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Chem Biodivers ; 14(12)2017 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-28963759

RESUMO

Two new flavones, 6,7-methylenedioxy-4-hydroxypeltogynan-7'-one (1), cochliophilin B (2), as well as two known ones, cochliophilin A (3) and 6-methoxy-7-hydroxy flavone (4), were isolated from the ethanol extract of the root of Phytolacca acinosa Roxb. Compound 1 is a flavanol framework with one δ-lactone unit, which is rather rare in nature. The structures of the new compounds were determined on the basis of extensive spectroscopic (IR, MS, 1D- and 2D-NMR) analyses, the absolute configuration of 1 was established by comparing experimental and calculated electronic circular dichroism spectra. The structures of known compounds were fixed by comparison with literatures data. Compounds 2 and 4 showed modest inhibitory activities against BEL-7402 cell line, with IC50 values of 28.22 and 39.16 µmol/L, respectively.


Assuntos
Flavonas/química , Phytolacca/química , Células A549 , Linhagem Celular Tumoral , Sobrevivência Celular/efeitos dos fármacos , Flavonas/isolamento & purificação , Flavonas/toxicidade , Humanos , Espectroscopia de Ressonância Magnética , Espectrometria de Massas , Conformação Molecular , Mycobacterium tuberculosis/efeitos dos fármacos , Phytolacca/metabolismo , Raízes de Plantas/química , Raízes de Plantas/metabolismo , Espectrofotometria Infravermelho
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