Particle balance and return loops for microplastics in a tertiary-level wastewater treatment plant.

Microplastics (MPs) from households, stormwater, and various industries are transported to wastewater treatment plants (WWTPs), where a high proportion of them are captured before discharging their residuals to watersheds. Although recent studies have indicated that the removed MPs are mainly retained in wastewater sludge, sludge treatment processes have gained less attention in MP research than water streams at primary, secondary, and tertiary treatments. In this study, we sampled 12 different process steps in a tertiary-level municipal WWTP in central Finland. Our results showed that, compared to the plant influent load, three times more MPs circulated via reject water from the sludge centrifugation back to the beginning of the treatment process. Fibrous MPs were especially abundant in the dewatered sludge, whereas fragment-like MPs were observed in an aqueous stream. We concluded that, compared to the tertiary effluent, sludge treatment is the major exit route for MPs into the environment, but sludge treatment is also a return loop to the beginning of the process. Our sampling campaign also demonstrated that WWTPs with varying hydraulic conditions (such as the one studied here) benefit from disc filter-based tertiary treatments in MP removal.

Optical Monitoring of Microplastics Filtrated from Wastewater Sludge and Suspended in Ethanol.

The abundance of microplastics (MPs) in the atmosphere, on land, and especially in water bodies is well acknowledged. In this study, we establish an optical method based on three different techniques, namely, specular reflection to probe the medium, transmission spectroscopy measurements for the detection and identification, and a speckle pattern for monitoring the sedimentation of MPs filtrated from wastewater sludge and suspended in ethanol. We used first Raman measurements to estimate the presence and types of different MPs in wastewater sludge samples. We also used microscopy to identify the shapes of the main MPs. This allowed us to create a teaching set of samples to be characterized with our optical method. With the developed method, we clearly show that MPs from common plastics, such as polypropylene (PP), polyethylene terephthalate (PET), polystyrene (PS), and polyethylene (PE), are present in wastewater sludge and can be identified. Additionally, the results also indicate that the density of the plastics, which influences the sedimentation, is an essential parameter to consider in optical detection of microplastics in complex natural environments. All of the methods are in good agreement, thus validating the optics-based solution.