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Activated carbon has an excellent porous structure and is considered a promising adsorbent and electrode material. In this study, activated carbon fibers (ACFs) with abundant microporous structures, derived from natural cotton fibers, were successfully synthesized at a certain temperature in an Ar atmosphere and then activated with KOH. The obtained ACFs were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), elemental analysis, nitrogen and carbon dioxide adsorption-desorption analysis, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and N2 adsorption-desorption measurement. The obtained ACFs showed high porous qualities and had a surface area from 673 to 1597 m2/g and a pore volume from 0.33 to 0.79 cm3/g. The CO2 capture capacities of prepared ACFs were measured and the maximum capture capacity for CO2 up to 6.9 mmol/g or 4.6 mmol/g could be achieved at 0 °C or 25 °C and 1 standard atmospheric pressure (1 atm). Furthermore, the electrochemical capacitive properties of as-prepared ACFs in KOH aqueous electrolyte were also studied. It is important to note that the pore volume of the pores below 0.90 nm plays key roles to determine both the CO2 capture ability and the electrochemical capacitance. This study provides guidance for designing porous carbon materials with high CO2 capture capacity or excellent capacitance performance.
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Wasted coal liquefaction residual was used to synthesize activated carbon fibers (ACFs) for CO2 capture, and the properties of the developed ACFs were optimized by adjusting the activation conditions, including the reaction temperature and soaking time. The yield, element distribution, pore structure, composition, functional group, morphology, and adsorption capacity of the as-synthesized ACFs were characterized by various apparatuses. In addition, static and dynamic adsorption experiments were conducted to investigate the adsorption capacity of CO2 in flue gas. The results revealed that the synthesized ACFs are mainly composed of carbon, accounting for more than 90% of the total elements. The specific surface area, pore volume, and pore width distribution of the prepared ACFs were optimized by changing the activation conditions, and ACFs with a specific surface area higher than 1400 m2/g were successfully developed by activation at 950 for 3 h. The amount of micropores occupied more than 90% of the total pore volume. The pore width distribution dominated by micropores is beneficial for CO2 adsorption since the diameter of CO2 is 0.33 nm. From FTIR and XPS analysis, it is found that the main structure of ACFs is a carbon skeleton composed of polycyclic aromatic hydrocarbons with a small number of oxygen-containing functional groups. The adsorption isotherm of ACFs for CO2 conforms to the Langmuir model, indicating that the adsorption process of CO2 by ACFs can be attributed to monolayer adsorption. Both the specific surface area and oxygen-containing functional groups have crucial effects on the adsorption capacity of CO2. The dynamic adsorption experiment determined that ACFs-920-3 had the highest adsorption capacity for CO2 in flue gas, and adsorption equilibrium was achieved after 7 min of adsorption. The adsorption process of CO2 in flue gas by the as-synthesized ACFs fits well with the pseudosecond kinetic model. The CO2 adsorption capacity of the obtained ACFs remained unchanged after 10 cycles of adsorption. A high-value-added route for synthesizing ACFs for CO2 capture using CLR as a raw material was developed.
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Developing filtering materials with high permeation flux and contaminant removal rate is of great importance for oily wastewater remediation. Herein, a robust three-dimensional (3D) activated carbon fibers (ACFs) based composite with uniformly grown layered double hydroxide (LDH) on the surface was successfully constructed through a feasible hydrothermal strategy. The LDH with a high surface energy and vertically aligned structure could provide superhydrophilicity to ACFs. Systematic investigation confirmed that the 3D material could overcome the size mismatch between the ACFs macropores and tiny emulsified droplets through the combination of size-sieving filtration on the surface and oil droplet coalescence in the fiber network. This process efficiently separated the intractable surfactant-stabilized oil-in-water emulsions with high permeation flux (up to 4.16 × 106 L m-2 h-1 bar-1). Notably, the LDH also had well-dispersed catalytic active sites, which could initiate advanced oxidation processes (AOPs) to efficiently eliminate various types of water-soluble organic pollutants (e.g., pharmaceuticals, phenolic compounds and organic dyes). The resulting modified ACFs exhibited exceptional removal rates for both oil and organic pollutants in the complex sewage during the continuous filtration process. These versatile abilities integrated with the facile preparation method reported herein provide outstanding prospects for the large-scale treatment of oily wastewater.
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Carvão Vegetal , Águas Residuárias , Fibra de Carbono , Óleos/química , EsgotosRESUMO
Extensive use of pesticides resulting in their accumulation in the environment presents a hazard for their non-target species, including humans. Hence, efficient remediation strategies are needed, and, in this sense, adsorption is seen as the most straightforward approach. We have studied activated carbon fibers (ACFs) derived from viscose fibers impregnated with diammonium hydrogen phosphate (DAHP). By changing the amount of DAHP in the impregnation step, the chemical composition and textural properties of ACFs are effectively tuned, affecting their performance for dimethoate removal from water. The prepared ACFs effectively reduced the toxicity of treated water samples, both deionized water solutions and spiked tap water samples, under batch conditions and in dynamic filtration experiments. Using the results of physicochemical characterization and dimethoate adsorption measurements, multiple linear regression models were made to reliably predict performance towards dimethoate removal from water. These models can be used to quickly screen among larger sets of possible adsorbents and guide the development of novel, highly efficient adsorbents for dimethoate removal from water.
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In this study, the activation with ZnCl2 and heat treatment at 950 °C were performed to polyacrylonitrile-based carbon fiber and phenol resin to prepare two types of activated carbon fibers (ACFs) with different amounts of quaternary nitrogen (N-Q). In order to investigate the effect of chemical properties of ACFs on nitrate adsorption, various experiments and assess were conducted on these samples. The pHpzc of Py-7.0Z4-9.5HT10 and PhR-6.0Z4-9.5HT30 was about 7.1 and 7.0, respectively, and was no significant difference in the results. The C-π sites had a large effect on the amount of nitrate adsorption, and its adsorption capacity was greatest when the solution pH was about 3. However, the adsorption affinity (Ke) of C-π sites was weaker than that of N-Q, and the contribution for adsorption was small when the solution was low concentration or neutral, while the N-Q was the dominant adsorption site of ACFs. It is expected that the N-Q affected the adsorption kinetics, and the higher the amount of N-Q, the faster the adsorption rate. Py-7.0Z4-9.5HT10 had a large amount of C-π sites and N-Q. Therefore, the equilibrium adsorption amount (Qe) of Py-7.0Z4-9.5HT10 was 1.02 mmol/g at solution pH 3, and the adsorption kinetics were also fast.
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Carvão Vegetal , Nitratos , Adsorção , Fibra de Carbono , Concentração de Íons de Hidrogênio , Cinética , NitrogênioRESUMO
In order to fabricate high performance fiber pseudocapacitors, the trade-off between high mass loading and high utilization efficiency of pseudocapacitive materials should be carefully addressed. Here, a solution that is to construct a carbon-based versatile scaffold is reported for loading pseudocapacitive materials on carbonaceous fibers. The scaffold can be easily built by conformally coating commercial pen ink on the fibers without any destruction to the fiber skeleton. Due to the high electrical conductivity and abundant macropore structure, it can provide sufficient loading room and a high ion/electron conductive network for pseudocapacitive materials. Therefore, their loading mass and utilization efficiency can be increased simultaneously, and thus the as-designed fibrous electrode displays a high areal capacitance of 649 mF cm-2 (or 122 mF cm-1 based on length), which is higher than most of the reported fiber pseudocapacitors. The simple and low-cost strategy opens up a new way to prepare high performance portable/wearable energy storage devices.
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Phenolic resin based activated carbon fibers (ACFs) were applied for the first time as a reversed-dispersive solid-phase extraction (r-DSPE) sorbent. A modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) method was applied to determine 26 pesticides (organophosphates, organochlorines, synthetic pyrethroids, and herbicides) in different complex matrices, including cauliflower, cucumber, banana, apple, wheat, and black gram. Different physicochemical characterization techniques were used to investigate the engineering and structural properties of the r-DSPE sorbent. All the chromatographic analyses were performed with a gas chromatograph equipped with an electron capture detector. The recoveries of all 26 pesticides were acceptable (70-120%), with relative standard deviations of less than 15%. The limit of detection and the limit of quantification were 1.13-5.48 ng/g and 3.42-16.60 ng/g, respectively. In the original QuEChERS method, primary secondary amine is extensively used as the r-DSPE sorbent in the cleanup process, but it is eightfold more expensive than the ACFs used in this study. Therefore, the modified QuEChERS method using ACFs during the cleanup process is more efficient, cheaper, and more robust to determine pesticides from different types of matrices, including vegetables, grains, and fruits, and ACFs could be used as a cost-effective alternative to primary secondary amine. Graphical Abstract Sample clean-up using PSA and ACF as r-DSPE sorbent in QuEChERS method.
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Carbono/química , Análise de Alimentos/métodos , Contaminação de Alimentos/análise , Resíduos de Praguicidas/análise , Extração em Fase Sólida/métodos , Fibra de Carbono , Carvão Vegetal/química , Cromatografia Gasosa/economia , Cromatografia Gasosa/métodos , Grão Comestível/química , Análise de Alimentos/economia , Frutas/química , Limite de Detecção , Resíduos de Praguicidas/isolamento & purificação , Extração em Fase Sólida/economia , Verduras/químicaRESUMO
The present work reports the preparation of activated carbon fibers (ACFs) from pineapple plant leaves, and its application on caffeine (CFN) removal from aqueous solution. The preparation procedure was carried out using the H3PO4 as activating agent and slow pyrolysis under N2 atmosphere. The characterization of materials was performed from the N2 adsorption and desorption isotherms, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), Raman spectroscopy, Boehm titration and pHpzc method. ACFs showed high BET surface area value (SBET = 1031m2 g-1), well-developed mesoporous structure (mesopore volume of 1.27cm³ g-1) and pores with average diameter (DM) of 5.87nm. Additionally, ACFs showed features of fibrous material with predominance of acid groups on its surface. Adsorption studies indicated that the pseudo-second order kinetic and Langmuir isotherm models were that best fitted to the experimental data. The monolayer adsorption capacity was found to be 155.50mgg-1. thermodynamic studies revealed that adsorption process is spontaneous, exothermic and occurs preferably via physisorption. The pineapple leaves are an efficient precursor for preparation of ACFs, which were successful applied as adsorbent material for removal of caffeine from the aqueous solutions.
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Ananas/química , Cafeína/análise , Carbono/química , Folhas de Planta/química , Poluentes Químicos da Água/análise , Purificação da Água/métodos , Adsorção , Brasil , Fibra de Carbono , Carvão Vegetal/química , Cinética , Modelos Teóricos , TermodinâmicaRESUMO
This study utilized activated carbon fibers (ACFs) as adsorbents to investigate the removal efficiency of naphthalene and toluene at elevated temperatures and their competitive adsorption behavior. Three types of ACFs, inlet concentrations of naphthalene (343, 457, and 572 mg·Nm-3), and toluene (2055, 2877, and 4110 mg·Nm-3) were investigated to determine the adsorption capacities of naphthalene and toluene. To study the reaction mechanisms of naphthalene and toluene on the ACFs, the BET, SEM, FTIR, and TGA methods were used to examine the physical and chemical characteristics of ACFs. Results showed ACF-A's superior adsorption capacity for naphthalene that was attributed to its mesoporous structure and hydrophobicity. Adsorption equilibrium studies indicated multilayer adsorption behavior. Competitive adsorption experiments demonstrated the displacement of toluene by naphthalene on ACF-A, highlighting its higher selectivity for naphthalene. Functional group analysis revealed changes in ACF surfaces after naphthalene adsorption, suggesting π-π dispersion and electron donor-acceptor interactions. Overall, this study underscores the importance of pore structure and surface properties in designing ACFs for the efficient adsorption of high-boiling-point organic pollutants.
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Activated carbon fibers (ACFs) derived from various polymeric fibers with the characteristics of a high specific surface area, developed pore structure, and good flexibility are promising for the new generation of chemical protection clothing. In this paper, a polyacrylonitrile-based ACF felt was prepared via the process of liquid phase pre-oxidation, along with a one-step carbonization and chemical activation method. The obtained ACF felt exhibited a large specific surface area of 2219.48 m2/g and pore volume of 1.168 cm3/g, as well as abundant polar groups on the surface. Owing to the developed pore structure and elaborated surface chemical property, the ACF felt possessed an intriguing adsorption performance for a chemical warfare agent simulant dipropyl sulfide (DPS), with the highest adsorption capacity being 202.38 mg/g. The effects of the initial concentration of DPS and temperature on the adsorption performance of ACF felt were investigated. Meanwhile, a plausible adsorption mechanism was proposed based on the kinetic analysis and fitting of different adsorption isotherm models. The results demonstrated that the adsorption process of DPS onto ACF felt could be well fitted with a pseudo-second-order equation, indicating a synergistic effect of chemical adsorption and physical adsorption. We anticipate that this work could be helpful to the design and development of advanced ACF felts for the application of breathable chemical protection clothing.
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The adhesion of high-viscosity oil contamination poses limitations on three-dimensional (3D) materials' practical use in treating oilfield-produced water (OPW). In this study, we developed a hybrid pDA/TiO2/SiO2 coating (PTS) on the surface of hydrophilic activated carbon (ACF1) through a combination of dopamine (DA) polymerization, ethyl orthosilicate (TEOS) hydrolysis, and the condensation of TiO2 nanoparticles (NPs) with SiO2 NPs. This coating was designed for gravity-based oil-water separation. The inherent porosity and generous pore size of ACF1-PTS conferred it an ultra-high permeation flux (pure water flux of 3.72 × 105 Lâm-2âh-1), allowing it to effectively separate simulated oil-water mixtures and oil-water emulsions while maintaining exceptional permeation flux and oil rejection efficiency. When compared to cleaning methods involving ethanol aqueous solutions and NaClO, ultraviolet (UV) illumination cleaning proved superior, enabling oil-contaminated ACF1-PTS to exhibit remarkable flux recovery efficiency and oil-removal capabilities during cyclic separation of actual OPW. Furthermore, the ACF1-PTS material demonstrated impressive stability and durability when exposed to acidic environments (acid, alkali, and salt), robust hydraulic washout conditions, and 25-cycle tests. This study offers valuable insights and research avenues for the development of highly efficient and environmentally friendly 3D oil-water separation materials for the actual treatment of OPW.
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Trace heavy metals exist in drinking water, having great adverse effects on human health and making it a huge challenge to remove. Herein, novel materials have been prepared by a simple and green method using single- (polydopamine (PDA) or 2,3-dimercaptopropanesulfonic sodium (DMPS)) (PDA-OACF or DMPS-OACF) and two-component (PDA and DMPS) (DMPS-PDA-OACF) functionalized activated carbon fibers pretreated by hydrogen peroxide for the removal of trace heavy metals. The as-prepared DMPS-OACF (7.5,20) under DMPS addition of 7.5 mg and sonication time of 20 min retained large specific surface area, micro-mesoporous structure and rich functional groups and showed better adsorption performance for trace lead and mercury. It also exhibited wide applicable ranges of pH (3.50-10.50) and concentration (50-1136 µg L-1), rapid adsorption kinetics, and excellently selective removal performance for trace lead. The maximum lead adsorption capacity reached 16.03 mg g-1 when the effluent lead concentration met World Health Organization (WHO) standard and the adsorbent can be regenerated by EDTA solution. The fitting results of adsorption kinetics and isotherm models revealed that the lead adsorption process was multi-site adsorption on heterogeneous surfaces and chemical adsorption. The excellent adsorption properties for trace heavy metals were attributed that the sulfur/oxygen/nitrogen-containing functional groups boosted diffusion and adsorption by electrostatic attraction and coordination, suggesting that DMPS-OACF (7.5,20) has great application potential in the removal of trace heavy metals.
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Água Potável , Metais Pesados , Oligoelementos , Poluentes Químicos da Água , Humanos , Chumbo , Carvão Vegetal/química , Fibra de Carbono , Poluentes Químicos da Água/análise , Metais Pesados/análise , Adsorção , Cinética , Concentração de Íons de HidrogênioRESUMO
Solar drying represents an attractive way to implement an efficient and green development strategy. The viability of open sorption thermal energy storage (OSTES) can compensate for the inherent shortcomings of intermittency and instability of solar energy for ensuring the continuity of the drying process. Nevertheless, the existing solar-powered OSTES technologies only allow a batch mode while being severely restricted by sunlight's availability, thereby heavily limiting the flexibility in managing OSTES on demand. Herein, a novel proof-of-concept that a standalone solar dryer integrated with a reversible solid-gas OSTES unit is presented. Using in situ electrothermal heating (in situ ETH) could rapidly release adsorbed water of activated carbon fibers (ACFs) in an energy-efficient manner to achieve a charging process with faster kinetics. Applying electrical power by a photovoltaic (PV) module, particularly during sunlight-absent or insufficient time, allowed multiple OSTES cycles to proceed. Moreover, ACFs cylindrical cartridges can be flexibly interconnected in either series or parallel, forming universal assemblies with well-controlled in situ ETH capacity. The mass storage density of ACFs with a water sorption capacity of 570 mg/g is 0.24 kW·h·kg-1. The desorption efficiencies of ACFs are higher than 90%, corresponding to 0.057 kW·h maximum energy consumption. The resulting prototype can diminish the fluctuation of air humidity along the night and provide a relatively steady and lower air humidity for the drying chamber. The energy-exergy and environment analysis of the drying section for both setups are estimated, respectively.
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Arctium , Energia Solar , Luz Solar , Fibra de Carbono , Carvão VegetalRESUMO
The release and accumulation of pesticides in the environment require the development of novel sustainable technologies for their removal. While adsorption is a classical approach, the design of new materials with enhanced adsorption properties could rationalize the remediation routes and decrease potential risks for their non-target organisms, including humans. More importantly, the use of adsorbents and their synthesis should be implemented in a sustainable and environmentally friendly manner. In this contribution, we studied the adsorption of organophosphorus pesticides (OPs) dimethoate, malathion, and chlorpyrifos on viscose fiber-derived activated carbon fibers (ACFs). The most efficient adsorption was found for chlorpyrifos, followed by malathion and dimethoate, while material properties were correlated with OP uptake. These ACFs are extremely efficient for chlorpyrifos adsorption, with experimentally observed adsorption capacitances reaching 240 mg g-1. Detailed analysis suggests that chlorpyrifos is physisorbed on ACF surfaces and that increased surface hydrophilicity reduces the uptake. Studied ACFs have great potential for practical application. They can reduce OPs' concentrations to such levels that no acute neurotoxic effects of the studied OPs in spiked tap water samples are seen, even for starting concentrations up to 104 times higher than the allowed ones. Finally, this study presents possible guidance for developing even more efficient and environmentally friendly adsorbents for chlorpyrifos, the most toxic among studied OPs.
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Clorpirifos , Praguicidas , Carvão Vegetal , Clorpirifos/análise , Dimetoato , Humanos , Malation/análise , Compostos OrganofosforadosRESUMO
This article focuses on EPR relaxation measurements in various carbon samples, e.g., natural carbons-anthracite, coal, higher anthraxolites, graphite; synthetically obtained carbons-glassy carbons, fullerenes, graphene, graphene oxide, reduced graphene oxide, graphite monocrystals, HOPG, nanoribbons, diamonds. The short introduction presents the basics of resonant electron spin relaxation techniques, briefly describing the obtained parameters. This review presents gathered results showing the processes leading to electron spin relaxation and typical ranges of electron spin relaxation rates for many different carbon types.
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The process of noble metals ions recovery and the removal small fraction of nanoparticles from waste solution is an urgent topic not only from the economic but also ecology point of view. In this paper, the use of activated carbon fibers (ACF) as a "trap" for gold nanoparticles obtained by a chemical reduction method is described. The synthesized nanoparticles were stabilized either electrostatically or electrosterically and then deposited on carbon fibers or activated carbon fibers. Moreover, the deposition of metal on fibers was carried out in a batch reactor and a microreactor system. It is shown, that process carried out in the microreactor system is more efficient (95%) as compared to the batch reactor and allows for effective gold nanoparticles removal from the solution. Moreover, for similar conditions, the adsorption time of the AuNPs on ACF is shortened from 11 days for the process carried out in the batch reactor to 2.5 min in the microreactor system.
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Contamination of water by nitrate has become a worldwide problem, being high levels of this ion detected in the surface, and groundwater, mainly due to the intensive use of fertilizers, and to the discharge of not properly treated effluents. This study aims to evaluate the electrocatalytic process, carried out in a cell divided into two compartments by a cation exchange membrane, and with a copper plate electrode as cathode, identifying the effects of current density, pH, the use of a catalyst in the nitrate reduction, and the production of gaseous compounds. The highest nitrate reduction was obtained with a current density of 2.0 mA cm-2, without pH adjustment and, in this condition, nitrite ion was mainly formed. The application of activated carbon fibers with palladium (1% wt. and 3% wt.) in an alkaline medium presented an increase in gaseous compounds formation. With 2.0 mA cm-2, pH adjustment, and applying 3% wt. Pd catalyst, the highest selectivity to gaseous compounds was obtained (95%) with no nitrite detection. These results highlight the viability of using the process developed at this work for the treatment of nitrate contaminated waters.
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Carvão Vegetal , Nitratos , Fibra de Carbono , Catálise , NitritosRESUMO
In the present study, we successfully prepared two different electrospun polyacrylonitrile (PAN) based-activated carbon nanofiber (ACNF) composites by incorporation of well-distributed Fe2O3 and Co3O4 nanoparticles (NPs). The influence of metal oxide on the structural, morphological, and textural properties of final composites was thoroughly investigated. The results showed that the morphological and textural properties could be easily tuned by changing the metal oxide NPs. Even though, the ACNF composites were not chemically activated by any activation agent, they presented relatively high surface areas (SBET) calculated by Brunauer-Emmett-Teller (BET) equation as 212.21 and 185.12 m2/g for ACNF/Fe2O3 and ACNF/Co3O4 composites, respectively. Furthermore, the ACNF composites were utilized as candidate adsorbents for CO2 and CH4 adsorption. The ACNF/Fe2O3 and ACNF/Co3O4 composites resulted the highest CO2 adsorption capacities of 1.502 and 2.166 mmol/g at 0 °C, respectively, whereas the highest CH4 adsorption capacities were obtained to be 0.516 and 0.661 mmol/g at 0 °C by ACNF/Fe2O3 and ACNF/Co3O4 composites, respectively. The isosteric heats calculated lower than 80 kJ/mol showed that the adsorption processes of CO2 and CH4 were mainly dominated by physical adsorption for both ACNF composites. Our findings indicated that ACNF-metal oxide composites are useful materials for designing of CO2 and CH4 adsorption systems.
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The pitch-based activated carbon fibers with nickel sulfide nanoparticles (ACF/NiS) were designed by in situ polymerization of ethylene tar with the addition of nickel nitrate followed by melt spinning, stabilization, carbonization, steam activation, and vulcanization processes. The ACF/NiS with hierarchical pore structure and abundant active sites was used as an anode material to improve Coulombic efficiency and increase capacity of potassium-ion batteries (PIBs). The results showed the obtained ACF/NiS with excellent specific surface area of 1552 m2 g-1 and high mesopore volume contribution of 38%, which delivered a high initial Coulombic efficiency of 84.22%, a high capacity of 292.5 mAh g-1, and retained 95.7% capacity retention after 200 cycles at 0.5 A g-1 current density. The NiS provided abundant active sites for the adsorption of potassium-ion, and the rich hierarchical structure shortened the electrolyte penetration path and expanded the storage space of potassium-ion, making it easier to store potassium-ion inside the ACF/NiS anode to obtain a better performance. This work presented one strategy for designing the hierarchical pore structure of pitch-based ACF to boost the capacity storage of PIBs and revealed that ACF-based carbon materials served as potential anodes for high-performance PIBs.
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The toluene poses a serious threat to the atmospheric environment and human health. Herein, the reduced graphene oxide (rGO)/TiO2 immobilized on the activated carbon fiber (ACF) are fabricated by ultrasonic assisted sol-gel impregnation method to photodegrade dynamic toluene. Characterizations of rGO/TiO2/ACF composites reveal that the majority of graphene oxide (GO) is reduced to rGO and rGO/TiO2 is evenly loaded onto the ACF surface in the form of a smooth film. Furthermore, the photoelectrochemical experiments demonstrate both rGO and ACF can enhance significantly the separation efficiency of electron-hole pairs. The maximum removal efficiency of rGO/TiO2/ACF-0.75% can be up to 85% under ultraviolet irradiation. The rGO/TiO2/ACF exhibits more excellent adsorption and photodegradation activity for dynamic toluene than both rGO/TiO2 and ACF due to the synergetic effect rather than a simple linear combination of the rGO/TiO2 and ACF for toluene conversion. The possible photodegradation pathway is proposed according to intermediates measured by GC-MS, and adsorption coupling photocatalytic mechanisms are discussed.