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1.
Sensors (Basel) ; 24(8)2024 Apr 22.
Artigo em Inglês | MEDLINE | ID: mdl-38676275

RESUMO

As graphene-related technology advances, the benefits of graphene metamaterials become more apparent. In this study, a surface-isolated exciton-based absorber is built by running relevant simulations on graphene, which can achieve more than 98% perfect absorption at multiple frequencies in the MWIR (MediumWavelength Infra-Red (MWIR) band as compared to the typical absorber. The absorber consists of three layers: the bottom layer is gold, the middle layer is dielectric, and the top layer is patterned with graphene. Tunability was achieved by electrically altering graphene's Fermi energy, hence the position of the absorption peak. The influence of graphene's relaxation time on the sensor is discussed. Due to the symmetry of its structure, different angles of light source incidence have little effect on the absorption rate, leading to polarization insensitivity, especially for TE waves, and this absorber has polarization insensitivity at ultra-wide-angle degrees. The sensor is characterized by its tunability, polarisation insensitivity, and high sensitivity, with a sensitivity of up to 21.60 THz/refractive index unit (RIU). This paper demonstrates the feasibility of the multi-frequency sensor and provides a theoretical basis for the realization of the multi-frequency sensor. This makes it possible to apply it to high-sensitivity sensors.

2.
Molecules ; 29(18)2024 Sep 23.
Artigo em Inglês | MEDLINE | ID: mdl-39339508

RESUMO

In recent years, solar energy has become popular because of its clean and renewable properties. Meanwhile, two-dimensional materials have become a new favorite in scientific research due to their unique physicochemical properties. Among them, monolayer molybdenum disulfide (MoS2), as an outstanding representative of transition metal sulfides, is a hot research topic after graphene. Therefore, we have conducted an in-depth theoretical study and design simulation using the finite-difference method in time domain (FDTD) for a solar absorber based on the two-dimensional material MoS2. In this paper, a broadband solar absorber and thermal emitter based on a single layer of molybdenum disulfide is designed. It is shown that the broadband absorption of the absorber is mainly due to the propagating plasma resonance on the metal surface of the patterned layer and the localized surface plasma resonance excited in the adjacent patterned air cavity. The research results show that the designed structure boasts an exceptional broadband performance, achieving an ultra-wide spectral range spanning 2040 nm, with an overall absorption efficiency exceeding 90%. Notably, it maintains an average absorption rate of 94.61% across its spectrum, and in a narrow bandwidth centered at 303 nm, it demonstrates a near-unity absorption rate, surpassing 99%, underscoring its remarkable absorptive capabilities. The weighted average absorption rate of the whole wavelength range (280 nm-2500 nm) at AM1.5 is above 95.03%, and even at the extreme temperature of up to 1500 K, its heat radiation efficiency is high. Furthermore, the solar absorber in question exhibits polarization insensitivity, ensuring its performance is not influenced by the orientation of incident light. These advantages can enable our absorber to be widely used in solar thermal photovoltaics and other fields and provide new ideas for broadband absorbers based on two-dimensional materials.

3.
Sensors (Basel) ; 23(17)2023 Aug 31.
Artigo em Inglês | MEDLINE | ID: mdl-37688037

RESUMO

Here, we document a D-type double open-loop channel floor plasmon resonance (SPR) photonic crystal fiber (PCF) for temperature sensing. The grooves are designed on the polished surfaces of the pinnacle and backside of the PCF and covered with a gold (Au) film, and stomata are distributed around the PCF core in a progressive, periodic arrangement. Two air holes between the Au membrane and the PCF core are designed to shape a leakage window, which no longer solely averts the outward diffusion of Y-polarized (Y-POL) core mode energy, but also sets off its coupling with the Au movie from the leakage window. This SPR-PCF sensor uses the temperature-sensitive property of Polydimethylsiloxane (PDMS) to reap the motive of temperature sensing. Our lookup effects point out that these SPR-PCF sensors have a temperature sensitivity of up to 3757 pm/°C when the temperature varies from 5 °C to 45 °C. In addition, the maximum refractive index sensitivity (RIS) of the SPR-PCF sensor is as excessive as 4847 nm/RIU. These proposed SPR-PCF temperature sensors have an easy nanostructure and proper sensing performance, which now not solely improve the overall sensing performance of small-diameter fiber optic temperature sensors, but also have vast application prospects in geo-logical exploration, biological monitoring, and meteorological prediction due to their remarkable RIS and exclusive nanostructure.

4.
Sensors (Basel) ; 22(17)2022 Aug 28.
Artigo em Inglês | MEDLINE | ID: mdl-36080942

RESUMO

The paper proposes an ultra-narrow band graphene refractive index sensor, consisting of a patterned graphene layer on the top, a dielectric layer of SiO2 in the middle, and a bottom Au layer. The absorption sensor achieves the absorption efficiency of 99.41% and 99.22% at 5.664 THz and 8.062 THz, with the absorption bandwidths 0.0171 THz and 0.0152 THz, respectively. Compared with noble metal absorbers, our graphene absorber can achieve tunability by adjusting the Fermi level and relaxation time of the graphene layer with the geometry of the absorber unchanged, which greatly saves the manufacturing cost. The results show that the sensor has the properties of polarization-independence and large-angle insensitivity due to the symmetric structure. In addition, the practical application of testing the content of hemoglobin biomolecules was conducted, the frequency of first resonance mode shows a shift of 0.017 THz, and the second resonance mode has a shift of 0.016 THz, demonstrating the good frequency sensitivity of our sensor. The S (sensitivities) of the sensor were calculated at 875 GHz/RIU and 775 GHz/RIU, and quality factors FOM (Figure of Merit) are 26.51 and 18.90, respectively; and the minimum limit of detection is 0.04. By comparing with previous similar sensors, our sensor has better sensing performance, which can be applied to photon detection in the terahertz band, biochemical sensing, and other fields.


Assuntos
Grafite , Refratometria , Metais , Refração Ocular , Dióxido de Silício
5.
Phys Chem Chem Phys ; 21(27): 14692-14700, 2019 Jul 10.
Artigo em Inglês | MEDLINE | ID: mdl-31215943

RESUMO

We have performed state-of-the-art ab initio calculations based on density functional theory to study the effect of Ti on helium dissolution and migration in a dilute Ti-doped ZrCo system. The formation energy of He-related defects predicts that it is preferable to occupy the VZr (Zr vacancy) at first. As for the Heint (interstitial site He), the results corroborate that Hetet (tetrahedral site He) is more stable than Heoct (octahedral site He) by 0.25 eV. The Heoct in the vicinity of Ti atoms becomes unstable, being relaxed into a nearby tetrahedral site, unlike in the pure ZrCo. We also reveal that ZrCo is susceptible to dopant Ti in terms of helium diffusion. The energy barrier for a Hetet to diffuse into a neighboring tetrahedral site is found to be about three times as large as the migration barrier between two adjacent octahedral interstitial sites (0.35 vs. 0.12 eV). In addition, the He atom can migrate from one octahedral site to another without going through a tetrahedral one in pure ZrCo. Furthermore, Hetet needs to overcome higher energy barriers of 0.27 eV and 0.58 eV in Ti-doped ZrCo than in the pure one (0.22 eV and 0.35 eV) along the 1nn (the first nearest neighbor) → 1nn → 2nn (the second nearest neighbor) pathway with the He atom escaping away from the Ti region. In addition, the dissociative energy barrier of the HeZr (Zr position substituted by the He atom) or HeCo (Co position substituted by the He atom) is somewhat higher in the presence of Ti than the pure one. All these conclusions elucidate that Ti acts as a trapping center for He impurities and blocks interstitial He mobility in ZrCo alloys.

6.
Phys Chem Chem Phys ; 21(37): 20909-20918, 2019 Oct 07.
Artigo em Inglês | MEDLINE | ID: mdl-31517356

RESUMO

The interactions of dopants with point defects such as that between vacancies and helium can affect helium evolution and ultimately the macroscopic properties of materials. Herein, the microscopic vacancy trapping mechanism for He defects and the formation of small HemVacn (consisting of m He atoms and n vacancies) clusters in pure and Ti-doped ZrCo systems are investigated by carrying out an extensive set of first-principles calculations based on density functional theory. Our results uncover the following: the helium atom can segregate from the adjacent interstitial (tetrahedral and octahedral) sites towards the vacancy center spontaneously, and therefore, a single He atom is energetically favorable to occupy a vacancy whether in the pure or in the doped system. The dopant Ti can act as a trapping center for He impurities similar to a vacancy. Moreover, it can improve the trapping ability and increase the trapping radius of the vacancies for helium. As for the effect of the Ti atom on the trapping of multiple helium atoms by the vacancy, the higher barrier in the doped systems than in the pure one implies that doping inhibits the formation of large HemVac clusters. Furthermore, in order to evaluate the effect of dopant Ti on the stability of He atoms in multiple vacancies, the binding energies of a helium atom, a vacancy (Vac), and a self-interstitial atom (SIA) to a helium-vacancy cluster (HemVacn) were obtained and compared with that of the pure system. The results suggest that the cluster growth can be inhibited by the dopant Ti, and therefore, the formation of large helium bubbles is also hindered. All the binding energies do not depend much on the cluster size but primarily on the helium-to-vacancy ratio (m/n) of the clusters. The stability of the clusters is decided by the competitive processes among the emission of He atoms, vacancies, and SIAs, and also depends on the helium-to-vacancy ratio. The present results provide an in-depth explanation for the effect of the dopant on helium behavior and could aid future tritium storage material design.

7.
Sensors (Basel) ; 18(12)2018 Dec 18.
Artigo em Inglês | MEDLINE | ID: mdl-30567404

RESUMO

In the present study, we design a tunable plasmonic refractive index sensor with nanoring-strip graphene arrays. The calculations prove that the nanoring-strip have two transmission dips. By changing the strip length L of the present structure, we find that the nanoring-strip graphene arrays have a wide range of resonances (resonance wavelength increases from 17.73 µm to 28.15 µm). When changing the sensing medium refractive index nmed, the sensitivity of mode A and B can reach 2.97 µm/RIU and 5.20 µm/RIU. By changing the doping level ng, we notice that the transmission characteristics can be tuned flexibly. Finally, the proposed sensor also shows good angle tolerance for both transverse magnetic (TM) and transverse electric (TE) polarizations. The proposed nanoring-strip graphene arrays along with the numerical results could open a new avenue to realize various tunable plasmon devices and have a great application prospect in biosensing, detection, and imaging.

8.
Phys Chem Chem Phys ; 17(4): 2641-50, 2015 Jan 28.
Artigo em Inglês | MEDLINE | ID: mdl-25500621

RESUMO

In this paper a simulation of the properties of surface plasmons on gold nanoplatelets with various cross-sections inscribed in a circle and an investigation of their field distributions to assign multiple SPRs are described. The manipulated propagation can be obtained through the evolution of edges and corners. Furthermore, the particle morphology and the associated spectral positions alone do not uniquely reflect the important details of the local field distribution or the resonance modes. The plasmon modes were investigated and found to be mainly excited along the edges and in the side and sloped side surfaces. The strong field distributions can generally be found around the corners and how the plasmons transmit through the corners to adjacent edges was also investigated. Besides the plasmons excited along the edges as were found for the triangular nanoplatelets, plasmons were excited in the interior region of the triangular surfaces and were also investigated. Despite this in the infrared region, plasmon modes were found to be along the edges for the hexagonal nanoplatelets. Also, it can be seen that the change of nanoplatelet thickness can support different plasmon modes ranging from dipolar resonance mode to quadrupole resonance mode. The thickness far below the skin depth can display complex plasmon modes along the edges and on the side and sloping side surfaces as well as the strong coupling between the top and bottom surfaces. The observed plasmon resonance modes in this simulation reflect the interference of all these contributions including the plasmons along the edges and on the side surfaces. This is an essential step towards a thorough understanding of plasmon modes and the effect of edge and corner evolution in polygonous nanoplatelets.

9.
Materials (Basel) ; 17(17)2024 Aug 29.
Artigo em Inglês | MEDLINE | ID: mdl-39274677

RESUMO

In recent years, absorbers related to metamaterials have been heavily investigated. In particular, VO2 materials have received focused attention, and a large number of researchers have aimed at multilayer structures. This paper presents a new concept of a three-layer simple structure with VO2 as the base, silicon dioxide as the dielectric layer, and graphene as the top layer. When VO2 is in the insulated state, the absorber is in the closed state, Δf = 1.18 THz (absorption greater than 0.9); when VO2 is in the metallic state, the absorber is open, Δf = 4.4 THz (absorption greater than 0.9), with ultra-broadband absorption. As a result of the absorption mode conversion, a phenomenon occurs with this absorber, with total transmission and total reflection occurring at 2.4 THz (A = 99.45% or 0.29%) and 6.5 THz (A = 90% or 0.24%) for different modes. Due to this absorption property, the absorber is able to achieve full-transmission and full-absorption transitions at specific frequencies. The device has great potential for applications in terahertz absorption, terahertz switching, and terahertz modulation.

10.
Dalton Trans ; 53(25): 10618-10625, 2024 Jun 25.
Artigo em Inglês | MEDLINE | ID: mdl-38857028

RESUMO

Utilizing the phase transition principle of VO2, this paper presents a tunable ultra-wideband terahertz perfect absorption device with simple structure and tunability. The proposed broadband terahertz perfect absorption device is a three-layer structure with a metal reflective layer, a silicon dioxide dielectric layer and a VO2 layer from bottom to top. It was found that the terahertz perfect absorption device's absorption could be dynamically adjusted from 1.2% to 99.9% when changing from an insulated to a metallic state. With the VO2 in the metallic state, the terahertz perfect absorption device has an absorption efficiency of more than 90% in 4.00 to 10.08 THz's ultra-broadband range and near-perfect absorption is achieved in the ranges of 4.71 THz to 5.16 THz and 7.74 THz to 8.06 THz. To explain the working principle of this terahertz perfect absorption device, this paper utilizes wave interference's principle, theory of impedance matching and electric field analysis. Compared to previously reported terahertz metamaterial devices, the vanadium dioxide device proposed in this paper is significantly optimized in terms of tunable range and absorption bandwidth. In addition, the terahertz perfect absorption device is polarization insensitive and maintains good absorptivity over a wide-angle incidence range. This tunable ultra-wideband terahertz perfect absorption device could have applications in the fields of modulation, stealth devices, and thermal emission devices.

11.
Micromachines (Basel) ; 14(5)2023 Apr 27.
Artigo em Inglês | MEDLINE | ID: mdl-37241576

RESUMO

This paper introduces a novel metamaterial absorber based on surface plasmon resonance (SPR). The absorber is capable of triple-mode perfect absorption, polarization independence, incident angle insensitivity, tunability, high sensitivity, and a high figure of merit (FOM). The structure of the absorber consists of a sandwiched stack: a top layer of single-layer graphene array with an open-ended prohibited sign type (OPST) pattern, a middle layer of thicker SiO2, and a bottom layer of the gold metal mirror (Au). The simulation of COMSOL software suggests it achieves perfect absorption at frequencies of fI = 4.04 THz, fII = 6.76 THz, and fIII = 9.40 THz, with absorption peaks of 99.404%, 99.353%, and 99.146%, respectively. These three resonant frequencies and corresponding absorption rates can be regulated by controlling the patterned graphene's geometric parameters or just adjusting the Fermi level (EF). Additionally, when the incident angle changes between 0~50°, the absorption peaks still reach 99% regardless of the kind of polarization. Finally, to test its refractive index sensing performance, this paper calculates the results of the structure under different environments which demonstrate maximum sensitivities in three modes: SI = 0.875 THz/RIU, SII = 1.250 THz/RIU, and SIII = 2.000 THz/RIU. The FOM can reach FOMI = 3.74 RIU-1, FOMII = 6.08 RIU-1, and FOMIII = 9.58 RIU-1. In conclusion, we provide a new approach for designing a tunable multi-band SPR metamaterial absorber with potential applications in photodetectors, active optoelectronic devices, and chemical sensors.

12.
Micromachines (Basel) ; 14(5)2023 Apr 30.
Artigo em Inglês | MEDLINE | ID: mdl-37241609

RESUMO

Solar energy is currently a very popular energy source because it is both clean and renewable. As a result, one of the main areas of research now is the investigation of solar absorbers with broad spectrum and high absorption efficiency. In this study, we create an absorber by superimposing three periodic Ti-Al2O3-Ti discs on a W-Ti-Al2O3 composite film structure. We evaluated the incident angle, structural components, and electromagnetic field distribution using the finite difference in time domain (FDTD) method in order to investigate the physical process by which the model achieves broadband absorption. We find that distinct wavelengths of tuned or resonant absorption may be produced by the Ti disk array and Al2O3 through near-field coupling, cavity-mode coupling, and plasmon resonance, all of which can effectively widen the absorption bandwidth. The findings indicate that the solar absorber's average absorption efficiency can range from 95.8% to 96% over the entire band range of 200 to 3100 nm, with the absorption bandwidth of 2811 nm (244-3055 nm) having the highest absorption rate. Additionally, the absorber only contains tungsten (W), titanium (Ti), and alumina (Al2O3), three materials with high melting points, which offers a strong assurance for the absorber's thermal stability. It also has a very high thermal radiation intensity, reaching a high radiation efficiency of 94.4% at 1000 K, and a weighted average absorption efficiency of 98.3% at AM1.5. Additionally, the incidence angle insensitivity of our suggested solar absorber is good (0-60°) and polarization independence is good (0-90°). These benefits enable a wide range of solar thermal photovoltaic applications for our absorber and offer numerous design options for the ideal absorber.

13.
Micromachines (Basel) ; 14(6)2023 Jun 11.
Artigo em Inglês | MEDLINE | ID: mdl-37374817

RESUMO

More and more researchers are studying the heat transfer performance of aeronautical materials at high temperatures. In this paper, we use a quartz lamp to irradiate fused quartz ceramic materials, and the sample surface temperature and heat flux distribution were obtained at a heating power of 45~150 kW. Furthermore, the heat transfer properties of the material were analyzed using a finite element method and the effect of surface heat flow on the internal temperature field was investigated. The results show that the fiber skeleton structure has a significant effect on the thermal insulation performance of fiber-reinforced fused quartz ceramics and the longitudinal heat transfer along the rod fiber skeleton is slower. As time passes, the surface temperature distribution tends to stability and reaches an equilibrium state. The surface temperature of fused quartz ceramic increases with the increase in the radiant heat flux of the quartz lamp array. When the input power is 5 kW, the maximum surface temperature of the sample can reach 1153 °C. However, the non-uniformity of the sample surface temperature also increases, reaching a maximum uncertainty of 12.28%. The research in this paper provides important theoretical guidance for the heat insulation design of ultra-high acoustic velocity aircraft.

14.
Micromachines (Basel) ; 14(9)2023 Sep 21.
Artigo em Inglês | MEDLINE | ID: mdl-37763965

RESUMO

This paper presents a new theoretical proposal for a surface plasmon resonance (SPR) terahertz metamaterial absorber with five narrow absorption peaks. The overall structure comprises a sandwich stack consisting of a gold bottom layer, a silica medium, and a single-layer patterned graphene array on top. COMSOL simulation represents that the five absorption peaks under TE polarization are at fI = 1.99 THz (95.82%), fⅡ = 6.00 THz (98.47%), fⅢ = 7.37 THz (98.72%), fⅣ = 8.47 THz (99.87%), and fV = 9.38 THz (97.20%), respectively, which is almost consistent with the absorption performance under TM polarization. In contrast to noble metal absorbers, its absorption rates and resonance frequencies can be dynamically regulated by controlling the Fermi level and relaxation time of graphene. In addition, the device can maintain high absorptivity at 0~50° in TE polarization and 0~40° in TM polarization. The maximum refractive index sensitivity can reach SV = 1.75 THz/RIU, and the maximum figure of merit (FOM) can reach FOMV = 12.774 RIU-1. In conclusion, our design has the properties of dynamic tunability, polarization independence, wide-incident-angle absorption, and fine refractive index sensitivity. We believe that the device has potential applications in photodetectors, active optoelectronic devices, sensors, and other related fields.

15.
Micromachines (Basel) ; 14(8)2023 Aug 14.
Artigo em Inglês | MEDLINE | ID: mdl-37630133

RESUMO

Since the use of chemical fuels is permanently damaging the environment, the need for new energy sources is urgent for mankind. Given that solar energy is a clean and sustainable energy source, this study investigates and proposes a six-layer composite ultra-wideband high-efficiency solar absorber with an annular microstructure. It achieves this by using a combination of the properties of metamaterials and the quantum confinement effects of semiconductor materials. The substrate is W-Ti-Al2O3, and the microstructure is an annular InAs-square InAs film-Ti film combination. We used Lumerical Solutions' FDTD solution program to simulate the absorber and calculate the model's absorption, field distribution, and thermal radiation efficiency (when it is used as a thermal emitter), and further explored the physical mechanism of the model's ultra-broadband absorption. Our model has an average absorption of 95.80% in the 283-3615 nm band, 95.66% in the 280-4000 nm band, and a weighted average absorption efficiency of 95.78% under AM1.5 illumination. Meanwhile, the reflectance of the model in the 5586-20,000 nm band is all higher than 80%, with an average reflectance of 94.52%, which has a good thermal infrared suppression performance. It is 95.42% under thermal radiation at 1000 K. It has outstanding performance when employed as a thermal emitter as well. Additionally, simulation results show that the absorber has good polarization and incidence angle insensitivity. The model may be applied to photodetection, thermophotovoltaics, bio-detection, imaging, thermal ion emission, and solar water evaporation for water purification.

16.
Guang Pu Xue Yu Guang Pu Fen Xi ; 32(2): 374-7, 2012 Feb.
Artigo em Zh | MEDLINE | ID: mdl-22512171

RESUMO

In the present paper, DFT method at the B3LYP/6-31+G* * (C, H, O)/LANL2DZ(Ag) level was used to optimize molecular configurations of furfural. Based on the optimized structure, the normal Raman spectrum (NRS) of FUR and the surface-enhanced Raman spectrum (SERS) of FUR adsorbed on Ag, Ag2 and Ag4 were all calculated, which were compared with the experimental values. The calculation results indicated that a good conformity was found between the computed and the experimental results. The results of furfural adsorbed on Ag4 were more approximate to the ever reported experimental date than those of furfural adsorbed on Ag and Ag2. At the end, detailed analysis of the Raman spectrum and more comprehensive assignments of the vibration mode for furfural were studied by the software of GaussView. The data of the SERS by comparing with the one of NRS show that furfural molecule and Ag atoms interact with each other. And we suppose that the molecular plane with the ring of adsorbed furfural molecule is vertically orientated to the silver surface. The work in this paper offers a theory evidence for detection and trace analysis of drinks containing furfural.

17.
Guang Pu Xue Yu Guang Pu Fen Xi ; 31(11): 2952-5, 2011 Nov.
Artigo em Zh | MEDLINE | ID: mdl-22242493

RESUMO

In the present paper, DFT method at the B3LYP/6-31++G** (C, H, N, S)/LANL2DZ(Ag) level was used to optimize molecular configurations of p-aminothiophenol. Based on the optimized structure, the normal Raman scattering (NRS) spectrum of PATP and the surface-enhanced Raman scattering(SERS) spectrum of PATP adsorbed on Ag and Ag2 were both calculated, and were compared with the results of other literatures values. The calculation results indicated that a good conformity was found between the computed and experimental results. The results of PATP adsorbed on Ag2 were more approximate to the ever reported experimental data than those of PATP adsorbed on Ag. At the end, detailed analysis of the Raman spectrum and more comprehensive assignments of the vibration mode for p-aminothiophenol were studied by the software of GaussView. In comparison with SERS spectrum and NRS spectrum of PATP molecule, the authors observed the stretching vibration bands in the SERS spectrum at about 213 cm(-1), which is due to Ag-S stretching vibration mode. The work in this paper has greatly directive value in understanding and explaining some experiment phenomenon, and helps to study the mechanism of surface-enhanced Raman scattering of PATP.

18.
J Phys Condens Matter ; 33(9): 095501, 2021 Mar 03.
Artigo em Inglês | MEDLINE | ID: mdl-33207328

RESUMO

The remarkable thermoelectric performance is predicted for half-Heusler (HH) compounds of CuLiX (X = Se, Te) based on the first-principles calculation, the deformation potential (DP) theory, and semi-classical Boltzmann theory. The Slack model is employed to evaluate the lattice thermal conductivity and the result is in good agreement with the previously reported data. The results of mechanical properties demonstrate that CuLiSe is ductile but CuLiTe is brittle. The relaxation time and the carrier mobility are calculated with DP theory. The electrical and thermal conductivities are obtained by using the semi-classical Boltzmann theory based on the relaxation approximation. The Seebeck coefficient and power factor are obtained and their characters are analyzed. The dimensionless figure of merits (ZT) is obtained for the p- and n-type CuLiX. The maximum ZT of 2.65 can be achieved for n-type CuLiTe at the carrier concentration of 3.19 × 1019 cm-3 and 900 K, which indicates that this compound is a very promising candidate for the highly efficient thermoelectric materials.

19.
Nanomaterials (Basel) ; 10(2)2020 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-32024205

RESUMO

In order to significantly enhance the absorption capability of solar energy absorbers in the visible wavelength region, a novel monolayer molybdenum disulfide (MoS2)-based nanostructure was proposed. Local surface plasmon resonances (LSPRs) supported by Au nanocubes (NCs) can improve the absorption of monolayer MoS2. A theoretical simulation by a finite-difference time-domain method (FDTD) shows that the absorptions of proposed MoS2-based absorbers are above 94.0% and 99.7% at the resonant wavelengths of 422 and 545 nm, respectively. In addition, the optical properties of the proposed nanostructure can be tuned by the geometric parameters of the periodic Au nanocubes array, distributed Bragg mirror (DBR) and polarization angle of the incident light, which are of great pragmatic significance for improving the absorption efficiency and selectivity of monolayer MoS2. The absorber is also able to withstand a wide range of incident angles, showing polarization-independence. Similar design ideas can also be implemented to other transition-metal dichalcogenides (TMDCs) to strengthen the interaction between light and MoS2. This nanostructure is relatively simple to implement and has a potentially important application value in the development of high-efficiency solar energy absorbers and other optoelectronic devices.

20.
Nanomaterials (Basel) ; 10(2)2020 Jan 24.
Artigo em Inglês | MEDLINE | ID: mdl-31991689

RESUMO

In this article, we present a design for a triple-band tunable metamaterial absorber with an Au nano-cuboids array, and undertake numerical research about its optical properties and local electromagnetic field enhancement. The proposed structure is investigated by the finite-difference time domain (FDTD) method, and we find that it has triple-band tunable perfect absorption peaks in the near infrared band (1000-2500 nm). We investigate some of structure parameters that influence the fields of surface plasmons (SP) resonances of the nano array structure. By adjusting the relevant structural parameters, we can accomplish the regulation of the surface plasmons resonance (SPR) peaks. In addition, the triple-band resonant wavelength of the absorber has good operational angle-polarization-tolerance. We believe that the excellent properties of our designed absorber have promising applications in plasma-enhanced photovoltaic, optical absorption switching and infrared modulator optical communication.

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