Investigation of the modifications properties in fused silica by the deep-focused femtosecond pulses.

In this study, we demonstrate the elongated Type I modifications in fused silica with an axial length > 50 µm. Such extended longitudinal dimensions were obtained by deep focusing radiation of a femtosecond laser inside fused silica at a depth of 2 mm. The transition from the Type II modification (nanogratings) to the Type I modification (refraction index change) was observed with increasing focusing depth at the constant pulse energy. The refractive index changes of ∼ 1.5×10-3 for a single pass and 2.4×10-3 for multiple passes were demonstrated. The radial dimensions of the deep-focused modifications were confined to 0.5-1.5 µm size. By overlapping the modifications in radial and axial directions, 1D phase grating in the depth range from 2 to 5 mm was recorded, allowing to split of the beam with a diffraction efficiency of > 96%. We demonstrate that the aberration-based recording with a Gaussian beam in fused silica is a simple tool for fabricating complex phase diffractive optical elements.

Transversal and axial modulation of axicon-generated Bessel beams using amplitude and phase masks for glass processing applications.

The control of laser-induced microcracks in the volume of transparent materials is essential for scribing processes. In this paper, we investigate the effect of various amplitude and single-level phase masks on both transverse and axial intensity distribution of the conventional axicon-generated Bessel beams. Furthermore, we demonstrate the volumetric crack control induced by an asymmetrical central core with an appropriately selected intensity level to avoid the influence of peripheral intensity maxima. Proper alignment of cracks and intra-distance between the modifications results in the reduced separation stress of the scribed samples. Furthermore, the additional amplitude modulation of the incident Gaussian beam is introduced to flatten the axial intensity distribution of the axicon-generated Bessel beam.

Quality and flexural strength of laser-cut glass: classical top-down ablation versus water-assisted and bottom-up machining.

The growing applicability of glass materials drives the development of novel processing methods, which usually lack comprehensive comparison to conventional or state-of-art ones. That is especially delicate for assessing the flexural strength of glass, which is highly dependent on many factors. This paper compares the traditional top-down laser ablation methods in the air to those assisted with a flowing water film using picosecond pulses. Furthermore, the bottom-up cutting method using picosecond and nanosecond pulses is investigated as well. The cutting quality, sidewall roughness, subsurface damage and the four-point bending strength of 1 mm-thick soda-lime glass are evaluated. The flexural strength of top-down cut samples is highly reduced due to heat accumulation-induced cracks, strictly orientated along the sidewall. The subsurface crack propagation can be reduced using water-assisted processing, leading to the highest flexural strength among investigated techniques. Although bottom-up cut samples have lower flexural strength than water-assisted, bottom-up technology allows us to achieve higher cutting speed, taper-less sidewalls, and better quality on the rear side surface and is preferable for thick glass processing.

Laser-assisted surface activation for fabrication of flexible non-enzymatic Cu-based sensors.

A rapid and effective technique has been develped for the fabrication of sensor-active copper-based materials on the surface of such flexible polymers as terephthalate, polyethylene naphthalate, and polyimide using the method of laser surface modification. For this purpose, we optimized the polymer surface activation parameters using laser sources with a picosecond pulse duration for subsequent selective metallization within the activated region. Furthermore, the fabricated copper structures were modified with gold nanostructures and by electrochemical passivation to produce copper-gold and oxide-containing copper species, respectively. As a result, in comparison with pure copper electrodes, these composite materials exhibit much better electrocatalytic performance concerning the non-enzymatic identification of biologically important disease markers such as glucose, hydrogen peroxide, and dopamine.

Development of Wireless Sensor Network for Environment Monitoring and Its Implementation Using SSAIL Technology.

The Internet of Things (IoT) technology and its applications are turning real-world things into smart objects, integrating everything under a common infrastructure to manage performance through a software application and offering upgrades with integrated web servers in a timely manner. Quality of life, the green economy, and pollution management in society require comprehensive environmental monitoring systems with easy-to-use features and maintenance. This research suggests implementing a wireless sensor network with embedded sensor nodes manufactured using the Selective Surface Activation Induced by Laser technology. Such technology allows the integration of electrical circuits with free-form plastic sensor housing. In this work, a low-cost asynchronous web server for monitoring temperature and humidity sensors connected to the ESP32 Wi-Fi module has been developed. Data from sensor nodes across the facility are collected and displayed in real-time charts on a web server. Multiple web clients on the same network can access the sensor data. The energy to the sensor nodes could be powered by harvesting energy from surrounding sources of electromagnetic radiation. This automated and self-powered system monitors environmental and climatic factors, helps with timely action, and benefits sensor design by allowing antenna and rf-circuit formation on various plastics, even on the body of the device itself. It also provides greater flexibility in hardware modification and rapid large-scale deployment.

Chemical etching of fused silica after modification with two-pulse bursts of femtosecond laser.

Bursts of femtosecond laser pulses were used to record internal modifications inside fused silica for selective chemical etching. Two-pulse bursts with a variable energy ratio between those pulses at a fixed inter-pulse duration of 14.5 ns were applied for the first time. The selective chemical etching rate of the laser-modified material with the burst of two pulses was compared to the single-pulse regime when etching in HF and KOH etchants. The advantage of the burst-mode processing was demonstrated when etching was performed in the KOH solution. More regular nanogratings were formed, and the etching initiation was more stable when burst pulses were applied for fused silica modification. The vertical planar structures were obtained using the two-pulse bursts with an energy ratio of 1:2, increasing the etching rate by more than 35% compared to the single-pulse processing. The highest ever reported selectivity of 1:2000 was demonstrated by introducing the two-pulse burst mode.

In-depth comparison of conventional glass cutting technologies with laser-based methods by volumetric scribing using Bessel beam and rear-side machining.

With the development of industrial lasers and novel glass processing techniques, which offer high speed, quality and precision, this becomes an attractive alternative to conventional methods, such as mechanical scribing and cleaving, diamond saw and waterjet cutting, commonly used in the industry. However, the emerging techniques lack thorough validation with respect to well-established methods. To this end, we present a detailed comparison of different glass cutting methods, taking into account surface quality, side-wall roughness, residual stresses and flexural strength. In addition, samples were examined after fracture, and the flexural strength was estimated according to the quarter elliptical corner flaws, which were the main reason of glass failure. Two laser glass processing techniques were investigated - the rear-side glass processing with tightly focused nanosecond laser pulses and sub-nanosecond laser volumetric scribing with asymmetrical Bessel beam. Results were compared to mechanical scribing and breaking, diamond saw and waterjet cutting.

Laser-fabricated axicons challenging the conventional optics in glass processing applications.

Laser-based fabrication can be an alternative technology to mechanical grinding and polishing processes. However, the performance of these elements in real applications still needs to be validated. In this paper, we demonstrate that the subtractive fabrication technology is able to produce high-quality axicons from fused silica, which can be efficiently used for glass processing. We comprehensively investigate axicons, fabricated by ultrashort pulsed laser ablation with subsequent CO2 laser polishing, and compare their performance with commercially available axicons. We show that laser-fabricated axicons are comparable in quality with a precision commercial axicon. Furthermore, we demonstrate the intra-volume glass modification and dicing, utilising mJ-level laser pulses. We show that the tilting operation of the laser-fabricated axicons results in the formation of directional transverse cracks, which significantly enhance the 1 mm-thick glass dicing process.

Laser-processed diffractive lenses for the frequency range of 4.7 THz.

The development of diffractive lenses for the upper terahertz (THz) frequency range above 1 THz was successfully demonstrated by employing a direct laser ablation (DLA) technology. Two types of samples such as the Soret zone plate lens and the multi-level phase-correcting Fresnel lens were fabricated of a metal foil and crystalline silicon, respectively. The focusing performance along the optical axis of a 4.745 THz quantum cascade laser beam with respect to the positioning angle of the sample was studied by using a real-time microbolometric camera. A binary-phase profile sample demonstrated the values of the focusing gain and focused beam size up to 25 dB and 0.15 mm (2.4λ), respectively. The increase of the phase quantization level to eight led to higher (up to 29 dB) focusing gain values without a measurable increase of optical losses. All the samples were tolerant to misalignment as large as 10 deg of oblique incidence with a focusing power drop no larger than 10%. The results pave the way for new applications of industry-ready DLA technology in the entire THz range.

Aberration-controlled Bessel beam processing of glass.

It is known that Bessel beam generation with a non-ideal axicon induces beam pattern distortions. In this paper, we introduce a simple method for non-ideal axicon-generated Bessel beam reconstruction by tilting the axicon perpendicular to its optical axis. We found an optimum axicon tilt angle where beam distortions can be compensated by inducing additional astigmatic aberrations. At optimal tilt angle, the central spot symmetry and focal depth was increased. By this method we could control crack formation symmetry in the bulk of glass, which is essential for many transparent material processing applications.

High-density gas capillary nozzles manufactured by hybrid 3D laser machining technique from fused silica.

In this report, an efficient hybrid laser technique, nanosecond laser rear-side processing and femtosecond laser-assisted selective etching (FLSE) for the manufacturing of high-density gas capillary targets, is demonstrated. Cylindrical capillary nozzles for laser betatron X-ray sources were numerically simulated, manufactured from fused silica by 3D laser inscription and characterized using interferometry and gas density reconstruction. The dependence of gas concentration profiles on the wall roughness of cylindrical channels is presented.

Laser Irradiation of Gd-Si and Gd-Si-Ge Colloid Mixtures for the Fabrication of Compound Nanoparticles.

Binary (Gd5 Si4 , GdSi) and ternary (Gd5 Si2 Ge2 ) compound nanoparticles (NPs) were prepared by laser irradiation of a mixture of colloidal solutions containing NPs of the relevant elements. It is assumed that the compound NPs are formed by heating, co-melting, and chemical interactions in the alloyed droplets. The blackbody-like radiation of the heated NPs was used for temperature control of the NP-preparation process. The obtained results demonstrate that laser irradiation of colloidal NPs provides unique possibilities not only for the synthesis of compound NPs but also for control of their phase composition and size. The synthesized Gd-based compound NPs exhibited magnetic transition at an ordering temperature, TC , in the range of 310-320 K. Thus, the magnetic properties of the synthesized particles confirm their potential for biomedical applications, in particular, for magnetic hyperthermia treatment.

Nanoscale thermal diffusion during the laser interference ablation using femto-, pico-, and nanosecond pulses in silicon.

Laser interference ablation in silicon using femto-, pico-, and nanosecond pulses was investigated. The experimental and computational results provide information about nanoscale thermal diffusion during the ultra-short laser-matter interaction. The temperature modulation depth was introduced as a parameter for quality assessment of laser interference ablation. Based on the experiments and calculations, a new semi-empirical formula which combines the interference period with the laser pulse duration, the thermal modulation depth and the thermal diffusivity of the material was derived. This equation is in excellent agreement with the experimental and modelling results of laser interference ablation. This new formula can be used for selecting the appropriate pulse duration for periodical structuring with the required resolution and quality.

Photo-polymerization differences by using nanosecond and picosecond laser pulses.

Formation of polymeric pillars by using laser interference lithography is compared for nanosecond and picosecond laser pulses. The experimental results are explained by dynamics of laser-excited radicals. The shape of fabricated structures demonstrates that thermal accumulation and oxygen diffusion from the surrounding air make an influence on polymerization when the pulse duration is in the nanosecond range. By using picosecond laser pulses, the thermal accumulation and oxygen diffusion effects are not important for low repetition rate (500 Hz), and they become relevant only at the repetition rates higher than ≥ 1 kHz. It is shown that thermal accumulation is caused by a low-temperature diffusivity and heat accumulation at the polymer-glass interface, and it plays a significant role in the final shape of the structures fabricated using the nanosecond laser pulses.

Experimental demonstration of pulse multiplexing and beam combining of four fiber lasers by noncollinear frequency conversion in an LBO crystal.

In this work, we provide proof-of-concept experimental realization of pulse multiplexing and beam combining of four pulsed Yb-doped fiber lasers by noncollinear frequency up-conversion in an LBO crystal. An overall conversion efficiency of 51% and up to 29 W average power in a combined 532 nm beam were achieved. These results correspond to an improvement by a factor of 2 compared to the average power extracted from a single fiber amplifier.

Non-ideal axicon-generated Bessel beam application for intra-volume glass modification.

The extended focal depth of Bessel beams is a very attracting property for glass cutting applications. However, Bessel beam generation with a non-ideal conical lens induces beam pattern distortions. We present our novel results on bulk modifications of soda-lime glass using a non-ideal axicon-generated Bessel beam. Modelling of the Bessel beam pattern and experimental measurements indicated ellipticity of the central core diameter. That resulted in the formation of cracks in a transverse direction inside the bulk of glass. Furthermore, we demonstrate the possibility to control the transverse crack propagation direction, which is crucial in the case of glass cutting applications.

Background-free electric field-induced second harmonic generation with interdigitated combs of electrodes.

The electric field-induced second harmonic (EFISH) generation is a powerful tool for the investigation of optical nonlinearities, material polarization, internal electric fields, and other properties of photonic materials and devices. A conventional generation of the second harmonics (SH) in materials with the disturbed centrosymmetry causes a field-independent background to EFISH and limits its applications. Here we suggest and analyze the application of the interdigitated combs of electrodes for EFISH generation in thin films. Interdigitated electrodes form an optical transmission amplitude diffraction grating. Phase matching of the EFISH radiation creates unusual diffraction fringes with the zero intensity along the zeroth order direction and with the diffraction angles different from diffraction angles of incident fundamental laser radiation and its second harmonics. It enables a simple geometrical separation of the EFISH signal from a conventional SH background, simplifies the sample preparation, and provides additional experimental possibilities. We demonstrate applicability of the suggested technique for characterization of submicrometer thickness organic films of transparent and resonantly interacting polymers and of their mixtures.

Bessel-like beam array formation by periodical arrangement of the polymeric round-tip microstructures.

Here, we report the formation of Bessel-like beam array from periodic patterns fabricated by the four-beam interference lithography. Characteristics of the generated Bessel-like beams depend on geometrical parameters of the fabricated microaxicon-like structures, which can be easily controlled via the laser processing parameters. The output beam characteristics disclose the attributes of Bessel beams. The demonstrated method enables an easy fabrication of angular-tolerant wavefront detectors, optical tweezers, optical imaging systems or materials processing tools, having a broad range of applications.

Ytterbium-doped fiber ultrashort pulse generator based on self-phase modulation and alternating spectral filtering.

We numerically and experimentally demonstrate a Yb-doped fiber ultrashort pulse generator based on self-phase modulation and alternating spectral filtering, operating at a wavelength of 1060 nm and providing a stable ultrashort pulse train. Pulses with energy up to 2.8 nJ were generated experimentally and were limited only by available pump power.

Reflective terahertz imaging with the TEM01 mode laser beam.

Reflective terahertz imaging with a first-order Hermite-Gaussian laser beam was experimentally investigated. High spatial resolution targets prepared by direct laser microprocessing were used to evaluate the performance. The reflection imaging system at 2.524 THz frequency demonstrated up to diffraction limited resolution using the single focusing mirror with the numerical aperture not smaller than 0.6. The TEM(01) mode laser beam was also applied for practical samples such as silicon solar cell terahertz (THz) imaging. It is shown that usage of appropriate optics enables us to obtain high-quality THz images with the multimode laser beam.