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1.
J Hazard Mater ; 137(3): 1328-32, 2006 Oct 11.
Artigo em Inglês | MEDLINE | ID: mdl-16777322

RESUMO

The simplest method is introduced for reliable estimating the detonation velocity of large class of CHNO explosives based elemental composition and specific structural groups. There is no need to use heat of formation and the other experimental data for calculation of detonation velocity in the new procedure. Only elemental composition and the number of special structural groups without using heat of formation of explosive is sufficient for reliable desk calculation of detonation velocity. The results show good agreement with experimental values with respect to computed results obtained by complex computer code using BKWS and BKWR equations of state. Predicted velocities of detonation have root-mean-square (rms) percent deviation of 2.2, 5.9 and 5.3 from experimental data for new method, BKWS and BKWR equations of state, respectively.


Assuntos
Explosões , Temperatura Alta
2.
J Phys Chem B ; 115(49): 14526-30, 2011 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-22017621

RESUMO

Preparation of the recording coating on the ink jet printing (RC-IJP) is proposed. The microstructure of RC-IJP was analyzed by scanning electron microscopy and atomic force microscope. The surface infiltration process of RC-IJP was studied. Fourier transform near-infrared (FT-NIR) spectra showed the combination and overtone vibrations information of the hydrogen-containing groups in RC-IJP structure. NIR spectra combined with partial least-squares methods were proposed for the noncontact analysis of the surface infiltration time and weight per unit area in RC-IJP. Forty-five samples were selected for the calibration sets of the surface infiltration time and weight per unit area, respectively. Spectral pretreatment method was used to develop robust calibration models. After the spectral pretreatment was optimized, the determination coefficient (R(2)) of the surface infiltration time and weight per unit area were 0.90 and 0.97, respectively. The analytical results showed that NIR spectra had significant potential for the analysis of the surface infiltration time and weight per unit area of RC-IJP.

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