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Chemosphere ; 288(Pt 3): 132609, 2022 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-34687683

RESUMO

This review article provides the recent progress in semiconductor-based zeolite photoactive materials for the application of noxious contaminants removal. The rapidly expanding industrialization and globalization cause serious threats to the environment or water bodies. The semiconductor@zeolite photocatalysts were implemented for water quality management/sustainment. The exclusive properties of zeolite material have been elaborated with their role in the photocatalysis process. The photoactive material's properties like single-atom catalysts (SACs), distribution of metal in the zeolite crystal were elaborated along with their role in catalytic reactions. Differently prepared semiconductor@zeolite composites such as TiO2@zeolite, binary and ternary composites, Fe/Ag/bismuth-modified/ZnO/ZnS/NiO/g-C3N4/core-shell/quantum dots modified zeolite composites, were systematically summarized. The research progress in morphologies, structural effect, degradation mechanism were recapitulated and tabulated form of % degradation with their optimal parameters such as catalyst dose, pollutant concentrations, pH, light source intensities were also provided. The significance of zeolite frameworks, the structural properties of semiconductor@zeolite photoactive materials to enhance the degradation efficiencies was explored. Analysis of the intermediate products of Norfloxacin, TCDD (2,3,7,8-tetrachlorodibenzo-p-dioxin), TCDF (2,3,7,8-tetrachlorodibenzofuran), diclofenac contaminants were systematically represented and structurally identified by GC-MS/HPLC-MS techniques.


Assuntos
Zeolitas , Catálise , Norfloxacino , Fotólise , Semicondutores
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