Coupled Electron-Nuclear Dynamics Induced and Monitored with Femtosecond Soft X-ray Pulses in the Amino Acid Glycine.

The coupling of electronic and nuclear motion in polyatomic molecules is at the heart of attochemistry. The molecular properties, transient structures, and reaction mechanism of these many-body quantum objects are defined on the level of electrons and ions by molecular wave functions and their coherent superposition, respectively. In the present contribution, we monitor nonadiabatic quantum wave packet dynamics during molecular charge motion by reconstructing both the oscillatory charge density distribution and the characteristic time-dependent nuclear configuration coordinate from time-resolved Auger electron spectroscopic data recorded in previous studies on glycine molecules [Schwickert et al. Sci. Adv. 2022, 8, eabn6848]. The electronic and nuclear motion on the femtosecond time scale was induced and probed in kinematically complete soft X-ray experiments at the FLASH free-electron laser facility. The detailed analysis of amplitude, instantaneous phase, and instantaneous frequency of the propagating many-body wave packet during its lifecycle provides unprecedented insight into dynamical processes beyond the Born-Oppenheimer approximation. We are confident that the refined experimental data evaluation helps to develop new theoretical tools to describe time-dependent molecular wave functions in complicated but ubiquitous non-Born-Oppenheimer photochemical conditions.

Femtosecond laser assisted selective etching of microchannels in lithium niobate.

Here, we report on the fabrication of cm-long microchannels in LiNbO3 by selective etching of femtosecond laser inscribed tracks using hydrofluoric acid. We achieved a 1 cm long microchannel after 300 h of etching a single track inscribed into the volume along the optical axis of LiNbO3. Furthermore, we investigated the dependence of the etching behavior on various writing parameters. Highly selective etching with a selectivity up to 104 was achieved and a functional relationship between the etched depth and time was found. Thus, our results set the first milestone for future fabrication of 3D-hollow microstructures in the volume of LiNbO3 combining its outstanding physical properties such as the strong nonlinearity as well as the acousto- and electrooptic properties with both microfluidic and photonic structures in a monolithic setup.

Watt-level 775†nm SHG with 70% conversion efficiency and 97% pump depletion in annealed/reverse proton exchanged diced PPLN ridge waveguides.

We report on fabrication of ridge waveguides formed in congruent periodically poled lithium niobate substrates using annealed and reverse proton exchange followed by diamond blade dicing. 1 W of second-harmonic generation at 775 nm has been obtained in a single-pass in 50 mm long ridge waveguides with internal conversion efficiency of 70%. At this power level, 97% pump depletion has been reached. Although elevated temperature operation and ridge geometry help to mitigate photorefractive damage (PRD) effects, nevertheless, at even higher second harmonic outputs significant power drop with blue shift and distortion of the SHG tuning curve have been observed indicating an onset of PRD.

Multiplexing temperature-compensated open-cavity Fabry-Perot sensors at a fiber tip.

We investigate multiplexing of four highly sensitive Fabry-Perot (FP) microresonators at the tip of a single-mode optical fiber for refractive index (RI) measurements with simultaneous temperature compensation. The individual sensing elements for RI or temperature consist of either open-cavity FP resonators or solid fiber core regions fabricated by diamond-blade dicing of single-mode optical fibers, respectively. The reflectivity of the open resonators is further enhanced by matched dielectric coatings. At the same time, the solid core resonators formed by the fiber pieces between the open cavities are used as thermometers. This allows immediate compensation for temperature cross-sensitivity during RI measurements. The general performance of the sensor is demonstrated by measuring the RI of sucrose solutions, where we use phase tracking of the characteristic Fourier transform components of the backreflected optical spectrum for evaluation. The temperature sensitivity is on average 20±/∘C with an accuracy of 0.01°C, fully sufficient for biomedical applications. Meanwhile, the four RI sensing (open) cavities show high sensitivity of approximately 1160 nm/RIU. Due to the compact size of the sensor, small spatial inhomogeneities of RI can be accurately detected. If the cavities are additionally filled with molecularly imprinted polymers or coated with thin functional layers, they could also be used for the detection of trace substances in biomedical laboratory-on-a-fiber applications.

Fiber-optic sensor measuring spatial distributions of refractive index and temperature.

In this work, we present a fiber sensor designed to measure simultaneously spatial inhomogeneities of the refractive index and temperature in liquid media, for example, induced by biochemical reactions. The sensor's constituent elements are Fabry-Perot microresonators fabricated in standard single-mode optical fibers by diamond blade dicing. To allow simultaneous measurements of different refractive indices, the sensor comprises two open cavities approximately 2 mm apart. With a small Si inlay inserted into one of the resonators used for temperature measurements, the sensor allows for immediate compensation of crosstalk between temperature- and composition-induced fluids' refractive index changes. The measurements were evaluated by phase tracking of the characteristic Fourier transform components of the sensor's backreflected spectra. The temperature sensitivity of the Si inlay is 0.063 rad/°C (79 pm/°C), and an accuracy of 0.01°C is obtained. Meanwhile, the two refractive index sensing (open) cavities show a sensitivity of 1168 and 1153 nm/RIU for temperature-compensated measurements. Finally, the sensor performance to measure spatial distributions is demonstrated by measuring the diffusion behavior of sucrose in water, which allows precise monitoring of hydration effects and breaking of bonds at elevated temperatures.

Efficient Nd:Ti:LiNbO3 ridge waveguide lasers emitting around 1085 nm.

In this work, we report on efficient neodymium-doped titanium in-diffused ridge waveguide lasers in x-cut congruent LiNbO3 under excitation at 814 nm. For the sample fabrication we used our novel technique of three-side evaporation and in-diffusion for Nd and Ti incorporation into pre-defined ridges. Due to improved photorefractive damage resistance by indium tin oxide (ITO) coating we achieved stable laser operation at 1084.7 nm with a maximum output power of 108 mW and a slope efficiency of 34% exceeding the best literature values for Nd:Ti:LiNbO3 ridge waveguide lasers.

Coherent propulsion with negative-mass fields in a photonic lattice.

In this Letter, we demonstrate the first, to the best of our knowledge, coherent propulsion with negative-mass fields in an optical analog. We observe a self-accelerating state, driven by a nonlinear coherent interaction of its two components that are experiencing diffractions of opposite signs in a photonic lattice, which is analogous to the interaction of two objects with opposite mass signs. Surprisingly, the coherent propulsion is highly immune to the initial phase of the two components, which is in sharp contrast with the behavior encountered in traditional coherent wave interactions. Compared to its incoherent counter-part, the coherent propulsion exhibits an enhanced acceleration.

Dual parameter fiber-integrated sensor for refractive index and temperature measurement based on Fabry-Perot micro-resonators.

We report on a miniature all-fiber dual parameter sensor capable of simultaneous measurement of the refractive index (RI) and temperature of fluids and gases. The high-sensitivity sensing element is comprised of two Fabry-Perot (FP) micro-resonators fabricated in a single-mode fiber and has a total length of <100 µm. The RI sensing cavity is formed by diamond blade dicing, whereas a thinner silicon inlay glued into it serves as a temperature sensor. The sensor's performance was tested on sucrose solutions over a range of temperatures. For the evaluation of the backreflected FP spectra, phase tracking of the characteristic Fourier transform components was used. Good accuracy (0.01°C) and linearity of temperature measurement with Si inlay with sensitivity 0.097 rad/°C (85.2 pm/°C) were found, whereas the open cavity allowed for reliable temperature-compensated measurements of 10-3 RI steps with 290 rad/RIU (1130 nm/RIU) sensitivity.

Periodically poled ridge waveguides in KTP for second harmonic generation in the UV regime.

Waveguide circuits play a key role in modern integrated optics and provide an appealing approach to scalability in quantum optics. We report on periodically poled ridge waveguides in z-cut potassium titanyl phosphate (KTiOPO4 or KTP), a material that has recently received growing interest due to its unique dispersion properties. Ridges were defined in surface-near rubidium-exchanged KTP by use of a precise diamond-blade dicing saw. We fabricated single-mode ridge waveguides at around 800 nm which exhibit widths of 1.9-3.2 µm and facilitated type-II second harmonic generation from 792 nm to 396 nm with high efficiency of 6.6 %/W·cm2. Temperature dependence of the second harmonic process was found to be 53 pm/K. The low temperature dependence and high nonlinear conversion efficiency make our waveguides ideally suited for future operations in classical nonlinear integrated optics and integrated quantum networking applications.

Rb/Ba side-diffused ridge waveguides in KTP.

We report on characterization of ridge waveguides fabricated in KTP (KTiOPO4) by use of diamond-blade dicing and Rb/Ba ion exchange. The waveguides were prepared in substrates that have their z-axis in the surface plane, perpendicular to the waveguide direction. This hinders the RbBa ions from diffusion into the depth, as they are only mobile along the z-axis, and improves the waveguide's resistance against elevated temperature. Attenuation coefficients of 0.3 dB/cm (0.4 dB/cm) for TM (TE) polarization were measured at 1060 nm wavelength. Internal conversion efficiency of up to 3.3%/(W cm2) was determined for type-II SHG of 1064 nm.