4 and 7 days using Alamar Blue®. The results were increased cell activity throughout the different culture times and a significant increase in cell activity in all samples from Day 1 to Day 7, and all systems tested showed significantly higher cell viability than the control group on Day 7 (p < 0.002). The adhesion of HGFs to the scaffolds studied by SEM showed that HGFs were successfully cultured on all types of scaffolds.
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Nanocompostos , Engenharia Tecidual , Etilenos , Humanos , Nanocompostos/química , Polietileno , Espectroscopia de Infravermelho com Transformada de Fourier , Engenharia Tecidual/métodos , Titânio/química , Titânio/farmacologia , Difração de Raios XRESUMO
The economic developments around the globe resulted in the increased demand of energy, which overburdened the supply chain sources of energy. Fossil fuel reserves are exploited to meet the high demand of energy and their combustion is becoming the main source of environmental pollution. So there is dire need to find safe, renewable and sustainable energy resources. Waste to energy (WtE) may be viewed as a possible alternate source of energy, which is economically and environmentally sustainable. Municipal solid waste (MSW) is a major contributor to the development of renewable energy and sustainable environment. At present the scarcity of renewable energy resources and disposal of MSW is a challenging problem for the developing countries, which has generated a wide ranging socioeconomic and environmental problems. This situation stimulates the researchers to develop alternatives for converting WtE under a variety of scenarios. Herein, the present scenario in developing the WtE technologies such as, thermal conversion methods (Incineration, Gasification, Pyrolysis, Torrefaction), Plasma technology, Biochemical methods, Chemical and Mechanical methods, Bio-electrochemical process, Mechanical biological treatment (MBT), Photo-biological processes for efficacious energy recovery and the challenges confronted by developing and developed countries. In this review, a framework for the evaluation of WtE technologies has been presented for the ease of researchers working in the field. Furthermore, this review concluded that WtE is a potential renewable energy source that will partially satisfy the demand for energy and ensure an efficient MSW management to overcome the environmental pollution.
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Eliminação de Resíduos , Gerenciamento de Resíduos , Biomassa , Incineração , Resíduos Sólidos , TecnologiaRESUMO
Nanostructures play an important role in targeting sparingly water-soluble drugs to specific sites. Because of the structural flexibility and stability, the use of template microemulsions (µEs) can produce functional nanopharmaceuticals of different sizes, shapes, and chemical properties. In this article, we report a new volatile oil-in-water (o/w) µE formulation comprising ethyl acetate/ethanol/brij-35/water to obtain the highly water-dispersible nanoparticles of an antihyperlipidemic agent, ezetimibe (EZM-NPs), to enhance its dissolution profile. A pseudoternary phase diagram was delineated in a specified brij-35/ethanol ratio (1:1) to describe the transparent, optically isotropic domain of the as-formulated µE. The water-dilutable µE formulation, comprising an optimum composition of ethyl acetate (18.0%), ethanol (25.0%), brij-35 (25.0%), and water (32.0%), showed a good dissolvability of EZM around 4.8 wt % at pH 5.2. Electron micrographs showed a fine monomodal collection of EZM-loaded µE droplets (â¼45 nm) that did not coalesce even after lyophilization, forming small spherical EZM-NPs (â¼60 nm). However, the maturity of nanodrug droplets observed through dynamic light scattering suggests the affinity of EZM to the nonpolar microenvironment, which was further supported through peak-to-peak correlation of infrared analysis and fluorescence measurements. Moreover, the release profile of the as-obtained EZM-nanopowder increased significantly >98% in 30 min, which indicates that a reduced drug concentration will be needed for capsules or tablets in the future and can be simply incorporated into the multidosage formulation of EZM.
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Hipolipemiantes , Água , Emulsões , Ezetimiba , SolubilidadeRESUMO
BACKGROUND: The aim of this study was to evaluate the effect of universal adhesives (UA) and silane on the microtensile bond strength (µTBS) of resin cement to a hybrid ceramic Vita Enamic (VE). METHODS: VE specimens were acid etched using hydrofluoric acid (HF) and were assigned to three groups (n = 10) based on the applied bonding technique. In group 1 (S), a silane-based primer was used as a surface treatment prior to the application of a resin cement (Variolink Esthetic DC). In group 2, a silane-containing UA, Clearfil Universal Bond (CUB) was used for the surface treatment, and in group 3, A silane-free UA, Tetric N-Bond Universal (TNU) was used for surface treatment. Resin cement build-ups were prepared. The bonded specimens were sectioned into resin-ceramic beams. Half of the beams of each group were stored for 24 h at 37 °C and the other half were subjected to a thermo-cycling aging. The microtensile bond strength (µTBS) was measured at a crosshead speed of 0.5 mm/min. Failure modes were assessed accordingly. Data were analyzed using a) two-way analysis of variance ANOVA followed by one-way ANOVA and Tukey tests between groups and b) independent t-test to detect differences (α = 0.05) for each group. The surface topographies of the ceramic surface were evaluated using scanning electron microscopy. RESULTS: The results showed that silane-based primer (S) application resulted in significantly higher (p < 0.05) µTBS values after 24 h and after thermocycling compared to both silane-containing UA (CUB) and silane-free UA (TNU). The µTBS values of all groups were significantly reduced after thermocycling. No statistically significant difference was observed between the µTBS of CUB and TNU after 24 h. However, TNU showed significantly higher µTBS after thermocycling. Different failure modes were observed, and adhesive failure was the most common in all groups. Marked surface topographic changes were observed following HF etching. CONCLUSION: It is concluded that, the UAs tested cannot be recommended as substitutes to the silanization of Hybrid ceramic.
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Cerâmica/química , Colagem Dentária , Cimentos de Resina/química , Condicionamento Ácido do Dente , Cimentos Dentários , Corrosão Dentária/métodos , Porcelana Dentária/química , Análise do Estresse Dentário , Estética Dentária , Humanos , Teste de Materiais , Microscopia Eletrônica de Varredura , Propriedades de Superfície , Resistência à TraçãoRESUMO
OBJECTIVE: To evaluate the degree of conversion (DC) and depth (extent) of cure of four resin cements (Variolink E, Calibra, NX3 and Variolink N) using Fourier transform infrared (FTIR) and Vickers Micro hardness (MH). METHODS: Ten disks (1mmx2mm) of each resin cement were light cured through a ceramic disk for 40 seconds prior to assessment. The ATR spectra of the uncured resin were collected in absorbance mode from 16 scans at 4 wave number resolutions. Degree of conversion was calculated by estimating the changes in peak height ratio of the absorbance intensities of aliphatic C=C peak at 1638 cm-1 and that of an internal standard peak of aromatic C=C at 1608 cm-1 during polymerization. For Vickers microhardness testing 10 disks of each cement specimen was exposed to 100 grams of load for 15 seconds. Three indentations were made 0.5mm apart and an average Vickers micro-hardness (MH) for each specimen. Two way ANOVA and multiple comparison tests were performed to assess data. RESULTS: The highest degree of conversion by peak area was shown by Variolink-Esthetic [light-cure (87.18±2.90%)]; however the lowest was observed in samples of Variolink-N [Dual cure (44.55±4.33%)]. Similarly, Variolink-Esthetic and NX3 cement showed significantly higher MH as compared to other groups. CONCLUSION: Ivocerin containing Variolink-E cement showed high degree of conversion and extent of polymerization when compared to conventional light and dual cure luting cements.
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AIM: This study aimed to compare the torque loss, fracture load, compressive strength, and failure types of selective-laser-sintered cobalt chromium (SLM-Co-Cr), computer-aided design and computer-aided manufacturing zirconium oxide (CAD-CAM-ZrO), and machined titanium (Ti) implant abutments. METHODS: Thirty endosseous dental implants were vertically embedded with machined Ti (control group), CAD-CAM-ZrO, and SLM-Co-Cr abutments. Abutment fabrication involved CAD-CAM milling and SLM technology. The de-torque assessment included preload reverse torque values (RTVs), cyclic loading, and post-RTVs using a customized protocol. Fracture load assessment employed ISO-14801 standards, and statistical analysis was conducted using ANOVA and Tukey Post hoc tests (p < 0.05). RESULTS: In pre-load RTVs, SLM-Co-Cr showed the lowest mean torque loss (24.30 ± 2.13), followed by machined Ti (27.33 ± 2.74) and CAD-CAM-ZrO (22.07 ± 2.20). Post-load RTVs decreased for all groups. Fracture load and compressive strength were highest for SLM-Co-Cr, with significant differences among groups (p < 0.001). Fracture types included abutment failures in SLM-Co-Cr and machined Ti, while CAD-CAM-ZrO exhibited crown separation with deformation. CONCLUSION: SLM-Co-Cr-fabricated implant abutments exhibited superior stability and resistance to rotational forces, higher fracture loads, and greater compressive strength compared to CAD-CAM-ZrO and machined Ti.
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Surface modified tissue engineered polypropylene / PP hernia meshes were fabricated by incorporating Bacterial cellulose / BC and chitosan / CS and phytochemical extracts. Under current practice, hernia and other traumatic injuries to the abdominal organs are clinically treated with surgical meshes. Often the foreign body reaction and infections result in relapse in patients which dictates additional reparative surgical procedures and pain. To improve the outcome of clinical restorative procedures new biomaterials with improved characteristics are required. The functionalized meshes were physically and chemically characterized using SEM, mechanical testing, FTIR and XRD. The antimicrobial activity was qualitatively and quantitatively tested using E. coli and S. aureus strains of bacteria. In vitro biocompatibility and wound healing effect of the modified meshes were performed using NIH3T3 fibroblast cell lines. Furthermore, tissue engineering potential of the meshes was evaluated using confocal fluorescent microscopy. In vivo implantation of the meshes was performed in male wistar rats for 21 days. Therefore, PP meshes with sustained drug delivery system augmented with anti-inflammatory and anti-microbial characteristics were developed. The coatings hereby not only increased the tensile strength of meshes but also prevented the modified meshes from causing infection. Current study resulted in CS-BC bioactive PP meshes loaded with phytochemicals which showed anti-inflammatory, antibacterial and wound healing potential. These meshes can be valuable to lessen the post-surgical complications of implanted PP mesh and thus reduce rejection and recurrence.
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Quitosana , Extratos Vegetais , Polipropilenos , Telas Cirúrgicas , Engenharia Tecidual , Quitosana/química , Animais , Camundongos , Polipropilenos/química , Células NIH 3T3 , Ratos , Extratos Vegetais/química , Extratos Vegetais/farmacologia , Engenharia Tecidual/métodos , Masculino , Cicatrização/efeitos dos fármacos , Materiais Biocompatíveis/química , Materiais Biocompatíveis/farmacologia , Escherichia coli/efeitos dos fármacos , Staphylococcus aureus/efeitos dos fármacos , Ratos Wistar , Antibacterianos/farmacologia , Antibacterianos/química , Teste de Materiais , Resistência à TraçãoRESUMO
Tissue engineering is currently one of the fastest-growing areas of engineering, requiring the fabrication of advanced and multifunctional materials that can be used as scaffolds or dressings for tissue regeneration. In this work, we report a bilayer material prepared by electrospinning a hybrid material of poly(vinyl alcohol) (PVA) and bacterial cellulose (BC NFs) (top layer) over a highly interconnected porous 3D gelatin-PVA hydrogel obtained by a freeze-drying process (bottom layer). The techniques were combined to produce an advanced material with synergistic effects on the physical and biological properties of the two materials. The bilayer material was characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and a water contact measurement system (WCMS). Studies on swelling, degradability, porosity, drug release, cellular and antibacterial activities were performed using standardized procedures and assays. FTIR confirmed cross-linking of both the top and bottom layers, and SEM showed porous structure for the bottom layer, random deposition of NFs on the surface, and aligned NFs in the cross section. The water contact angle (WCA) showed a hydrophilic surface for the bilayer material. Swelling analysis showed high swelling, and degradation analysis showed good stability. The bilayer material released Ag-sulfadiazine in a sustained and controlled manner and showed good antibacterial activities against severe disease-causing gram + ive and -ive (Escherichia coli, Staphylococcus aureus, and Pseudomonas aeruginosa) bacterial strains. In vitro biological studies were performed on fibroblasts (3T3) and human embryonic kidneys (HEK-293), which showed desirable cell viability, proliferation, and adhesion to the bilayer. Thus, the synergistic effect of NFs and the hydrogel resulted in a potential wound dressing material for wound healing and soft tissue engineering.
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The treatment adherence of narcotics-addicted individuals with reduced incidences of relapse can be enhanced by a sustained drug release formulation of antinarcotics. So far, different drug formulations have been reported with sustained drug release periods of 28 and 35 days. To further enhance this duration, different formulations of injectable hydrogels (IHs) have been developed by combining low molecular weight (LMW) and high molecular weight (HMW) chitosan (CS) with guar gum (GG) and crosslinking them by sodium bi phosphate dibasic. The structural, morphological, and physicochemical properties of LMW-CS IH, and HMW-CS IH were evaluated using Fourier transform infrared spectroscopy (FT-IR), thermo-gravimetric analysis (TGA), scanning electron microscopy (SEM), and rheological, swelling, and biodegradation analysis. The HMW-CS IH showed high crosslinking, increased thermal stability, high mechanical strength, elevated swelling, and low biodegradation. The antinarcotic drugs naltrexone (NTX) and disulfiram (DSF) were loaded separately into the HMW-CS IH and LMW-CS IH. The release of NTX and DSF was investigated in phosphate buffer saline (PBS) and ethanol (0.3%, 0.4%, and 0.5%) over a 56-day period using an UV spectrophotometer. The drug release data were tested in zero-order, first-order, and Korsemeyer-Peppas mathematical models. In PBS, all prepared formulations followed non-Fickian drug release, while in ethanol, only NTX HMW-CS IH followed non-Fickian release in all three different concentrations of ethanol.
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The production of renewable materials from alternative sources is becoming increasingly important to reduce the detrimental environmental effects of their non-renewable counterparts and natural resources, while making them more economical and sustainable. Chemical surfactants, which are highly toxic and non-biodegradable, are used in a wide range of industrial and environmental applications harming humans, animals, plants, and other entities. Chemical surfactants can be substituted with biosurfactants (BS), which are produced by microorganisms like bacteria, fungi, and yeast. They have excellent emulsifying, foaming, and dispersing properties, as well as excellent biodegradability, lower toxicity, and the ability to remain stable under severe conditions, making them useful for a variety of industrial and environmental applications. Despite these advantages, BS derived from conventional resources and precursors (such as edible oils and carbohydrates) are expensive, limiting large-scale production of BS. In addition, the use of unconventional substrates such as agro-industrial wastes lowers the BS productivity and drives up production costs. However, overcoming the barriers to commercial-scale production is critical to the widespread adoption of these products. Overcoming these challenges would not only promote the use of environmentally friendly surfactants but also contribute to sustainable waste management and reduce dependence on non-renewable resources. This study explores the efficient use of wastes and other low-cost substrates to produce glycolipids BS, identifies efficient substrates for commercial production, and recommends strategies to improve productivity and use BS in environmental remediation.
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Recuperação e Remediação Ambiental , Glicolipídeos , Tensoativos , Tensoativos/química , Recuperação e Remediação Ambiental/métodos , Biodegradação AmbientalRESUMO
Efficient and cost-effective biosorbents derived from biowaste are highly demanding to handle various environmental challenges, and demonstrate the remarkable synergy between sustainability and innovation. In this study, the extraction of uranium U(VI) was investigated on biowaste activated carbon (BAC) obtained by chemical activation (phosphoric acid) using Albizia Lebbeck pods as biowaste. The biowaste powder (BP), biowaste charcoal (BC) and BAC were evaluated by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR) and Brunauer-Emmett-Teller (BET) with nitrogen adsorption for thermal properties, chemical structures, porosity and surface area, respectively. The pHPZC for acidic or basic nature of the surface and X-ray diffraction (XRD) analysis were performed for BAC. The morphological and elemental analysis were performed by scanning electron microscopy (SEM) and energy dispersive X-ray (EDX). The extraction of uranium U(VI) ions from aqueous solutions using BAC as sorbent was investigated by using different variables such as pH, contact time, initial uranium U(VI) concentration and BAC dose. The highest adsorption (90.60% was achieved at 0.5 g BAC dose, 2 h contact time, pH 6, 10 ppm initial U(VI) concentration and with 200 rpm shaking speeds. The production of this efficient adsorbent from biowaste could be a potential step forward in adsorption of uranium to meet the high demand of uranium for nuclear energy applications.
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The development of advanced multifunctional wound dressings remains a major challenge. Herein, a novel multilayer (ML) electrospun nanofibers (NFs) wound dressing based on diethylenetriamine (DETA) functionalized polyacrylonitrile (PAN), TiO2 nanoparticles (NPs) coating (Ct), and bioderived gelatin (Gel) was developed for potential applications in wound healing. The ML PAN-DETA-Ct-Gel membrane was developed by combining electrospinning, chemical functionalization, synthesis, and electrospray techniques, using a layer-by-layer method. The ML PAN-DETA-Ct-Gel membrane is comprised of an outer layer of PAN-DETA as a barrier to external microorganisms and structural support, an interlayer TiO2 NPs (Ct) as antibacterial function, and a contact layer (Gel) to improve biocompatibility and cell viability. The NFs membranes were characterized by scanning electron microscopy (SEM), surface profilometry, BET analysis, and water contact angle techniques to investigate their morphology, surface roughness, porosity, and wettability. The ML PAN-DETA-Ct-Gel wound dressing exhibited good surface roughness, porosity, and better wettability. Cell morphology, proliferation, and viability were determined using fibroblasts (3T3), and antibacterial assays were performed against six pathogens. The ML PAN-DETA-Ct-Gel NFs membrane showed good cell morphology, proliferation, viability, and antibacterial activity compared with other membranes. This new class of ML NFs membranes offers a multifunctional architecture with adequate biocompatibility, cell viability, and antibacterial activity.
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Gelatina , Nanofibras , Gelatina/química , Nanofibras/química , Aminas , DEET , Antibacterianos/química , BandagensRESUMO
This article presents a methodological approach to use manganese (Mn3+Mn7+)-modified black titanium dioxide (Mn/BTiO2) as a photocatalyst to optimize and improve visible-light-driven photodegradation of treated agro-industrial effluent (TPOME). A modified wet chemical process was used to prepare BTiO2. The BTiO2 was then wet impregnated with Mn and calcined at 300 °C for 1 h to produce Mn/BTiO2. The activity of Mn/BTiO2 was investigated in terms of photo-assisted elimination of chemical oxygen demand (COD), phenolic compounds (PCs), color, and total organic carbon (TOC). Using the design of experiments (DOE), the conditions of the photocatalytic process, including photocatalyst loading, Mn concentration, hydrogen peroxide (H2O2) dose, and irradiation time, were optimized. Under the optimum conditions (0.85 g/L photocatalyst loading, 0.048 mol/L H2O2 dose, 0.301 wt.% Mn concentration, and 204 min irradiation time) COD, PCs, color, and TOC removal efficiencies of 88.87%, 86.04%, 62.8%, and 84.66%, respectively, were obtained. Statistical analysis showed that the response variable's removal from TPOME estimation had high R2 and low RMSE, MSE, MAD, MAE, and MAPE values, indicating high reliability. This study demonstrated the significant potential of the developed photocatalytic system for the treatment of waste effluent generated by the palm oil industry and other agro-industries, with the ability to simultaneously reduce a number of organic pollution indicators (OPIs).
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Peróxido de Hidrogênio , Eliminação de Resíduos Líquidos , Óleo de Palmeira , Peróxido de Hidrogênio/química , Manganês/análise , Fotólise , Reprodutibilidade dos Testes , Titânio/química , Resíduos Industriais/análiseRESUMO
Resin composite mimics tooth tissues both in structure and properties, and thus, they can withstand high biting force and the harsh environmental conditions of the mouth. Various inorganic nano- and micro-fillers are commonly used to enhance these composites' properties. In this study, we adopted a novel approach by using pre-polymerized bisphenol A-glycidyl methacrylate (BisGMA) ground particles (XL-BisGMA) as fillers in a BisGMA/triethylene glycol dimethacrylate (TEGDMA) resin system in combination with SiO2 nanoparticles. The BisGMA/TEGDMA/SiO2 mixture was filled with various concentrations of XL-BisGMA (0, 2.5, 5, and 10 wt.%). The XL-BisGMA added composites were evaluated for viscosity, degree of conversion (DC), microhardness, and thermal properties. The results demonstrated that the addition of a lower concentration of XL-BisGMA particles (2.5 wt.%) significantly reduced (p ≤ 0.05) the complex viscosity from 374.6 (Pa·s) to 170.84. (Pa·s). Similarly, DC was also increased significantly (p ≤ 0.05) by the addition of 2.5 wt.% XL-BisGMA, with the pristine composite showing a DC of (62.19 ± 3.2%) increased to (69.10 ± 3.4%). Moreover, the decomposition temperature has been increased from 410 °C for the pristine composite (BT-SB0) to 450 °C for the composite with 10 wt.% of XL-BisGMA (BT-SB10). The microhardness has also been significantly reduced (p ≤ 0.05) from 47.44 HV for the pristine composite (BT-SB0) to 29.91 HV for the composite with 2.5 wt.% of XL-BisGMA (BT-SB2.5). These results suggest that a XL-BisGMA could be used to a certain percentage as a promising filler in combination with inorganic fillers to enhance the DC and flow properties of the corresponding resin-based dental composites.
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Dental resin composites (DRCs) have gained immense popularity as filling material in direct dental restorations. They are highly valued for their ability to closely resemble natural teeth and withstand harsh oral conditions. To increase the clinical performance of dental restorations, various fillers are incorporated into DRCs. Herein, the effect of incorporating pre-polymerized triethylene glycol dimethacrylate (P-TEGDMA) as a co-filler in varying proportions (0%, 2.5%, 5%, and 10% by weight) into bisphenol A-glycidyl methacrylate (BisGMA)/TEGDMA/SiO2 resin composite was investigated. The obtained DRCs were examined for morphology, rheological properties, degree of crosslinking (DC), Vickers microhardness (VMH), thermal stability, and flexural strength (FS). The results revealed that SiO2 and P-TEGDMA particles were uniformly dispersed. The introduction of P-TEGDMA particles (2.5 wt.%) into the resin composite had a remarkable effect, leading to a significant reduction (p ≤ 0.05) in complex viscosity, decreasing from 393.84 ± 21.65 Pa.s to 152.84 ± 23.94 Pa.s. As a result, the DC was significantly (p ≤ 0.05) improved from 61.76 ± 3.80% to 68.77 ± 2.31%. In addition, the composite mixture demonstrated a higher storage modulus (G') than loss modulus (Gâ³), indicative of its predominantly elastic nature. Moreover, the thermal stability of the DRCs was improved with the addition of P-TEGDMA particles by increasing the degradation temperature from 410 °C to 440 °C. However, the VMH was negatively affected. The study suggests that P-TEGDMA particles have the potential to be used as co-fillers alongside other inorganic fillers, offering a means to fine-tune the properties of DRCs and optimize their clinical performance.
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The aim of this work was to assess the limiting rate of eugenol (Eg) and eugenyl-glycidyl methacrylate (EgGMA) at which the ideal degree of conversion (DC) of resin composites is achieved. For this, two series of experimental composites, containing, besides reinforcing silica and a photo-initiator system, either EgGMA or Eg molecules at 0-6.8 wt% per resin matrix, principally consisting of urethane dimethacrylate (50 wt% per composite), were prepared and denoted as UGx and UEx, where x refers to the EgGMA or Eg wt% in the composite, respectively. Disc-shaped specimens (5 × 1 mm) were fabricated, photocured for 60 s, and analyzed for their Fourier transform infrared spectra before and after curing. The results revealed concentration-dependent DC, increased from 56.70% (control; UG0 = UE0) to 63.87% and 65.06% for UG3.4 and UE0.4, respectively, then dramatically decreased with the concentration increase. The insufficiency in DC due to EgGMA and Eg incorporation, i.e., DC below the suggested clinical limit (>55%), was observed beyond UG3.4 and UE0.8. The mechanism behind such inhibition is still not fully determined; however, radicals generated by Eg may drive its free radical polymerization inhibitory activity, while the steric hindrance and reactivity of EgGMA express its traced effect at high percentages. Therefore, while Eg is a severe inhibitor for radical polymerization, EgGMA is safer and can be used to benefit resin-based composites when used at a low percentage per resin.
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A new eugenyl dimethacrylated monomer (symbolled BisMEP) has recently been synthesized. It showed promising viscosity and polymerizability as resin for dental composite. As a new monomer, BisMEP must be assessed further; thus, various physical, chemical, and mechanical properties have to be investigated. In this work, the aim was to investigate the potential use of BisMEP in place of the BisGMA matrix of resin-based composites (RBCs), totally or partially. Therefore, a list of model composites (CEa0, CEa25, CEa50, and CEa100) were prepared, which made up of 66 wt% synthesized silica fillers and 34 wt% organic matrices (BisGMA and TEGDMA; 1:1 wt/wt), while the novel BisMEP monomer has replaced the BisGMA content as 0.0, 25, 50, and 100 wt%, respectively. The RBCs were analyzed for their degree of conversion (DC)-based depth of cure at 1 and 2 mm thickness (DC1 and DC2), Vickers hardness (HV), water uptake (WSP), and water solubility (WSL) properties. Data were statistically analyzed using IBM SPSS v21, and the significance level was taken as p < 0.05. The results revealed no significant differences (p > 0.05) in the DC at 1 and 2 mm depth for the same composite. No significant differences in the DC between CEa0, CEa25, and CEa50; however, the difference becomes substantial (p < 0.05) with CEa100, suggesting possible incorporation of BisMEP at low dosage. Furthermore, DC1 for CEa0-CEa50 and DC2 for CEa0-CEa25 were found to be above the proposed minimum limit DC of 55%. Statistical analysis of the HV data showed no significant difference between CEa0, CEa25, and CEa50, while the difference became statistically significant after totally replacing BisGMA with BisMEP (CEa100). Notably, no significant differences in the WSP of various composites were detected. Likewise, WSL tests revealed no significant differences between such composites. These results suggest the possible usage of BisMEP in a mixture with BisGMA with no significant adverse effect on the DC, HV, WSP, and degradation (WSL).
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BACKGROUND: Non-newtonian fluids, especially shear thinning fluids, have several applications in the polymer industry, food industry, and even everyday life. The viscosity of shear thinning fluids is decreased by two or three orders of magnitude due to the alignment of the molecules in order when the shear rate is increased, and it cannot be ignored in the case of polymer processing and lubrication problems. OBJECTIVE: So, the effects of viscosities at the low and high shear rates on the heat and mass boundary layer flow of shear thinning fluid over moving belts are investigated in this study. For this purpose the generalized Carreau model of viscosity relate to shear rate is used in the momentum equation. The Carreau model contains the five parameters: low shear rate viscosity, high shear rate viscosity, viscosity curvature, consistency index, and flow behavior index. For the heat flow, the expression of the thermal conductivity model similar to the viscosity equation due to the non-Newtonian nature of the fluid is used in the energy equation. METHODS: On the mathematical model of the problem, boundary layer approximations are applied and then simplified by applying the similarity transformations to get the solution. The solution of the simplified equations is obtained by numerical technique RK-shooting method. The results are compared with existing results for limited cases and found good agreement. RESULTS: The results in the form of velocity and temperature profiles under the impact of all the viscosity's parameters are obtained and displayed in graphical form. Moreover, the boundary layer parameters such as the thickness of the regions, momentum thickness, and displacement thickness are calculated to understand the structure of the boundary layer flow of fluid. CONCLUSION: The velocity and temperature of the fluid are decreased and increased respectively by all viscosity's parameters of the model. So, the results of the boundary layer fluid flow under rheological parameters will not only help engineers to design superior chemical equipment but also help improve the economy and efficiency of the overall process.
Assuntos
Temperatura Alta , Modelos Teóricos , Polímeros , Reologia/métodos , ViscosidadeRESUMO
Polymethyl methacrylate (PMMA) is often used in restorative dentistry for its easy fabrication, aesthetics, and low cost for interim restorations. However, poor mechanical properties to withstand complex masticatory forces are a concern for clinicians. Therefore, this study aimed to modify a commercially available PMMA-based temporary restorative material by adding TiO2 and ZrO2 nanoparticles in different percentages as fillers and to investigate its physio-mechanical properties. Different percentages (0, 0.5, 1.5, and 3.0 wt%) of TiO2 and ZrO2 nanoparticles were mixed with the pristine PMMA resin (powder to liquid ratio: 1 : 1) and homogenized using high-speed mixer. The composites obtained were analyzed for their flexural strength (F.S.), elastic modulus (E.M.), Vickers hardness (H.V.), surface roughness Ra, morphology and water contact angle (WCA). The mean average was determined with standard deviation (SD) to analyze the results, and a basic comparison test was conducted. The results inferred that adding a small amount (0.5 wt%) of TiO2 and ZrO2 nanoparticles (NPs) could significantly enhance the physio-mechanical and morphological characteristics of PMMA interim restorations. EM and surface hardness increased with increasing filler content, with 3.0 wt.% ZrO2 exhibiting the highest EM (3851.28 MPa), followed by 3.0 wt.% TiO2 (3632.34 MPa). The WCA was significantly reduced from 91.32 ± 4.21° (control) to 66.30 ± 4.23° for 3.0 wt.% ZrO2 and 69.88 ± 3.55° for 3.0 wt.% TiO2. Therefore, TiO2 and ZrO2 NPs could potentially be used as fillers to improve the performance of PMMA and similar interim restorations.