Valorization of spent brewery yeast biosorbent with sonication-assisted adsorption for dye removal in wastewater treatment.

The effluent of textile industries containing synthetic dyes contributed to substantial pollution to water bodies. The biosorption process of Congo Red dye was successfully performed by integrating ultrasonication in the adsorption step with spent brewery yeast as a novel and renewable biosorbent. The adsorption process was hindered when ultrasonication was employed together with the biosorbent, indicating that desorption process had occurred. The adsorption process showed that 4 g/L of biosorbent was the optimum dosage for adsorption of 50 mg/L of Congo Red dye, and that the adsorption equilibrium fitted to the Langmuir model, with kinetics best fitted with pseudo-second order model. The maximum capacity of the adsorption was 52.6 mg/g, showing the potential of spent brewery yeast to aid in removing wastewater pollutants. Maximal Congo Red dye recovery (100%) was achieved in the sonication-assisted desorption studies using 0.01M NaOH as the eluting agent. The ultrasonication effects contributed to the efficient recovery of dye and good conversion of spent brewery yeast to biosorbent can be beneficial for treating pollution from textile wastewater.

Management of disposable surgical masks for tackling pandemic-generated pollution: Thermo-acoustic investigations and life cycle assessment of novel recycled building panels.

The COVID-19 pandemic has changed people's habits, causing them to use large amounts of disposable items and exacerbating the already existing issue of pollution. One way to reduce the environmental impact of this shift in daily habits is to recycle these items, e.g. surgical masks that are the most common personal protective equipment against the virus, to produce panels for building applications. In this work, both the thermal and acoustical performance of such panels are evaluated using a small and a large scale investigation under real-world conditions. Small scale thermal tests are performed by means of the Hot Disk instrument while the acoustic investigations are performed by means of the impedance tube. Large scale tests are carried out in a reverberation chamber assessing both the heat flow passing through the wall and the acoustic absorption coefficient of the panels. Finally, the environmental impact of the innovative recycled panel is also investigated in a life cycle perspective. Overall, the material behavior scored well on these tests, suggesting that the proposed approach may be a good recycling method.

Experimental validation of acoustic and thermal modeling in heterogeneous phantoms using the hybrid angular spectrum method.

PURPOSE: The aim was to quantitatively validate the hybrid angular spectrum (HAS) algorithm, a rapid wave propagation technique for heterogeneous media, with both pressure and temperature measurements. METHODS: Heterogeneous tissue-mimicking phantoms were used to evaluate the accuracy of the HAS acoustic modeling algorithm in predicting pressure and thermal patterns. Acoustic properties of the phantom components were measured by a through-transmission technique while thermal properties were measured with a commercial probe. Numerical models of each heterogeneous phantom were segmented from 3D MR images. Cylindrical phantoms 30-mm thick were placed in the pre-focal field of a focused ultrasound beam and 2D pressure measurements obtained with a scanning hydrophone. Peak pressure, full width at half maximum, and normalized root mean squared difference (RMSDn) between the measured and simulated patterns were compared. MR-guided sonications were performed on 150-mm phantoms to obtain MR temperature measurements. Using HAS-predicted power density patterns, temperature simulations were performed. Experimental and simulated temperature patterns were directly compared using peak and mean temperature plots, RMSDn metrics, and accuracy of heating localization. RESULTS: The average difference between simulated and hydrophone-measured peak pressures was 9.0% with an RMSDn of 11.4%. Comparison of the experimental MRI-derived and simulated temperature patterns showed RMSDn values of 10.2% and 11.1% and distance differences between the centers of thermal mass of 2.0 and 2.2 mm. CONCLUSIONS: These results show that the computationally rapid hybrid angular spectrum method can predict pressure and temperature patterns in heterogeneous models, including uncertainties in property values and other parameters, to within approximately 10%.

Effects of Syllable Position, Fundamental Frequency, Duration and Amplitude on Word Stress in Mandarin Chinese.

This study examined the importance of syllable position, duration, and tone/pitch for the assignment of stress in Chinese hums. Twenty native Mandarin speakers and 20 native English speakers were asked to assign primary stress to two-syllable Chinese hums. The importance of acoustic cues for stress assignment was also evaluated. Our findings indicate that syllable position plays the most prominent role in stress assignment. Native Chinese listeners preferred to assign stress to final syllables whereas native English listeners preferred to assign stress to initial syllables. Both language groups were sensitive to different acoustic cues in assigning stress. The effects of complex interactions of syllable position, tone, duration and intensity on stress assignment in Chinese hums for both language groups support the hypothesis that linguistic experience affects speech perception at the suprasegmental level.

I know that voice! Mothers' voices influence children's perceptions of emotional intensity.

The ability to interpret others' emotions is a critical skill for children's socioemotional functioning. Although research has emphasized facial emotion expressions, children are also constantly required to interpret vocal emotion expressed at or around them by individuals who are both familiar and unfamiliar to them. The current study examined how speaker familiarity, specific emotions, and the acoustic properties that comprise affective prosody influenced children's interpretations of emotional intensity. Participants were 51 7- and 8-year-olds presented with speech stimuli spoken in happy, angry, sad, and nonemotional prosodies by both each child's mother and another child's mother unfamiliar to the target child. Analyses indicated that children rated their own mothers as more intensely emotional compared with the unfamiliar mothers and that this effect was specific to angry and happy prosodies. Furthermore, the acoustic properties predicted children's emotional intensity ratings in different patterns for each emotion. The results are discussed in terms of the significance of the mother's voice in children's development of emotional understanding.

Infants use phonetic detail in speech perception and word learning when detail is easy to perceive.

Infants successfully discriminate speech sound contrasts that belong to their native language's phonemic inventory in auditory-only paradigms, but they encounter difficulties in distinguishing the same contrasts in the context of word learning. These difficulties are usually attributed to the fact that infants' attention to the phonetic detail in novel words is attenuated when they must allocate additional cognitive resources demanded by word-learning tasks. The current study investigated 15-month-old infants' ability to distinguish novel words that differ by a single vowel in an auditory discrimination paradigm (Experiment 1) and a word-learning paradigm (Experiment 2). These experiments aimed to tease apart whether infants' performance is dependent solely on the specific acoustic properties of the target vowels or on the context of the task. Experiment 1 showed that infants were able to discriminate only a contrast marked by a large difference along a static dimension (the vowels' second formant), whereas they were not able to discriminate a contrast with a small phonetic distance between its vowels, due to the dynamic nature of the vowels. In Experiment 2, infants did not succeed at learning words containing the same contrast they were able to discriminate in Experiment 1. The current findings demonstrate that both the specific acoustic properties of vowels in infants' native language and the task presented continue to play a significant role in early speech perception well into the second year of life.

Physical and Sensory Properties of Japanese Quince Chips Obtained by Osmotic Dehydration in Fruit Juice Concentrates and Hybrid Drying.

Japanese quince has high health value, but due to its taste and texture, it is difficult to eat raw. The use of innovative drying methods to produce dried snack foods from these fruits may be of interest to producers and consumers. The physicochemical and sensory properties of 3 mm slices of Japanese quince fruit (with skin, without seeds) obtained by osmotic pre-treatment in chokeberry and apple juice concentrates, and with the use of convection (convective drying, C-D), freeze-drying (F-D), and convection-microwave-vacuum drying (hybrid) are assessed. The methods of drying osmo-dehydrated slices do not affect the dry matter content. In most dried quince, the water activity is 0.40 or lower. Pre-osmotic dehydration and drying have a significant impact on the mechanical and acoustic properties of quince chips. Sensory attractive chips emit loud acoustic emission (AE) during the breaking test. Chips that are osmo-dehydrated in a mixture of chokeberry juice concentrate and sucrose and dried by a hybrid method are attractive. They have a dark red color given by chokeberry concentrate and a slight sweet (with a slight sour-bitter) taste. The sensory evaluation was useful for determining the quality of the chips in terms of their texture (crispness) tested by mechanical methods. Their sensory ratings (overall desirability as weight of color, taste, crispness, and flavor) are high and similar (from 3.8 to 4.1). The use of innovative drying methods with pre-osmotic treatment allows obtaining dried material with properties comparable to those obtained by the F-D method, but in a much shorter time, i.e., with lower energy and using a simple method.

Pre- and Paralinguistic Vocal Production in ASD: Birth Through School Age.

PURPOSE OF REVIEW: We review what is known about how pre-linguistic vocal differences in autism spectrum disorder (ASD) unfold across development and consider whether vocalization features can serve as useful diagnostic indicators. RECENT FINDINGS: Differences in the frequency and acoustic quality of several vocalization types (e.g., babbles and cries) during the first year of life are associated with later ASD diagnosis. Paralinguistic features (e.g., prosody) measured during early and middle childhood can accurately classify current ASD diagnosis using cross-validated machine learning approaches. Pre-linguistic vocalization differences in infants are promising behavioral markers of later ASD diagnosis. In older children, paralinguistic features hold promise as diagnostic indicators as well as clinical targets. Future research efforts should focus on (1) bridging the gap between basic research and practical implementations of early vocalization-based risk assessment tools, and (2) demonstrating the clinical impact of targeting atypical vocalization features during social skill interventions for older children.

Three-month-old human infants use vocal cues of body size.

Differences in vocal fundamental (F0) and average formant (Fn) frequencies covary with body size in most terrestrial mammals, such that larger organisms tend to produce lower frequency sounds than smaller organisms, both between species and also across different sex and life-stage morphs within species. Here we examined whether three-month-old human infants are sensitive to the relationship between body size and sound frequencies. Using a violation-of-expectation paradigm, we found that infants looked longer at stimuli inconsistent with the relationship-that is, a smaller organism producing lower frequency sounds, and a larger organism producing higher frequency sounds-than at stimuli that were consistent with it. This effect was stronger for fundamental frequency than it was for average formant frequency. These results suggest that by three months of age, human infants are already sensitive to the biologically relevant covariation between vocalization frequencies and visual cues to body size. This ability may be a consequence of developmental adaptations for building a phenotype capable of identifying and representing an organism's size, sex and life-stage.

Development and validation of a MRgHIFU non-invasive tissue acoustic property estimation technique.

MR-guided high-intensity focussed ultrasound (MRgHIFU) non-invasive ablative surgeries have advanced into clinical trials for treating many pathologies and cancers. A remaining challenge of these surgeries is accurately planning and monitoring tissue heating in the face of patient-specific and dynamic acoustic properties of tissues. Currently, non-invasive measurements of acoustic properties have not been implemented in MRgHIFU treatment planning and monitoring procedures. This methods-driven study presents a technique using MR temperature imaging (MRTI) during low-temperature HIFU sonications to non-invasively estimate sample-specific acoustic absorption and speed of sound values in tissue-mimicking phantoms. Using measured thermal properties, specific absorption rate (SAR) patterns are calculated from the MRTI data and compared to simulated SAR patterns iteratively generated via the Hybrid Angular Spectrum (HAS) method. Once the error between the simulated and measured patterns is minimised, the estimated acoustic property values are compared to the true phantom values obtained via an independent technique. The estimated values are then used to simulate temperature profiles in the phantoms, and compared to experimental temperature profiles. This study demonstrates that trends in acoustic absorption and speed of sound can be non-invasively estimated with average errors of 21% and 1%, respectively. Additionally, temperature predictions using the estimated properties on average match within 1.2 °C of the experimental peak temperature rises in the phantoms. The positive results achieved in tissue-mimicking phantoms presented in this study indicate that this technique may be extended to in vivo applications, improving HIFU sonication temperature rise predictions and treatment assessment.

Listening to trees in the forest: Attentional set influences how semantic and acoustic factors interact in auditory perception.

Studies of auditory object perception claim that semantic properties dominate acoustic properties in determining identification accuracy. Yet the direction of the semantic effect is mixed, with some studies showing an advantage for detecting incongruent sounds and others reporting a congruent sound advantage. Here we examine the role of the participant's attentional set when identifying auditory objects in naturalistic soundscapes. We varied the acoustic and semantic properties of the sounds orthogonally in two experiments. In Experiment 1 participants tuned their attention broadly to detect any change between two successive soundscapes (e.g., two restaurant soundscapes, with and without a child coughing). In Experiment 2 they tuned attention more narrowly to a probe presented after a soundscape (e.g., a restaurant soundscape with a child coughing, followed by the coughing sound alone). In both experiments, semantic relations between the objects and backgrounds helped to disambiguate objects that blended acoustically with the background. When attending globally (Experiment 1), objects that were acoustically similar yet semantically incongruent tended to be missed (e.g., bouncing basketball on a construction site), as though camouflaged by the gist of the soundscape. When attending locally (Experiment 2), semantically congruent foil objects led to false positive reports under acoustically similar conditions (hammering sounds on a construction site), as though the gist of the soundscape contributed to their plausible inclusion. In summary, although attentional set had a strong influence on the specific kinds of errors made, both results pointed to participants using a semantically congruent high-level schema to report the sounds they heard.

Investigation into the Acoustic Properties of Polylactic Acid Sound-Absorbing Panels Manufactured by 3D Printing Technology: The Influence of Nozzle Diameters and Internal Configurations.

Sound-absorbing panels are widely used in the acoustic design of aircraft parts, buildings and vehicles as well as in sound insulation and absorption in areas with heavy traffic. This paper studied the acoustic properties of sound-absorbing panels manufactured with three nozzle diameters (0.4 mm, 0.6 mm and 0.8 mm) by 3D printing from three types of polylactic acid filaments (Grey Tough PLA; Black PLA Pro; Natural PLA) and with six internal configurations with labyrinthine zigzag channels (Z1 and Z2). The absorption coefficient of the sample with the Z2 pattern, a 5.33 mm height, a 0.6 mm nozzle diameter and with Black PLA Pro showed the maximum value (α = 0.93) for the nozzle diameter of 0.6 mm. Next in position were the three samples with the Z1 pattern (4 mm height) made from all three materials used and printed with a nozzle diameter of 0.4 mm with a sound absorption coefficient value (α = 0.91) at 500 Hz. The highest value of the sound transmission loss (56 dB) was found for the sample printed with a nozzle size of 0.8 mm with the Z2 pattern (8 mm height) and with Black PLA Pro. The extruded material, the nozzle diameter and the internal configuration had a significant impact on the acoustic performance of the 3D-printed samples.

High-resolution acoustic mapping of tunable gelatin-based phantoms for ultrasound tissue characterization.

Background: The choice of gelatin as the phantom material is underpinned by several key advantages it offers over other materials in the context of ultrasonic applications. Gelatin exhibits spatial and temporal uniformity, which is essential in creating reliable tissue-mimicking phantoms. Its stability ensures that the phantom's properties remain consistent over time, while its flexibility allows for customization to match the acoustic characteristics of specific tissues, in addition to its low levels of ultrasound scattering. These attributes collectively make gelatin a preferred choice for fabricating phantoms in ultrasound-related research. Methods: We developed gelatin-based phantoms with adjustable parameters and conducted high-resolution measurements of ultrasound wave attenuation when interacting with the gelatin phantoms. We utilized a motorized acoustic system designed for 3D acoustic mapping. Mechanical evaluation of phantom elasticity was performed using unconfined compression tests. We particularly examined how varying gelatin concentration influenced ultrasound maximal intensity and subsequent acoustic attenuation across the acoustic profile. To validate our findings, we conducted computational simulations to compare our data with predicted acoustic outcomes. Results: Our results demonstrated high-resolution mapping of ultrasound waves in both gelatin-based phantoms and plain fluid environments. Following an increase in the gelatin concentration, the maximum intensity dropped by 30% and 48% with the 5 MHz and 1 MHz frequencies respectively, while the attenuation coefficient increased, with 67% more attenuation at the 1 MHz frequency recorded at the highest concentration. The size of the focal areas increased systematically as a function of increasing applied voltage and duty cycle yet decreased as a function of increased ultrasonic frequency. Simulation results verified the experimental results with less than 10% deviation. Conclusion: We developed gelatin-based ultrasound phantoms as a reliable and reproducible tool for examining the acoustic and mechanical attenuations taking place as a function of increased tissue elasticity and stiffness. Our experimental measurements and simulations gave insight into the potential use of such phantoms for mimicking soft tissue properties.

A Dynamic Ultrasound Phantom with Tissue-Mimicking Mechanical and Acoustic Properties.

Tissue-mimicking phantoms are valuable tools that aid in improving the equipment and training available to medical professionals. However, current phantoms possess limited utility due to their inability to precisely simulate multiple physical properties simultaneously, which is crucial for achieving a system understanding of dynamic human tissues. In this work, novel materials design and fabrication processes to produce various tissue-mimicking materials (TMMs) for skin, adipose, muscle, and soft tissue at a human scale are developed. Target properties (Young's modulus, density, speed of sound, and acoustic attenuation) are first defined for each TMM based on literature. Each TMM recipe is developed, associated mechanical and acoustic properties are characterized, and the TMMs are confirmed to have comparable mechanical and acoustic properties with the corresponding human tissues. Furthermore, a novel sacrificial core to fabricate a hollow, ellipsoid-shaped bladder phantom complete with inlet and outlet tubes, which allow liquids to flow through and expand this phantom, is adopted. This dynamic bladder phantom with realistic mechanical and acoustic properties to human tissues in combination with the developed skin, soft tissue, and subcutaneous adipose tissue TMMs, culminates in a human scale torso tank and electro-mechanical system that can be systematically utilized for characterizing various medical imaging devices.

Mycelium-Based Composites as a Sustainable Solution for Waste Management and Circular Economy.

The global population is expected to increase by nearly 2 billion individuals over the next three decades, leading to a significant surge in waste generation and environmental challenges. To mitigate these challenges, there is a need to develop sustainable solutions that can effectively manage waste generation and promote a circular economy. Mycelium-based composites (MBCs) are being developed for various applications, including packaging, architectural designs, sound absorption, and insulation. MBCs are made by combining fungal mycelium with organic substrates, using the mycelium as a natural adhesive. Mycelium, the vegetative part of fungi, can be grown on various organic feedstocks and functionalized into a range of diverse material types that are biobased and thus more sustainable in their production, use, and recycling. This work aims to obtain mycelium-based composites with acoustic absorption properties, using coffee grounds and agricultural waste as raw materials. The topic approached presents a new method of recovering spent coffee grounds that does not involve high production costs and reduces two current environmental problems: noise pollution and abundant waste. Measurements of the normal-incidence sound absorption coefficient were presented and analyzed. Mycelium-based composites offer an innovative, sustainable approach to developing bio-composite sound-absorbing surfaces for interior fittings. The material by Ganoderma lucidum exhibits exceptional sound-absorbing properties at frequencies below 700 Hz, which is a crucial aspect of creating sound-absorbing materials that effectively absorb low-frequency sound waves. The modular construction system allows for a high degree of flexibility to adapt to short-term changes in the workplace.

Sound Absorption Performance and Mechanical Properties of the 3D-Printed Bio-Degradable Panels.

The 3D printing process allows complex structures to be obtained with low environmental impact using biodegradable materials. This work aims to develop and acoustically characterize 3D-printed panels using three types of materials, each manufactured at five infill densities (20%, 40%, 60%, 80% and 100%) with three internal configurations based on circular, triangular, and corrugated profiles. The highest absorption coefficient values (α = 0.93) were obtained from the acoustic tests for the polylactic acid material with ground birch wood particles in the triangular configuration with an infill density of 40%. The triangular profile showed the best acoustic performance for the three types of materials analysed and, from the point of view of the mechanical tests, it was highlighted that the same triangular configuration presented the highest resistance both to compression (40 MPa) and to three-point bending (50 MPa). The 40% and 60% infill density gave the highest absorption coefficient values regardless of the material analyzed. The mechanical tests for compression and three-point bending showed higher strength values for samples manufactured from simple polylactic acid filament compared to samples manufactured from ground wood particles. The standard defects of 3D printing and the failure modes of the interior configurations of the 3D-printed samples could be observed from the microscopic analysis of the panels. Based on the acoustic results and the determined mechanical properties, one application area for these types of 3D-printed panels could be the automotive and aerospace industries.

A review of recent developments in kenaf fiber/polylactic acid composites research.

Kenaf fiber has recently garnered exponential interest as reinforcement in composite materials across diverse industries owing to its superior mechanical attributes, ease of manufacture, and inherent biodegradability. In the discourse of this review, various methods of manufacturing kenaf/Polylactic acid (PLA) composites have been discussed meticulously, as delineated in recently published scientific literatures. This paper delves into the chemical modification of kenaf fiber, examining its consequential impact on tensile strength and thermal stability of the kenaf/PLA composites. Further, this review illuminates the role of innovative 3D printing techniques and fiber orientation in augmenting the mechanical robustness of the kenaf/PLA composites. Simultaneously, recent insightful explorations into the acoustic properties of the kenaf/PLA composites, underscoring their potential as sustainable alternative to conventional materials have been reviewed. Serving as a comprehensive repository of knowledge, this review paper holds immense value for researchers aiming to utilize the capabilities of kenaf fiber reinforced PLA composites.

Experimental Study on the Damage Characteristics and Acoustic Properties of Red Sandstone with Different Water Contents under Microwave Radiation.

Rock breaking is one of the most basic issues in deep underground engineering. Water plays an important role in the rock response under microwave radiation. Consequently, microwave radiation experiments using red sandstone with different water contents were conducted. The damage characteristics and ultrasonic properties of red sandstone after microwave radiation were primarily investigated, and the representative conclusions were drawn as follows: With the increase in water content, the time of complete formation of the rupture surface of the rock sample gradually decreased, and the decreasing range gradually increased. When the fracture surface is completely formed, the samples with a higher water content have more powdery rock cuttings and less surface roughness. The damage degree of the samples does not increase significantly with the increase in the water content when the sample is radiated at the same time. As the microwave radiation time is increased, the damage degree of the sample will increase significantly. Through the ultrasonic velocity test, it can be suggested that the sample exhibits obvious zonal damage characteristics under the action of a microwave. Generally speaking, it is a very effective means of improving the degree of microwave attenuation of the rock by increasing the water content of the rock mass.

The influence of bone model geometries on the determination of skull acoustic properties.

In this study, we investigated the impact of various simulated skull bone geometries on the determination of skull speed of sound and acoustic attenuation values via optimization using transmitted pressure amplitudes beyond the bone. Using the hybrid angular spectrum method (HAS), we simulated ultrasound transmission through four model sets of different geometries involving sandwiched layers of diploë and cortical bone in addition to three models generated from CT images of ex-vivo human skull-bones. We characterized cost-function solution spaces for each model and, using optimization, found that when a model possessed appreciable variations in resolvable layer thickness, the predefined attenuation coefficients could be found with low error (RMSE < 0.01 Np/cm). However, we identified a spatial frequency cutoff in the models' geometry beyond which the accuracy of the property determination begins to fail, depending on the frequency of the ultrasound source. There was a large increase in error of the attenuation coefficients determined by the optimization when the variations in layer thickness were above the identified spatial frequency cutoffs, or when the lateral variations across the model were relatively low in amplitude. For our limited sample of three CT-image derived bone models, the attenuation coefficients were determined successfully. The speed of sound values were determined with low error for all models (including the CT-image derived models) that were tested (RMSE < 0.4 m/s). These results illustrate that it is possible to determine the acoustic properties of two-component models when the internal bone structure is taken into account and the structure satisfies the spatial frequency constraints discussed.

Water content monitoring in water-in-oil emulsions using a delay line cell.

The extraction process of crude oil requires addition of water, resulting in complex emulsions, in which the phases must be separated before the petrochemical processing starts. An ultrasonic cell may be used to determine in real time the water content in water-in-crude oil emulsions. The water content of emulsions can be related to parameters, such as propagation velocity, density and relative attenuation. The ultrasonic measurement cell developed here is composed of two piezoelectric transducers, two rexolite buffer rods, and a sample chamber. It is an inexpensive and robust system. The cell measures the parameters at different temperatures and flow conditions. The tests were performed using emulsions with water volume concentrations from 0% to 40%. The experimental results show that this cell is able to obtain more precise parameters, when compared to similar ultrasonic techniques. The data acquired in real time may be used to improve the emulsion separation, decreasing greenhouse gases and energy requirements.