CuCo2O4 nanoneedle arrays growth on carbon cloth as a non-enzymatic electrochemical sensor with low detection limit ketoprofen recognition.

An electrochemical sensor for detecting ketoprofen was constructed by in-situ grown copper cobaltate (CuCo2O4) nanoneedle arrays on a carbon cloth (CC) substrate. The resulting porous nanoneedle arrays not only expose numerous electrochemically active sites but also significantly enhance the electrochemical apparent active area and current transmission efficiency. By leveraging its electrochemical properties, the sensor achieves an impressive detection limit for ketoprofen of 0.7 pM, with a linear range spanning from 2 pM ~ 2 µM. Furthermore, the sensor exhibits remarkable reproducibility, anti-interference capabilities, and stability. Notably, the developed sensor also performed ketoprofen detection on real samples (including drug formulations and wastewater) and demonstrated excellent recognition ability. These exceptional performances can be attributed to the direct growth of CuCo2O4 nanoneedle arrays on the CC substrate, which facilitates a robust electrical connection, provides abundant electrocatalytic active sites, and expands the apparent active area. Consequently, these improvements contribute to the efficient trace detection capabilities of the ketoprofen sensor.

Bulk Passivation Enables Hundredfold-Enhanced Electroluminescence of Monophosphine Cu4 I4 Cubes.

Electroluminescent (EL) clusters emerged rapidly, owing to their organic-inorganic hybrid character useful for comprehensive performance integration and the potential for large-scale display and lighting applications. However, despite their good photoluminescent (PL) properties, until present, no efficient EL monodentate ligand-based clusters were reported due to structural variation during processing and excitation and exciton confinement on cluster-centered quenching states. Here we demonstrate an effective bulky passivation strategy for efficient cluster light-emitting diodes with a monophosphine Cu4 I4 cube named [TMeOPP]4 Cu4 I4 . With terminal pyridine groups, an active matrix named TmPyPB supports an effective host-cluster interplay for configuration fixation, structural stabilization, and exciton-confinement optimization. Compared to common inactive hosts, the passivation effects of TmPyPB markedly reduce trap-state densities by 24-40 % to suppress nonradiative decay, resulting in state-of-the-art PL and EL quantum yields reaching 99 % and 15.6 %, respectively, which are significantly improved by about 7-fold. TmPyPB simultaneously increases EL luminance to 104 nits, which is ≈100-fold that of the non-doped analogue.

Bimetallic MOFs-derived coral-like Ag-Mo2C/C interwoven nanorods for amperometric detection of hydrogen peroxide.

Coral-like Ag-Mo2C/C-I and blocky Ag-Mo2C/C-II composites were obtained from one-step in situ calcination of [Ag(HL)3(Mo8O26)]n·nH2O [L: N-(pyridin-3-ylmethyl) pyridine-2-amine] under N2/H2 and N2 atmospheres, respectively. The coral-like morphology of Ag-Mo2C/C-I is composed of interwoven nanorods embedded with small particles, and the nano-aggregate of Ag-Mo2C/C-II is formed by cross-linkage of irregular nanoparticles. The above composites are decorated on glassy carbon electrode (GCE) drop by drop to generate two enzyme-free electrochemical sensors (Ag-Mo2C/C/GCE) for amperometric detection of H2O2. In particular, the coral-like Ag-Mo2C/C-I/GCE sensor possesses rapid response (1.2 s), high sensitivity (466.2 µA·mM-1·cm-2), and low detection limit (25 nM) towards trace H2O2 and has wide linear range (0.08 µM~4.67 mM) and good stability. All these sensing performances are superior to Ag-Mo2C/C-II/GCE, indicating that the calcining atmosphere has an important influence on microstructure and electrochemical properties. The excellent electrochemical H2O2 sensing performance of Ag-Mo2C/C-I/GCE sensor is mainly attributed to the synergism of unique microstructure, platinum-like electron structure of Mo2C, strong interaction between Mo and Ag, as well as the increased active sites and conductivity caused by co-doped Ag and carbon. Furthermore, this sensor has been successfully applied to the detection of H2O2 in human serum sample, contact lens solution, and commercial disinfector, demonstrating the potential in related fields of environment and biology. Graphical abstract.

Ionic liquid([C12mim][PF6])-assisted synthesis of TiO2 /Ti2O (PO4)2 nanosheets and the chemoresistive gas sensing of trimethylamine.

The architecture of PO43- modified 2D TiO2 nanosheets was constructed by ionic liquids (ILs)-assisted hydrothermal method. The nanosheet structure can be regulated by the addition of different amount of ionic liquid. Using the composite nanosheets  a chemoresistive gas sensor was prepared for trimethylamine (TMA) detection. Most reported TMA sensors need to be operated at a relatively high operating temperature, but in this paper, the as-synthesized PO43--modified 2D TiO2/Ti2O(PO4)2 nanosheet sensor has high response (S = 87.46), short response time (14.6 s), and good reproducibility to 100 ppm TMA gas, when the temperature is 170 °C. In contrast to the single-phase TiO2 sensor, the gas-sensing property of the composite one is obviously enhanced. Moreover, its response shows excellent linear relationship with TMA concentration from 0.2 to 500 ppm, and a detection limit of 0.2 ppm. The TMA detection mechanism was investigated by analyzing the changes of the surface adsorption oxygen content by XPS and gaseous products using gas chromatography after the sensor was in contact with TMA.

Synthesis of ZnO@poly-o-methoxyaniline nanosheet composite for enhanced NH3-sensing performance at room temperature.

Poly-o-methoxyaniline (POMA) and zinc oxide (ZnO) composites were prepared via in situ polymerization and characterized by thermogravimetry thermal analysis, X-ray diffraction analysis, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and N2 sorption measurement. The composites show different morphology when the ratio of POMA and ZnO varies. At a ratio of 2:2, the composite shows thinner nanosheet structure with smooth surface and exhibits best response to NH3 at room temperature. The ZnO@POMA nanosheet sensor shows good selectivity and a wide response range (linear ranges from 0.05-1 pmm and 10-100 ppm of NH3). The lowest detection limit reaches 0.05 ppm. The sensor exhibits good reversibility. Based on the testing results of ultraviolet diffuse reflection spectroscopy and Kelvin probe technique, the adsorption and desorption of NH3 molecules on the sensing material and the formation of p-n heterostructure between ZnO and POMA and their synergistic effects are further explained. More importantly, the sensor possessed excellent moisture resistance. The overall test results of ZnO@POMA show that the sensor has good practical applicability for detecting trace NH3 at room temperature. Graphical abstract.

One step synthesis of PANI/Fe2O3 nanocomposites and flexible film for enhanced NH3 sensing performance at room temperature.

Novel sea cucumber-shaped polyaniline/ferric oxide (PANI/Fe2O3) nanocomposites were synthesized using a simple and efficient one step hydrothermal process, and the nanocomposites were further assembled onto a polyethylene terephthalate (PET) flexible substrate. Through the monitoring of the resistance of the PANI/Fe2O3 nanocomposites thick films and PANI/Fe2O3-PET flexible sensors, the responses of the sensors to various 100 ppm gases including methanol, triethylamine, aniline and another five gases were obtained. It was found that two kinds of sensors exhibit a high selectivity towards NH3. The PANI/Fe2O3 nanocomposites-based sensor has a good response and a low detection limit (0.3 ppm) at room temperature (20 ± 5 °C). It also shows a good linearity relationship in a certain concentration of NH3. After assembling into the PANI/Fe2O3-PET flexible film sensor, the response of the sensor is significantly increased to 6.12 for 100 ppm NH3, the detection limit is as low as 0.5 ppm, and the sensor shows good stability and linearity, which is more conducive to the application of such a material in wearable gas sensors.

A hollow urchin-like α-MnO2 as an electrochemical sensor for hydrogen peroxide and dopamine with high selectivity and sensitivity.

A hollow urchin-like α-MnO2 material has been synthesized by a hydrothermal method starting from MnSO4·H2O and (NH4)2S2O8, and by using silver(I) as the catalyst. It has a hollow morphology with diameters of 5-6 µm and consists of densely aligned nanowires, with a 30-40 nm width and a 1.5 µm length. The diameter of the cavities and the thickness of the shell are about 1.2 µm and 300 nm, respectively. The material was placed on a glassy carbon electrode (GCE), and electrochemical experiments showed the respective sensor to possess good stability and reproducibility. The modified GCE displays response to both hydrogen peroxide (H2O2) and dopamine (DA) at working potentials of -0.40 V and +0.4 V, respectively (both versus SCE). H2O2 can be detected with an 80 nM detection limit, and DA with a 12 nM detection limit (at S/N = 3). Graphical abstract Schematic presentation of synthesis of a hollow urchin-like α-MnO2, which taking MnSO4.H2O and (NH4)2S2O8 as raw materials and was further used to construct an electrocatalytic sensor for hydrogen peroxide and dopamine with low detection limit, desirable selectivity and sensitivity.

Co3O4/carbon hollow nanospheres for resistive monitoring of gaseous hydrogen sulfide and for nonenzymatic amperometric sensing of dissolved hydrogen peroxide.

Co3O4/carbon hybrid hollow nanospheres (hs-Co3O4/C) with an empty cavity and a thin shell, were synthesized starting from the pectin and cobalt acetate via cross-linking deposition at room temperature and post-calcination. The hierarchical structure is constructed from the interconnected nanoparticles in the residual carbon matrix, and the carbon content can be adjusted by changing the calcination temperature. The gas sensor based on hs-Co3O4/C calcined at 300 °C in air shows high response towards 50 ppm of H2S (S = 95.5) and good selectivity at a low working temperature (92 °C). The detection limit is as low as 0.1 ppm. The non-enzymatic glassy carbon electrode based sensor constructed from the same material exhibits excellent electrocatalytic activity for H2O2 with the sensitivity of 405.8 µA∙mM∙cm-2 at 0.3 V (vs. SCE) in alkaline solution. The chronoamperometric response time is < 3 s and the detection limit (at S/N = 3) is 0.30 µM. The good sensing performances are attributed to the synergetic effect of unique hollow nanostructure and appropriate amount of carbon in the hybrid material. The porous nanostructure can increase the mass transfer efficiency, and the cross-linked nanoparticles with good crystallinity also improve the conductivity of materials. The presence of carbon enhances the charge transfer ability and increases the specific surface, thereby improving the sensor performance. Graphical abstract Schematic illustration of the formation of hollow Co3O4 nanospheres composited with pectin-derived carbon. The material displays excellent selectivity for H2S gas and in non-enzymatic detection of dissolved H2O2.

Study on the Inhibition Mechanism of Hydration Expansion of Yunnan Gas Shale using Modified Asphalt.

Drilling fluids play an essential role in shale gas development. It is not possible to scale up the use of water-based drilling fluid in shale gas drilling in Yunnan, China, because conventional inhibitors cannot effectively inhibit the hydration of the illite-rich shale formed. In this study, the inhibition performance of modified asphalt was evaluated using the plugging test, expansion test, shale recovery experiment, and rock compressive strength test. The experimental results show that in a 3% modified asphalt solution, the expansion of shale is reduced by 56.3%, the recovery is as high as 97.8%, water absorption is reduced by 24.3%, and the compression resistance is doubled compared with those in water. Moreover, the modified asphalt can effectively reduce the fluid loss of the drilling fluid. Modified asphalt can form a hydrophobic membrane through a large amount of adsorption on the shale surface, consequently inhibiting shale hydration. Simultaneously, modified asphalt can reduce the entrance of water into the shale through blocking pores, micro-cracks, and cracks and further inhibit the hydration expansion of shale. This demonstrates that modified asphalt will be an ideal choice for drilling shale gas formations in Yunnan through water-based drilling fluids.

Synergy of Active Sites and Charge Transfer in Branched WO3/W18O49 Heterostructures for Enhanced NO2 Sensing.

Achieving reliable detection of trace levels of NO2 gas is essential for environmental monitoring and protection of human health protection. Herein, a thin-film gas sensor based on branched WO3/W18O49 heterostructures was fabricated. The optimized WO3/W18O49 sensor exhibited outstanding NO2 sensing properties with an ultrahigh response value (1038) and low detection limit (10 ppb) at 50 °C. Such excellent sensing performance could be ascribed to the synergistic effect of accelerated charge transfer and increased active sites, which is confirmed by electrochemical impedance spectroscopy and temperature-programmed desorption characterization. The sensor exhibited an excellent detection ability to NO2 under different air quality conditions. This work provides an effective strategy for constructing WO3/W18O49 heterostructures for developing NO2 gas sensors with an excellent sensing performance.

Complexation and degradation of tetracycline by activation of molecular oxygen with biochar-supported nano-zero-valent copper composite.

Nano-zero-valent copper (nZVC) is a superior molecular oxygen (O2) activator for the abatement of organic pollutants due to its high electron utilization rate. However, the activation efficiency of O2 is compromised by the agglomeration tendency of nZVC particles and the concomitant reduction of the available active sites. To address this problem, the biochar (BC) with porous structure and abundant surface functional groups is utilized to disperse and stabilize nZVC for O2 activation (simplified as the nZVC/BC/O2 system) for efficient removal of tetracycline (TC). The nZVC/BC composite possesses a high specific area with well-distributed nZVC particles on the BC surface, which guarantees the superior dispersion and high reactivity in the activation of O2. The efficacy of the nZVC/BC/O2 system for TC abatement is evaluated and the underlying mechanism is elucidated. The results show that nZVC/BC/O2 system can achieve excellent removal of TC with the efficiencies of more than 85% in the pH range of 4.0-9.0, which originated from the combined action of complexation and degradation. The degradation is dominated by reactive oxygen species (ROS) including •OH, •O2- and 1O2 generated by Cu0/Cu+ activated O2 while the generation of Cu2+ via oxygen oxidation on the surface of nZVC/BC can remove TC by complexation adsorption. This study highlights the complexation and degradation in the removal of TC and can be expected to exhibit application prospects in the water and wastewater treatment.

Solvent-directed multiple correspondence fluorescent probe for highly selective and sensitive detection of Cu2+ and Mg2.

A solvent-directed, new Schiff base multiple correspondence fluorescent probe, (E)-2-(2-hydroxybenzylidene) hydrazine-1-carboxamid (L), was synthesized for selective sensing of Cu2+ and Mg2+ ions. L showed excellent selectivity and high sensitivity toward Cu2+ in "turn off" mode with a detection limit of 40.5 nM in 10 mM, pH = 7.0 PBS buffer. Contrary to that, when acetonitrile was used as the solvent, L exhibited highly selective and sensitive fluorescence sensing ability for Mg2+ in "turn on" mode with a detection limit of 9.5 nM. L can coordinate to Cu2+ and Mg2+ in a 1:1 molar ratio, respectively, evidenced by Job's plot analysis. Their binding modes were investigated by NMR, IR and XPS spectroscopies. Moreover, the satisfied results were obtained when L was used to detect Cu2+ and Mg2+ in real water samples.

A Novel Amphoteric Ion-Modified, Styrene-Based Nano-Microsphere and Its Application in Drilling Fluid.

With the gradual depletion of shallow oil and gas, deep oil and gas has become the focus of development. However, deep formations generally face the challenge of high-temperature and high-salinity, and drilling fluid agents are prone to failure, leading to drilling fluid intrusion into the formation that can cause serious drilling accidents such as well bore collapse. For this, a styrene-based nano-microsphere (SSD) modified with amphoteric ions was developed, with a particle size of 228 nm which could resist temperatures up to 200 °C and sodium chloride (NaCl) up to saturation. SSD has significant salt-responsive properties and its aqueous dispersion becomes transparent with increasing salinity. The SSD provided superior plugging performance in solutions containing NaCl, with a core plugging efficiency of 95.2%, and it was significantly better than the anion-modified microspheres. In addition, in drilling fluids under high temperature and high-salinity conditions, the SSD promotes particle gradation of drilling fluids and improves the zeta potential through its own plugging and synergistic effect with clay, which significantly improves the comprehensive performance of drilling fluids, such as stability, rheological performance, and filtration reduction performance. The development of SSD provides a new idea for research of high-temperature and high-salinity-resistant drilling fluid agents.

Novel Modified Styrene-Based Microspheres for Enhancing the Performance of Drilling Fluids at High Temperatures.

Ensuring wellbore stability is of utmost importance for safety when drilling in deep formations. However, high temperatures severely disrupt the drilling fluid gel system, leading to severe stability issues within ultra-deep formations containing micropores. This study focused on the development of a polymer-based plugging material capable of withstanding high temperatures up to 200 °C. A kind of microsphere, referred to as SST (styrene-sodium styrene sulfonate copolymer), was synthesized with a particle size of 322 nm. Compared to polystyrene, the thermal stability of SST is greatly improved, with a thermal decomposition temperature of 362 °C. Even after subjecting SST to hot rolling at 200 °C for 16 h, the particle size, elemental composition, and zeta potential remained stable within an aqueous dispersion system. The results of core displacement and NMR tests demonstrate that SST considerably reduces the pore diameter with a remarkable plugging efficiency of 78.9%. Additionally, when drilling fluids reach 200 °C, SST still enhances drilling fluid suspension and dispersion, and reduces fluid loss by over 36% by facilitating the dispersion of clay particles, improving the gel structure of the drilling fluid, resisting clay dehydration, and promoting plugging. The development of SST provides valuable insights into the preparation of high-temperature-resistant microspheres and the formulation of effective plugging agents for deep-well drilling fluids.

Selective detection of trace carbon monoxide at room temperature based on CuO nanosheets exposed to (111) crystal facets.

In recent years, carbon monoxide (CO) intoxication incidents occur frequently, and the sensitive detection of CO is particularly significant. At present, most reported carbon monoxide (CO) sensors meet the disadvantage of high working temperature. It is always a challenge to realize the sensitive detection of carbon monoxide at room temperature. In this study, CuO nanosheets exposed more (111) active crystal facets and oxygen vacancy defects were synthesized by a simple and environmentally friendly one-step hydrothermal method. The sensor has good comprehensive gas sensing performance, compared with other sensors that can detect CO at room temperature. The response value to 100 ppm CO at room temperature is as high as 39.6. In addition, it also has excellent selectivity, low detection limit (100 ppb), good reproducibility, moisture resistance and long-term stability (60 days). This excellent gas sensing performance is attributed to the special structural characteristics of 2D materials and the synergistic effect of more active crystal facets exposed on the crystal surface and oxygen vacancy defects. Therefore, it is expected to become a promising sensitive material for rapid and accurate detection of trace CO gas under low energy consumption, reduce the risk of poisoning, and then effectively protect human life safety.

Interfacial Passivation Enormously Enhances Electroluminescence of Triphenylphosphine Cu4 I4 Cube.

Defect is one of the key factors limiting optoelectronic performances of organic-inorganic hybrid systems. Although high-efficiency bidentate ligands based electroluminescent (EL) clusters reported, until present, only few EL clusters based on monodentate ligands are realized since their structural instability induces more surface/interface defects. Herein, this bottleneck is first overcome in virtue of interfacial passivation by electron transporting layers (ETL). Through using TmPyPB with meta-linked pyridines as ETL, photoluminescent (PL) and EL quantum efficiencies of the simplest monophosphine Cu4 I4 cube [TPP]4 Cu4 I4 are greatly improved by ≈2 and 23 folds, respectively, as well as ≈200 folds increased luminance, corresponding to a huge leap from nearly unlighted (<20 nits) to highly bright (>3000 nits). The passivation effect of TmPyPB on surface defects of cluster layer is embodied as preventing interfacial charge trapping and suppressing exciton nonradiation.

Activation of peracetic acid with zero-valent iron for tetracycline abatement: The role of Fe(II) complexation with tetracycline.

Peracetic acid (PAA) is an excellent oxidant that can produce multiple carbon-centered radicals (R•C). A novel advanced oxidation process (AOP) that combines PAA and nanoscale zero-valent iron (i.e. nZVI/PAA) is constructed to evaluate its performance toward tetracycline (TC) abatement. The nZVI/PAA process shows excellent abatement efficacy for TC in the pH range of 3.5-7.5. The presence of humic acid, HPO42- and HCO3- exerts inhibitory effects on TC abatement, while the presence of Cl- displays negligible influence in the nZVI/PAA process. Nanoscale zero-valent iron (nZVI) exhibits excellent reusability with no apparent variation in crystallinity. CH3C(O)OO• is the predominant active radical that contributes to TC abatement, in which leakage of Fe(II) from the nZVI surface is crucial for a radical generation. Due to the strong complexation tendency of TC towards Fe(II), the Fe(II)-TC complexes are formed, which significantly accelerates the PAA decomposition and TC abatement compared to free Fe(II). In addition, the degradation intermediates of TC are identified, and a possible degradation pathway is proposed. These results will be useful for the application of PAA-based AOPs in the treatment of water containing organic micropollutants.

Non-enzymatic nitrite amperometric sensor fabricated with near-spherical ZnO nanomaterial.

A unique near-spherical ZnO nanostructure was synthesized by using mixed solvents composed of polyethylene glycol-400 (PEG-400) and water at the volume ratio of 12:1 via the solvo-thermal method, and it possessed an ideal morphology with higher uniformity, better dispersion and small particle size. Such ZnO was employed to modify glass carbon electrode (GCE) for the construction of electrochemical sensor, i.e. near-spherical ZnO/GCE, whose nitrite sensing performance was evaluated by Chronoamperometry (CA) and Linear Sweep Voltammetry (LSV). In order to emphasis the superior sensing property and extensive suitability for different electrochemical detection techniques, the excellent but not the same nitrite detection performance obtained from CA and LSV was individually given in detail. This sensor based on CA showed broad linearity range of 0.6 µM-0.22 mM and 0.46 mM-5.5 mM, improved sensitivity of 0.785 µA µM-1 cm-2 accompanied with low LOD of 0.39 µM. With regard to LSV, wide linearity response of 1.9 µM-0.8 mM and 1.08 mM-5.9 mM, high sensitivity of 0.646 µA µM-1 cm-2 with LOD of 0.89 µM were obtained. Meanwhile, this sensor displayed outstanding repeatability with RSD of 2.96% (n = 4), high reproducibility with low RSD (1.72%-2.35%, n = 4), strong selectivity towards nitrite with the concentration set at one-tenth of the interfering substances, ideal stability with the peak current intensity above 90% of its initial value after storage for one month and acceptable recovery of 1.72-2.35% to actual samples including ham sausage, pickle and tap water. The near-spherical ZnO nanomaterial may be a preferred candidate for the fabrication of nitrite electrochemical sensor, which may exhibit a fascinating application in terms of food analysis and environmental monitoring.

Rapid detection of H2S gas driven by the catalysis of flower-like α-Bi2Mo3O12 and its visual performance: A combined experimental and theoretical study.

Metal oxide semiconductor (MOSs) are attractive materials for the development of H2S gas sensors. However, detecting H2S with short response and recovery times while also lowering the limit of detection to sub-ppb levels remains a significant challenge. We therefore developed flower-like α-Bi2Mo3O12 microspheres for H2S gas detection that provide fast response and recovery times (3 and 22 s, respectively, for 100 ppm H2S), while also reducing the limit of detection to 1 ppb. The sensor performs well in terms of sensitivity, reproducibility, long-term stability, including humidity stability. X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculations revealed that H2S dissociates readily on the reduced α-Bi2Mo3O12 surface and that Mo plays a catalytic role, accelerating the rate of H2S decomposition and enabling a fast response. Moreover, test strips containing α-Bi2Mo3O12 were also prepared, which enabled the naked eye detection of ppm-level H2S gas at room temperature; a light-yellow to orange to brown color change occurs when exposed to H2S, due to its conversion into stable sulfides. This work expands the application of α-Bi2Mo3O12 to H2S gas sensing, and provides a strategy for the use of MOSs as sensor materials for the detection of other gases.

Controllable construction of ZnFe2O4-based micro-nano heterostructure for the rapid detection and degradation of VOCs.

Micro-nano heterogeneous oxides have received extensive attention due to their distinctive physicochemical properties. However, it is a challenge to prepare the hierarchical multicomponent metal oxide nanomaterials with abundant heterogeneous interfaces in a controllable way. In this work, the effective construction of the heterogeneous structure of the material is achieved by regulating the ratio of metal salts under thermal solvent condition. Three-dimensional spheres (ZnFe2O4) constructed by zero-dimensional ultra-small nanoparticles, in particular three-dimensional hollow sea urchin spheres (ZnO/ZnFe2O4) constructed by one-dimensional nanorods and three-dimensional hydrangeas (α-Fe2O3/ZnFe2O4) assembled by two-dimensional nanosheets were obtained. The two composite materials contain a large number of heterojunctions, which enhances the sensitivity of material to volatile organic compounds gas. Among them, the α-Fe2O3/ZnFe2O4 composite shows the best sensing performance for VOCs. For example, its response to 100 ppm acetone reaches 142 at 170 °C with the response time shortened to 3 s and the detection limit falling to 10 ppb. Meanwhile, the composite material presents a degradation rate of more than 90% for VOCs at a flow rate of 20 mL/min at 170 °C. In addition, the sensing and sensitivity mechanism of the composite material are studied in detail by combining GC-MS, XPS with UV diffuse reflectance tests.