RESUMO
One of the valuable fractions of paraffinic oils is the diesel fraction, which can be used as a commercial fuel. However, the high content of alkanes of normal structure (~10-40%) in the diesel fraction leads to a deterioration in the performance characteristics of the fuel and, as a result, the inability to use the diesel fraction without additional processing in the cold season at lower temperatures, which is critical for many regions with cold winters. The process of catalytic dewaxing is one of the most promising ways to improve the low-temperature characteristics of diesel fractions. This work is devoted to studying the activity of promoted Ni, Mo, and Ni-Mo catalysts based on mesoporous aluminosilicate and pre-activated bentonite in dewaxing diesel fractions. The effect of the nature and content of promoting additives on the activity of bifunctional catalysts in the process of hydroisodewaxing of diesel fraction in a flow-type reactor in the temperature range of 260-340 °C, pressure of 2 MPa and feed space velocity of 1 h-1 was studied. It is shown that the synthesized bifunctional catalysts based on mesoporous aluminosilicate and pre-activated bentonite from the Tagan field (Ni/MAS-H-bentonite, Mo/MAS-H-bentonite, and Ni-Mo/MAS-H-bentonite) have the necessary balance of Lewis and Bronsted acid centers strengths. It allows them to selectively conduct the hydroisodewaxing process. It has been established that the use of the synthesized 5% Ni-1% Mo/MAS-H-bentonite bifunctional catalyst in the diesel fractions hydroisodewaxing process under optimal process conditions makes it possible to obtain diesel fuel with low-temperature characteristics that meet the requirements for cold climate fuels: cold filter plugging point (CFPP)-minus 33 °C, flash point in a closed cup-39 °C and pour point-minus 36 °C.
RESUMO
Electrochemical methods have been increasingly gaining popularity in the field of wastewater treatment. However, the performance of these methods can be highly affected by the polarity direction as determined by the electrodes arrangement (anode to cathode or cathode to anode); as well as the characteristics of the wastewater to be treated as determined by the type of wastewater. The presented research work investigated the relationship between polarity direction and the removal of pollutants from poultry slaughterhouse wastewater using titanium and aluminium electrode materials. In the first case, the wastewater was exposed to the Ti (anode)-Al (cathode) combination, whereas in the second case the wastewater was subjected to the Al (anode)-Ti (cathode) arrangement. The two cases were designed to see if the polarity direction of the chosen electrode materials affected the removal of pollutants. The removal efficiencies were computed as a ratio of the remaining concentration in the treated effluent to the concentration before treatment. It was observed that the production processes generate highly fluctuating wastewater in terms of pollution loading; for instance, 422 to 5340 Pt-Co (minimum to maximum) were recorded from color, 126 to 2264 mg/L were recorded from total dissolved solids, and 358 to 5998 mg/L from chemical oxygen demand. Also, the research results after 40 min of retention time showed that both electrode arrangements achieved relatively high removal efficiencies; Whereby, the aluminium to titanium polarity achieved up to 100% removal efficiency from turbidity while the titanium to aluminium polarity achieved a maximum of 99.95% removal efficiency from turbidty. Also, a similar phenomenon was observed from total dissolved solids; whereby, on average 0 mg/L was achieved when the wastewater was purified using the aluminium to titanium arrangement, while on average 2 mg/L was achieved from the titanium to aluminium arrangement. A little higher removal efficiency discrepancy was observed from ammonia; whereby, the aluminium to titanium arrangement outperformed the titanium to aluminium arrangement with average removal efficiencies of 82.27% and 64.11%, respectively.
RESUMO
Due to the numerous health benefits and therapeutic properties, herbs and plant metabolites/extracts are gaining popularity. This is particularly evident in the current era of drug resistance and the adverse effects of chemical drugs. Ocimum basilicum, also known as basil, has been extensively studied for its pharmacological benefits, including antimicrobial, antifungal, antioxidant, anti-inflammatory, antiviral, and wound healing properties. As a result, this plant has the potential to treat a wide range of diseases in both humans and animals. Ocimum basilicum contains various bioactive chemical compounds, such as neryl acetate, 1,8-cineole, p-allylanisole, geraniol, methyl eugenol, methyl chavicol, and trans-α-bergamotene. The latest advancements in technology can be utilised to enhance the beneficial properties of raw Ocimum basilicum extract. This review compiles and presents the profile of phytocomponents and pharmacological properties of Ocimum basilicum. The findings presented here will contribute to further research on this remarkable herb, aiming to develop effective pharmaceutical solutions for various health issues in humans and animals.