X-ray absorption measurements on an ultrasonic spray aerosol.

Spray deposition of thin films and coatings is a widely used manufacturing process owing to its low cost, versatility and simple implementation. The objective of the presented experiments was to investigate whether X-ray absorption measurements on solutes carried by aerosols are possible, and what count rates can be achieved depending on solution flow through and the resulting mass density in the interrogation volume. The investigated prototypical spray aerosol was InCl(3) dissolved in water or ethanol dispersed via an ultrasonic nebulizer. InCl(3) spray is essential for the ion layer gas reaction process used for the deposition of In(2)S(3) buffer layers for highly efficient chalcopyrite solar cells. The discussed experiments demonstrate that measurements are possible, but that the achievement of good signal-to-noise ratios requires extended sampling times and concentrated solutions.

Comprehensive comparison of various techniques for the analysis of elemental distributions in thin films.

The present work shows results on elemental distribution analyses in Cu(In,Ga)Se2 thin films for solar cells performed by use of wavelength-dispersive and energy-dispersive X-ray spectrometry (EDX) in a scanning electron microscope, EDX in a transmission electron microscope, X-ray photoelectron, angle-dependent soft X-ray emission, secondary ion-mass (SIMS), time-of-flight SIMS, sputtered neutral mass, glow-discharge optical emission and glow-discharge mass, Auger electron, and Rutherford backscattering spectrometry, by use of scanning Auger electron microscopy, Raman depth profiling, and Raman mapping, as well as by use of elastic recoil detection analysis, grazing-incidence X-ray and electron backscatter diffraction, and grazing-incidence X-ray fluorescence analysis. The Cu(In,Ga)Se2 thin films used for the present comparison were produced during the same identical deposition run and exhibit thicknesses of about 2 µm. The analysis techniques were compared with respect to their spatial and depth resolutions, measuring speeds, availabilities, and detection limits.

Direct evidence for a reduced density of deep level defects at grain boundaries of Cu(In,Ga)Se2 thin films.

The unusual optoelectronic properties of chalcopyrite grain boundaries (GBs) have become the subject of an intense debate in recent years. In this work we investigate the defect density at GBs of Cu(In,Ga)Se2 by scanning tunneling spectroscopy. Contrary to our expectation, our results give evidence for a reduced density of deep level defects and point to an increased density of defect levels in resonance with the lower conduction band at GBs. Our findings imply low recombination activity at GBs, and thus can explain the low impact of GBs on the efficiency of chalcopyrite based solar cells.

Spectroscopic investigation of the deeply buried Cu(In,Ga)(S,Se)2/Mo interface in thin-film solar cells.

The Cu(In,Ga)(S,Se)(2)Mo interface in thin-film solar cells has been investigated by surface-sensitive photoelectron spectroscopy, bulk-sensitive x-ray emission spectroscopy, and atomic force microscopy. It is possible to access this deeply buried interface by using a suitable lift-off technique, which allows us to investigate the back side of the absorber layer as well as the front side of the Mo back contact. We find a layer of Mo(S,Se)(2) on the surface of the Mo back contact and a copper-poor stoichiometry at the back side of the Cu(In,Ga)(S,Se)(2) absorber. Furthermore, we observe that the Na content at the Cu(In,Ga)(S,Se)(2)Mo interface as well as at the inner grain boundaries in the back contact region is significantly lower than at the absorber front surface.

[A new method for the determination of circulating blood volume--erythrocyte marking with sodium fluorescein]. / Eine neue Methode zur Bestimmung des zirkulierenden Blutvolumens--Erythrozytenmarkierung mit Fluorescein-Natrium.

The knowledge of circulating blood volume extends the possibility of judgement of the circulation status and is a valuable help for the management of volume therapy. Blood volume measurements are rarely done in clinical practice in underestimation of their value for the therapy because of their high technical expense, long duration of examination, bad repeatability and radiation exposure. A method for blood volume determination which possesses more favorable abilities than known radioactive methods has been developed by staining red cells with fluorescein sodium. This paper presents an insight into the method and examines the reliability of measurement by means of repeated determinations in vivo.

Blood volume determination with sodium fluorescein and radioactive chromium--a clinical comparison of methods.

OBJECTIVE: There exists no method so far for the determination of circulating blood volume as an important parameter of circulatory function widely usable under clinical conditions. Therefore, the present study was designed to investigate whether identical distribution spaces could be measured by two methods for blood volume determination using sodium fluorescein (SoF) and radioactively labelled red blood cells (51Cr*). DESIGN: Comparative study. SETTING: Operating theatre, recovery room, or intensive care unit of a university hospital. PATIENTS: 35 patients undergoing abdominal, urological or vascular surgery. INTERVENTIONS: Simultaneous determinations of blood volume using SoF and 51Cr* in the intra- and postoperative period. RESULTS: There were no significant differences between the calculated means of blood volume (4,445 vs. 4,407 ml), red cell volume (1,554 vs. 1,540 ml), and plasma volume (2,891 vs. 2,807 ml) for 51Cr*-vs. SoF-stained red blood cells. The coefficient of correlation between the two methods was r = 0.95. The mean percentage error was -0.6% between the two methods, the precision 5.6%. CONCLUSIONS: SoF-stained erythrocytes allow a determination of the same distribution space as the well-established radioactive method using 51Cr*. Therefore, SoF-staining may replace 51Cr* labelling of red blood cells for the determination of blood volume in patients.