Surface activity, mechanisms, kinetics, and thermodynamic study of adsorption of malachite green dye onto sulfuric acid-functionalized Moringa oleifera leaves from aqueous solution.

In the present study, activated carbon prepared from H2SO4-functionalized Moringa oleifera leaves (ACMOL) was used as a potential adsorbent for the effective removal of malachite green (MG) dye from aqueous media. FT-IR, SEM, EDS, Zeta potential, XRD, BET, proximate, and CHNS analysis techniques were used for surface characterization of the ACMOL. The adsorption efficiency of the ACMOL was investigated as a function of varying adsorbent dosage (0.02-0.2 g/100 mL), pH (3.0-9.0), ionic strength (0.1-0.5 M KCl), urea concentration (0.1-0.5 M), contact time (30-210 min), and temperature (303-323 K). The representative adsorption isotherms belong to the typical L-type. Maximum percentage removal was found to be 84% (124.40 mg/g) for MG dye concentration (30 mg/L) at pH 7.0 and 303 K with ACMOL dose 0.02 g/100 mL. The adsorption kinetics and equilibrium experimental data of MG dye adsorption on the ACMOL were well explained by the pseudo-second-order kinetics (R2 = 0.99) and Langmuir isotherm model (R2 = 0.99), respectively. The value of adsorption and desorption coefficient was found to be 0.036 min-1 and 0.025 mg min-1/L, respectively. Thermodynamic study showed the spontaneous (ΔG° = - 31.33, - 31.92, and - 32.49 kJ/mol at temperatures 303 K, 313 K, and 323 K, respectively) and exothermic (ΔH° = - 13.7 kJ/mol) nature of the adsorption with some structural changes occurring on the ACMOL surface (ΔS° = 58.198 J/K·mol).

An Insight into the Effect of Schiff Base and their d and f Block Metal Complexes on Various Cancer Cell Lines as Anticancer Agents: A Review.

Over the last few decades, an alarming rise in the percentage of individuals with cancer and those with multi-resistant illnesses has forced researchers to explore possibilities for novel therapeutic approaches. Numerous medications currently exist to treat various disorders, and the development of small molecules as anticancer agents has considerable potential. However, the widespread prevalence of resistance to multiple drugs in cancer indicates that it is necessary to discover novel and promising compounds with ideal characteristics that could overcome the multidrug resistance issue. The utilisation of metallo-drugs has served as a productive anticancer chemotherapeutic method, and this approach may be implemented for combating multi-resistant tumours more successfully. Schiff bases have been receiving a lot of attention as a group of compounds due to their adaptable metal chelating abilities, innate biologic properties, and versatility to tweak the structure to optimise it for a specific biological purpose. The biological relevance of Schiff base and related complexes, notably their anticancer effects, has increased in their popularity as bio-inorganic chemistry has progressed. As a result of learning about Schiff bases antitumor efficacy against multiple cancer cell lines and their complexes, researchers are motivated to develop novel, side-effect-free anticancer treatments. According to study reports from the past ten years, we are still seeking a powerful anticancer contender. This study highlights the potential of Schiff bases, a broad class of chemical molecules, as potent anticancer agents. In combination with other anticancer strategies, they enhance the efficacy of treatment by elevating the cytotoxicity of chemotherapy, surmounting drug resistance, and promoting targeted therapy. Schiff bases also cause cancer cell DNA repair, improve immunotherapy, prevent angiogenesis, cause apoptosis, and lessen the side effects of chemotherapy. The present review explores the development of potential Schiff base and their d and f block metal complexes as anticancer agents against various cancer cell lines.

Potential of powdered activated mustard cake for decolorising raw sugar.

BACKGROUND: Carbon decolorisation has become customary in the food processing industries; however, it is not economical. Extensive research has therefore been directed towards investigating potential substitutes for commercial activated carbons which might have the advantage of offering an effective, lower-cost replacement for existing bone char or coal-based granular activated carbon (GAC). RESULTS: The physical (bulk density and hardness), chemical (pH and mineral content) and adsorption characteristics (iodine test, molasses test and raw sugar decolorisation efficiency) of powdered activated mustard cake (PAMC) made from de-oiled mustard cake were determined and compared to commercial adsorbents. Although the colour removal efficiency of the PAMC is lower than that of commercial materials, it is cost effective and eco-friendly compared to the existing decolorisation/refining processes. To reduce the load on GAC/activated carbon/charcoal, PAMC could be used on an industrial scale. A decolorisation mechanism has been postulated on the basis of oxygen surface functionalities and surface charge of the PAMC and, accordingly, charge transfer interaction seems to be responsible for the decolorisation mechanism. In addition, a complex interplay of electrostatics and dispersive interaction seem to be involved during the decolorisation process. CONCLUSION: A low-cost agricultural waste product in the form of de-oiled mustard cake was converted to an efficient adsorbent, PAMC, for use in decolorising raw as well as coloured sugar solutions. The physical, chemical, adsorption characteristics and raw sugar decolorisation efficiency of PAMC were determined and compared to those of commercial adsorbents. The colour removal efficiency of the PAMC is lower than that of commercial materials but it is cost effective and eco-friendly as compared to existing decolorisation/refining processes. The availability of the raw material for the production of PAMC further demands its use on an industrial scale.

Surface activity, kinetics, thermodynamics and comparative study of adsorption of selected cationic and anionic dyes onto H3PO4-functionalized bagasse from aqueous stream.

The discharge of dyes into the water body creates toxicity to aquatic organisms because of their aromatic structure and difficult degradation. So, the treatment of dye-contaminated wastewater is required before releasing it. In the present study, thermally treated (600 °C) and H3PO4 (55%)-functionalized bagasse, henceforth called thermochemically activated bagasse (TCAB), was synthesized as potential adsorbent for the effective removal of selected cationic and anionic dyes from their aqueous stream. TCAB characterization was done employing FT-IR, SEM, XRD, zeta potential, BET, and PZC techniques. The comparative study shows that the relative adsorption on TCAB followed the sequence, methyl red (185 mg/g) > safranin (178 mg/g) > congo red (146 mg/g) > brilliant green (139 mg/g) > malachite green (130 mg/g) > bromocresol green (94 mg/g). The adsorption efficiency was investigated concerning the effect of change in TCAB dose (0.05-0.3 g/100 mL), initial dye concentration (20-200 mg/L), pH (4.0-10.0), ionic strength (0.1-0.5 M KCl), urea concentration (0.1-0.5 M) and temperature (25-45 °C). The representative adsorption isotherms belong to typical L-type. The time-dependent dye removal was best explained by the pseudo-second-order (PSO) kinetic model (R2 = 0.9859-0.9991), while equilibrium data were best explained by the Freundlich model (R2 = 0.9881-0.9961). Thermodynamic study showed the spontaneous (ΔG0 <0) and exothermic nature (ΔH0 <0) of the adsorption of different cationic and anionic dyes. The cyclic adsorption ability of TCAB for different dyes was checked up to three cycles (185 to 168 mg/L for MR, 178 to 165 mg/L for SF, 146 to 130 mg/L for CR, 139 to 127 mg/L for BG, 130 to 114 mg/L for MG and 94 to 80 mg/L for BCG), and no significant decrease in the adsorption capacity was noticed. So, the present study provides valuable insights into the adsorption of cationic and anionic dyes onto H3PO4-functionalized bagasse. Addressing the adsorptive aspects enhances the clarity, reliability and applicability of the study's findings and contributes to its overall scientific impact.

Characterization of persistent organic pollutants and culturable and non-culturable bacterial communities in pulp and paper sludge after secondary treatment.

Due to the presence of various organic contaminants, improper disposal of pulp-paper wastewater poses harm to the environment and human health. In this work, pulp-paper sludge (PPS) after secondary treatment were collected from M/s Century Pulp-paper Mills in India, the chemical nature of the organic pollutants was determined after solvent extraction. All the isolates were able to produce lipase (6.34-3.93 U ml-1) which could account for the different fatty acids detected in the PPS. The dominant strains were in the classes of α and γ Proteobacteria followed by Firmicutes. The Shannon-Weiner diversity indexes for phylotype richness for the culturable and non-culturable bacterial community were 2.01 and 3.01, respectively, indicating the non-culturable bacterial strains has higher species richness and diversity compared to the culturable bacterial strains. However, the culturable strains had higher species evenness (0.94 vs 0.90). Results suggested only a few isolated strains were resistant to the POPs in the PPS, where as non-cultural bacteria survived by entering viable but non-cultural state. The isolated strains (Brevundimonas diminuta, Aeromonas punctata, Enterobacter hormaechei, Citrobacter braakii, Bacillus pumilus and Brevundimonas terrae) are known for their multidrug resistance but their tolerance to POPs have not previously been reported and deserved further investigation. The findings of this research established the presence of POPs which influence the microbial population. Tertiary treatment is recommended prior to the safe disposal of pulp paper mill waste into the environment.

Kinetics of complex formation of Fe(III) with caffeic acid: Experimental and theoretical study.

Kinetic study on the complexation of caffeic acid with ferric chloride was performed in aqueous solution at pH 9.0. The complex was characterized by IR, UV-Vis spectroscopy and FE-SEM techniques. Kinetic data were obtained and used to model the reaction kinetics for the disappearance of the caffeic acid. The operational variables have been studied in the temperature range from 25 to 45 °C, initial iron and caffeic acid concentration from 0.6 mg/100 ml (ranging from 2.0 ml to 8 ml/100 ml). The complexation reaction was found to be a first-order with rate constants for k1 (formation) 4.7 × 10-3 s-1. Additionally, the effect of concentration and temperature on the complexation reaction was investigated. Apparent kinetic parameters of the complex formation of Fe(III) with caffeic acid were found as; pre-exponential factor A (-1.17 min-1), enthalpy of activation (ΔH°)# (-2188 J mol-1), entropy of activation, (ΔS°)# (-7.34 J mol-1 K-1) and Gibbs free energy of activation, (ΔG°)#(-0.68 J). The apparent activation energy of the complexation reaction was evaluated to be 289.29 J mol-1 which is consistent with the chemistry of Fe(III) with polyphenols which are supposed to mimic the interaction of Fe(III) with transferrin in biological media. Various theoretical parameters of the studied complex such as hardness, electronegativity, softness, total energy, dipole moment and point group symmetry were calculated employing Density functional theory (DFT) and found as 0.04465, 0.2130, 22.39, 0.5201 × 10-8 eV, 15.13 Debye, and C1, respectively.

The effect of high intensity ultrasound (HIU) on the kinetics of crystallization of sucrose: Elimination of latent period.

The application of a technique to eliminate the latent period during crystallization of sucrose by high intensity ultrasound (HIU) was investigated in this paper. Employing HIU (20 kHz, 750 W) to crystallization of sucrose, latent period was eliminated and it was found to obey first order kinetics (K ∼10-5s-1) in the temperature range of 30-50 °C. Employing Arrhenius equation, the average energy of activation (Ea) estimated as 5.0 kcal mol-1. Traditional knowledge indicates that crystallization is sufficiently spontaneous; however, the magnitude of "K" and other thermodynamic quantities of the process indicate that crystallization is actually a slow process. Generally, chemical reactions which posses low rate constants, need the high energy of activation. On the contrary, the energy of activation is appreciably less. The energy of activation with a rate constant of the order of 10-5s-1 could be predicted of the order of 20 kcal mol-1 at 27 °C. The low energy of activation for crystallization of sucrose is of interest. A very interesting elucidation can be had from neutron diffraction data and transport property of the sucrose which is discussed in details in this paper.

Kinetics of complex formation of Fe(III) with syringic acid: Experimental and theoretical study.

Kinetic study on the complexation of syringic acid with Fe(III) was described in aqueous solution at pH 9.0 together with a reappraisal of spectral evidence for chelate formation. The complexation reaction was found to be a first-order with rate constants for k1 (formation) 3.67 × 10-2 min-1. Additionally, the effect of concentration and temperature on the complexation reaction was investigated. The gustatory properties of the isolated complex were investigated and complex showed no metallic taste. The isolated complex was stable at pH 9.0. The apparent activation energy of the complexation reaction was evaluated to be 168 kcal/mol. The total iron content was determined in the isolated complex by AAS technique and was found 0.0073/100 ml. The specific rotation of the complex was found at -85°.

A ternary Fe(ii)-terpyridyl complex-based single platform for reversible multiple-ion recognition.

Multiple ion-recognition activity by a ternary Fe(ii)-terpyridyl complex, [Fe(PhT)(PT)]2+ (1) (PhT = 4'-phenyl-2,2':6',2''-terpyridine; PT = 4'-pyridyl-2,2':6',2''-terpyridine), is demonstrated for cyanide (CN-), fluoride (F-) and hydroxide (OH-) ions in an aqueous medium with sufficient sensitivity, fast response, reproducibility and selectivity with a dual optical read-out. The sensing event was reversible with the "by-eye" visualization of back and forth colour changes. Three cyanide ions replaced PT from 1, as observed from the crystal structure of the 1 + CN- couple. Fluoride and hydroxide ions appeared to show multivariate interactions with 1. Observed structural and spectral changes correlated well with theoretical calculations. A string of cations at quantitative levels (Ag+/Hg2+/Fe2+/Fe3+) was used to decouple the 1 + anion complex to yield 1, which enabled the recognition of these cations while permitting the reuse of 1 for at least five set-reset cycles.

Adsorption behavior of selected monosaccharides onto an alumina interface.

The adsorption of glucose and fructose from their aqueous solutions onto an alumina interface has been carried out spectrophotometrically at room temperature. The adsorption isotherms are characterized as typical L-type and an adsorption mechanism on the basis of dipolar interactions has been suggested. In addition to this, a partial role of metal-saccharide interactions as found in organometallic complexes (OMCs) for the observed adsorption cannot be ruled out. Various kinetic and thermodynamic parameters of the adsorption process have been evaluated. The effects of variation in experimental conditions of the system have also been investigated. The adsorption exhibited a typical response to the pH effect and maximum adsorption was found near the isoelectric point of alumina (pH 9.0). The anionic addition to the suspension affects the adsorbed amount and Cl(-), SO(4)(2-), and PO(4)(3-) affect the adsorption quantitatively. The addition of similar concentration of cations was found to reduce the adsorbed amount. The presence of cationic and anionic detergents was found to influence both the adsorbed amount and the adsorption rate. The temperature was found to have an inverse effect on adsorption. Adsorptive kinetic parameters have revealed that fructose tends to be a better adsorbate than glucose. This is found to be consistent with the chelation behaviour of monosaccharides as found in the OMC of monosaccharides. The thermodynamics of the adsorption model indicates its spontaneous and exothermic nature. The negative values of entropy are an indication of the probability of a favorable nature of adsorption.

Poly-vinyl alcohol (PVA) and malachite green: a new reagent system for the microdetermination of phosphate in water and wastewater.

A selective and sensitive method is described for the microdetermination of phosphate in water and wastewater employing a new reagent system. The method is based on the reaction between ammonium molybdate, PVA (stabilizer) and malachite green (lambdamax 600nm). Beer's law is obeyed up to 10ppm. The use of PVA as a substitute for Tween 20 makes more soluble the malachite green-phosphomolybdic acid complex; it becomes more sensitive and less of reagents are needed to obtain the same sensitivity as when Tween 20 is used as a stabilizer. It offers advantages like reliability, non-interference by silicates and reproducible in addition to its simplicity, instant colour development and allows economy in reagents such as ammonium molybdate and malachite green. It's cost is less than half of the Tween 20 method. This method is more suited for the measurements for the range of 0.01 to 10 mg p/L.