RESUMO
Disk-shaped torque sensors are widely used in robotic joints and wheel driving. However, in terms of conventional spoke-type geometries, there is always a trade-off between sensitivity and stiffness, because their strain exposure depends upon a bending deformation mode which causes strain nonuniformity. This paper presents a lever-type method of strain exposure that performs a uniaxial tension and compression deformation mode to optimize the strain uniformity and improve the trade-off. Moreover, on the basis of this approach, the proposed disk F-shaped torque sensor enjoys has axial thinness, easy installation of strain gauges and flexible customization. The simulation and experimental results have validated the basic design idea.
RESUMO
Due to the low intrinsic hole mobility caused by the orthogonal conformation of two fluorene units in Spiro-OMeTAD which is a classic hole-transporting material (HTM) in perovskite solar cells (PSCs), Spiro-OMeTAD based PSCs generally can only obtain high performances through a sophisticated doping process with dopants/additives, which adds to the cost and complicacy of device fabrication, and also adversely affects the stability of PSC devices. Herein, a novel dispiro-based HTM, WH-1, is designed by cleverly replacing the central carbon atom of Spiro-OMeTAD with cyclohexane, and the spatial configuration of the HTM is changed from vertical orthogonality of the two fluorene units to a parallel arrangement, which is beneficial for the formation of a homogeneous and compact HTM film on the surface of the perovskite film, improvement of intermolecular electronic coupling and intrinsic hole mobility. WH-1 is obtained by two-step facile synthesis with a high yield from commercially available materials. WH-1 is used in PSCs as a dopant-free HTM, which is the first time that the dispiro-based molecule has been applied as a dopant-free HTM, and a power conversion efficiency (PCE) of 19.57% is obtained, rivaling Li-TFSI/t-BP doped Spiro-OMeTAD in PCE (20.29%), and showing obvious superior long-term stability.