Design of pH-responsive SAP polymer for pore solution chemistry regulation and crack sealing in cementitious materials.

The crack development is considered to be one of the most severe threats to the durability of concrete infrastructure. This study aims to enhance the durability performance of cementitious material with the pH-responsive Superabsorbent Polymer (SAP). The SAP was synthesized with acrylic acid (AA)-methyl acrylate (MA) precursors, and three type samples with different crosslinking levels were prepared. The examination on the pH sensitivity indicated that the swelling capacity of the prepared SAP would first increase and then decrease with solution alkalinity, and the peak swelling potential was achieved around pH value of 12 for all the three type SAP with solution/gel mass ratio of 500. Further examination indicated the alkalinity of the buffer solution was reduced during the adsorption test, which can be caused by the hydrolysis of the amide groups and the crosslinker. Besides that, it was also found the solution/gel ratio and the Ca(OH)2 content could affect the swelling potential of the SAP. After that, the performance tests were conducted for the evaluation of concrete with SAP. A wax-coating protocol for the SAP was designed by using the hot-water method to prevent its swelling during mixing process. It was found that the strength reduction for samples with wax-coated SAP was insignificant compared to that of the control samples. Furthermore, durability tests supported the wax-shell could be broken by the crack propagation in concrete. And further experimental studies are needed to optimize the wax-size and shell thickness for enhanced self-sealing efficiency.

Early-Age Cracking of Fly Ash and GGBFS Concrete Due to Shrinkage, Creep, and Thermal Effects: A Review.

Supplementary cementitious materials (SCMs) are eco-friendly cementitious materials that can partially replace ordinary Portland cement (OPC). The occurrence of early-age cracking in OPC-SCM blended cement is a significant factor impacting the mechanical properties and durability of the concrete. This article presents a comprehensive review of the existing research on cracking in OPC-SCM concrete mix at early ages. To assess the effects of SCMs on the early-age cracking of concrete, the properties of blended cement-based concrete, in terms of its viscoelastic behavior, evolution of mechanical performance, and factors that affect the risk of cracking in concrete at early ages, are reviewed. The use of SCMs in OPC-SCM concrete mix can be an effective method for mitigating early-age cracking while improving the properties and durability of concrete structures. Previous research showed that the shrinkage and creep of OPC-SCM concrete mix are lower than those of conventional concrete. Moreover, the lower cement content of OPC-SCM concrete mix resulted in a better resistance to thermal cracking. Proper selection, proportioning, and implementation of SCMs in concrete can help to optimize the performance and reduce the environmental impact of OPC-SCM concrete mix.

Effect of Various Fly Ash and Ground Granulated Blast Furnace Slag Content on Concrete Properties: Experiments and Modelling.

Concrete is known as the most globally used construction material, but it releases a huge amount of greenhouse gases due to cement production. Recently, Supplementary Cementitious Materials (SCMs) such as fly ash and Ground Granulated Blast Furnace Slag (GGBFS) have been widely used in concrete to reduce the cement content. However, SCMs can alter the mechanical properties and time-dependent behaviors of concrete and the early age mechanical properties of concrete significantly affect the concrete cracking in the engineering field. Therefore, evaluation of the development of the mechanical properties of SCMs-based concrete is vital. In this paper, the time development of mechanical properties of concrete mixes with various fly ash and GGBFS was experimentally investigated. Four different cement replacement levels including 0%, 20%, 30%, and 40% by fly ash and GGBFS as well as ternary binders were considered. Compressive strength, splitting tensile strength, flexural strength, and elastic modulus of concrete were measured until 28 days. Three additional concrete mixes with ternary binders were also cast to investigate the early-age autogenous shrinkage development until 28 days. In addition, prediction models in existing standards were used and compared to experimental results. The comparison results showed that the prediction models overestimated the compressive strength but underestimated the splitting tensile strength development and autogenous shrinkage. As a result, a model capturing the effect of fly ash and GGBFS on the development of compressive and splitting tensile strength is proposed to improve the prediction accuracy for current standards and empirical models.