Directed Dehydration as Synthetic Tool for Generation of a New Na4 SnS4 Polymorph: Crystal Structure, Na+ Conductivity, and Influence of Sb-Substitution.

We present the convenient synthesis and characterization of the new ternary thiostannate Na4 SnS4 (space group I 4 1 / a c d ) by directed removal of crystal water molecules from Na4 SnS4 ⋅14 H2 O. The compound represents a new kinetically stable polymorph of Na4 SnS4 , which is transformed into the known, thermodynamically stable form (space group P 4 ‾ 2 1 c ) at elevated temperatures. Thermal co-decomposition of mixtures with Na3 SbS4 ⋅9 H2 O generates solid solution products Na4-x Sn1-x Sbx S4 (x=0.01, 0.10) isostructural to the new polymorph (x=0). Incorporation of Sb5+ affects the bonding and local structural situation noticeably evidenced by X-ray diffraction, 119 Sn and 23 Na NMR, and 119 Sn Mössbauer spectroscopy. Electrochemical impedance spectroscopy demonstrates an enormous improvement of the ionic conductivity with increasing Sb content for the solid solution (σ25°C =2×10-3 , 2×10-2 , and 0.1 mS cm-1 for x=0, 0.01, and 0.10), being several orders of magnitude higher than for the known Na4 SnS4 polymorph.

Heavy Metal Contamination Alters the Co-Decomposition of Leaves of the Invasive Tree Rhus typhina L. and the Native Tree Koelreuteria paniculata Laxm.

Invasive and native plants can coexist in the same habitat; however, the decomposition process may be altered by the mixing of invasive and native leaves. Heavy metal contamination may further alter the co-decomposition of both leaf types. This study evaluated the effects of two concentrations (35 mg·L-1 and 70 mg·L-1) and three types (Pb, Cu, and combined Pb + Cu) of heavy metal contamination on the co-decomposition of leaves of the invasive tree Rhus typhina L. and the native tree Koelreuteria paniculata Laxm, as well as the mixed effect intensity of the co-decomposition of the mixed leaves. A polyethylene litterbag experiment was performed over six months. The decomposition coefficient of the two trees, mixed effect intensity of the co-decomposition, soil pH and enzymatic activities, soil bacterial alpha diversity, and soil bacterial community structure were determined. A high concentration of Pb and combined Pb + Cu significantly reduced the decomposition rate of R. typhina leaves. A high concentration of Pb or Cu significantly reduced the decomposition rate of the mixed leaves. In general, R. typhina leaves decomposed faster than K. paniculata leaves did. There were synergistic effects observed for the co-decomposition of the mixed leaves treated with combined Pb + Cu, regardless of concentration, but there were antagonistic effects observed for the co-decomposition of the mixed leaves treated with either Pb or Cu, regardless of concentration. A high concentration of Pb or Cu may increase antagonistic effects regarding the co-decomposition of mixed-leaf groups. Thus, heavy metal contamination can significantly affect the intensity of the mixed effect on the co-decomposition of heterogeneous groups of leaves.

Succession of fungal community and enzyme activity during the co-decomposition process of rice (Oryza sativa L.) straw and milk vetch (Astragalus sinicus L.).

The co-incorporation of rice straw (RS) and milk vetch (MV) into paddy fields has been increasingly applied as a sustainable farming practice in southern China. Our previous study revealed the contribution of bacteria to the co-decomposition of the RS and MV mixture, although additional underlying factors driving the co-decomposition process need to be clarified. The present study further determined the succession of fungal communities and enzyme activity in the co-decomposition process of the RS and MV mixture. The results showed that non-additive synergistic effects on biomass loss were observed in 55.6% of the sampled RS and MV mixture during the co-decomposition process, stimulating mixture decomposition. Overall fungal abundance was 19.6-30.6% higher in the RS and MV mixture throughout the study than in the single residue. Fungal diversity and community structure were mainly affected by the sampling date rather than the type of residue. Specifically, mixing RS and MV significantly increased the abundance of Peziza sp. and Reticulascus tulasneorum (lignocellulose- and lignin-decomposing fungi) and exhibited higher activities of C- and N-related hydrolases than monospecific residues. Random forest (RF) models showed that bacteria contributed more to the residue decomposition and activities of C-related hydrolases, N-related hydrolases, and oxidases than fungi. However, both RF and partial least squares path models revealed that fungal abundance and community structure directly or indirectly affected the residue decomposition rate. These findings showed that mixing RS and MV could stimulate their decomposition by enhancing C-related hydrolase activity and Peziza sp. and Reticulascus tulasneorum abundance.

Using milk vetch (Astragalus sinicus L.) to promote rice straw decomposition by regulating enzyme activity and bacterial community.

The present study determined the dynamic changes of enzyme activity and bacterial community in rice straw (RS) and milk vetch (MV) co-decomposing process. Results showed that mixing RS and MV promoted decomposition. The mixture enhanced ß-glucosidase and ß-cellobiohydrolase activities relative to its monospecific residue during the mid-late stage of decomposition. The mixture enhanced Enterobacteriaceae (monosaccharide decomposing bacteria) abundance during the initial stage of decomposition, and the abundance of Hydrogenispora, Bacteroides, Ruminiclostridium, and Acidobacteriaceae that could hydrolyze fiber during the mid-late stage of decomposition relative to single RS and MV, respectively, which would benefit mixture decomposition. Furthermore, more interconnected and competitive relations existed between the bacteria in the mixture. These results indicated that mixing RS and MV promoted residue decomposition by increasing hydrolytic enzyme activities and changing bacterial community. This study concluded that co-incorporating RS and MV may be recommended as a promising practice for the efficient utilization of RS resources.

The improved treatment of liquid crystals into non-hazardous molecules using a microwave-assisted hydrothermal method.

Liquid crystal (LC), as a crucial component of liquid crystal display (LCD), improperly treatment of which will possibly impair ecosystems and human health. In view of the advantages of hydrothermal reaction and microwave irradiation, this paper intensively studied the process of microwave-assisted hydrothermal (MWAH) decomposition of LC wastes. The experimental materials include a kind of refractory fluorinated liquid crystal commonly used in thin-film transistor LCD, and its mixture with the other two typical liquid crystal monomers in the waste low-end display panels. Under the MWAH process, the optimized condition for thorough decomposition of 0.67 g.L-1 fluorinated liquid crystal is 0.653 mol.L-1 H2O2, 1 g.L-1 AC, 300 mL water, 250 °C and 7 min. The superiority of microwave in enhancing hydrothermal treatment efficiency was verified by the first-order kinetic reaction equation fitted for the decomposition process under optimal condition, along with two possible decomposition pathways tentatively proposed after characterizing the intermediate products. Under the same condition, 1 g.L-1 mixture of fluorinated liquid crystal and the other two liquid crystal monomers were entirely decomposed with no harmful byproduct detected, suggesting that microwave irradiation could effectively promote the hydrothermal decomposition of liquid crystal wastes.