Nanostructured Surfaces Enhance Nucleation Rate of Calcium Carbonate.

Nucleation and growth of calcium carbonate on surfaces is of broad importance in nature and technology, being essential to the calcification of organisms, while negatively impacting energy conversion through crystallization fouling, also called scale formation. Previous work studied how confinements, surface energies, and functionalizations affect nucleation and polymorph formation, with surface-water interactions and ion mobility playing important roles. However, the influence of surface nanostructures with nanocurvature-through pit and bump morphologies-on scale formation is unknown, limiting the development of scalephobic surfaces. Here, it is shown that nanoengineered surfaces enhance the nucleation rate by orders of magnitude, despite expected inhibition through effects like induced lattice strain through surface nanocurvature. Interfacial and holographic microscopy is used to quantify crystallite growth and find that nanoengineered interfaces experience slower individual growth rates while collectively the surface has 18% more deposited mass. Reconstructions through nanoscale cross-section imaging of surfaces coupled with classical nucleation theory-utilizing local nanocurvature effects-show the collective enhancement of nano-pits.

Influence of an Axial-Electromagnetic Field Treatment Device with a Solenoid Structure on Crystallization Fouling on the Tube Side of a Shell-and-Tube Heat Exchanger.

In this study, the influence of an axial-electromagnetic field treatment device (AEFTD) with a solenoid structure using different electromagnetic frequencies on calcium carbonate (CaCO3) crystallization fouling on the tube side of a shell-and-tube heat exchanger was investigated. The experimental results indicated that the application of the AEFTD could effectively reduce fouling resistance and decelerate the growth rate of CaCO3 fouling. The opposite trend between fouling resistance and the outlet temperature of an experimental fluid indicated that the application of the AEFTD could enhance heat transfer. Meanwhile, the crystal morphologies of the fouling samples were analyzed by means of scanning electron microscopy (SEM). The axial-electromagnetic field favored the formation of vaterite as opposed to calcite. Non-adhesive vaterite did not easily aggregate into clusters and was suspended in bulk to form muddy fouling that could be carried away by turbulent flow. Furthermore, the anti-fouling mechanism of the axial-electromagnetic field is discussed in detail. The anti-fouling effect of the AEFTD on CaCO3 fouling exhibited extreme characteristics in this study. Therefore, the effectiveness of the AEFTD is contingent upon the selection of the electromagnetic parameters.

Analysis of crystallization fouling in electric water heating.

In the present study, the main influencing factors of crystallization fouling in electric water heating were investigated. Dependence on the saturation index and four operating parameters was analyzed, namely: liquid temperature, surface temperature, flow rate and electrical leakage current. A focus of the study was the influence of electrical leakage current on the fouling behavior and the morphology of the deposited crystal layers. The investigation shows that the aforementioned parameters influence the fouling process and crystal size growth in a different way. The experimental results were used to find a correlation between the electrical leakage current and induction time. In addition, a modeling approach is presented which allows an estimation of the fouling mass flux.