Light-driven oscillations of entangled nematic colloidal chains.

Laser tweezers have been used to drive the oscillations of a chain of entangled colloidal particles in the nematic liquid crystal 5CB. The amplitude and phase of light-driven oscillations have been determined for the motion of individual colloidal particles. The collective motion of 4.8µm silica particles is highly damped for a driving frequency above 0.5Hz. The results were compared to an effective bead-spring model, where the motion of elastically coupled particles is hindered by viscous damping and hydrodynamic coupling. Qualitative agreement between theory and experiment was obtained.

Topological defect transformation and structural transition of two-dimensional colloidal crystals across the nematic to smectic-A phase transition.

We observe that topological defects in nematic colloids are strongly influenced by the elasticity and onset of smectic layering across the nematic (N) to smectic-A (SmA) phase transition. When approaching the SmA phase from above, the nematic hyperbolic hedgehog defect that accompanies a spherical colloidal inclusion is transformed into a focal conic line in the SmA phase. This phase transformation has a strong influence on the pairwise colloidal interaction and is responsible for a structural transition of two-dimensional colloidal crystals. The pretransitional behavior of the point defect is supported by Landau-de Gennes Q-tensor modeling accounting for the increasing elastic anisotropy.

Chiral bipolar colloids from nonchiral chromonic liquid crystals.

We demonstrate that high anisotropy of elastic constants of chromonic liquid crystals leads to a number of spontaneously twisted nematic director fields around colloidal particles in these non-chiral fluids. For spherical colloidal particles with surface inducing degenerate planar nematic ordering we observe that boojum defects at the particles' poles acquire twisted internal structure, extending up to three particle diameters along the rubbing direction of the cell. The twist handedness of the two boojum defects at the poles of the particle can be either the same or opposite, and we can switch the defects handedness by localized thermal microquenching. Numerical simulations confirm that the transitions into the distorted states are induced by lowering of the twist elastic constant, which results in two (meta)stable chiral configurations of the boojums, separated by an energy barrier much higher than the thermal energy. We show that boojum handedness can change the pairwise elastic interaction between the two particles positioned along the rubbing direction from repulsive to attractive.