MXenes as emerging adsorbents for removal of environmental pollutants.

MXenes are a recently emerging class of two-dimensional nanomaterials that have gained considerable interest in the field of environmental protection. Owing to their high surface area, abundant terminal groups, and unique two-dimensional layered structures, MXenes have demonstrated high efficacy as adsorbents for various pollutants. Here we focused on the latest developments in the field of MXene-based adsorbents, including the structure and properties of MXenes, their synthesis and modification methods, and their adsorption performance and mechanisms for various pollutants. Among the pollutants that have been reported to be adsorbed by MXenes are radionuclides (U(VI), Sr(II), Cs(I), Eu(III), Ba(II), Th(IV), and Tc(VII)/Re(VII)), heavy metals (Hg(II), Cu(II), Cr(VI), and Pb(II)), dyes, per- and polyfluoroalkyl substances (PFAS), antibiotics (tetracycline, ciprofloxacin, and sulfonamides), antibiotic resistance genes (ARGs), and other contaminates. Moreover, future directions in MXene research are also suggested in this review.

Thin-Film Composite Membranes with a Carbon Nanotube Interlayer for Organic Solvent Nanofiltration.

Compared to the traditional chemical-crosslinking-based polymer, the porous polytetrafluoroethylene (PTFE) substrate is considered to be an excellent support for the fabrication of thin-film composite (TFC) organic solvent nanofiltration (OSN) membranes. However, the low surface energy and chemical inertness of PTFE membranes presented major challenges for fabricating a polyamide active layer on its surface via interfacial polymerization (IP). In this study, a triple-layered TFC OSN membrane was fabricated via IP, which consisted of a PA top layer on a carbon nanotube (CNT) interlayer covering the macroporous PTFE substrate. The defect-free formation and cross-linking degree of the PA layer can be improved by controlling the CNT deposition amount to achieve a good OSN performance. This new TFC OSN membrane exhibited a high dye rejection (the rejection of Bright blue B > 97%) and a moderate and stable methanol permeated flux of approximately 8.0 L m−2 h−1 bar−1. Moreover, this TFC OSN membrane also exhibited an excellent solvent resistance to various organic solvents and long-term stability during a continuous OSN process.